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A processing technology for improving the intrinsic coercive force of rare earth permanent magnets

A rare earth permanent magnet, intrinsic coercive force technology, applied in inductor/transformer/magnet manufacturing, electrical components, circuits, etc., can solve the problems of reducing side effects, long time, affecting magnet remanence, etc. The effect of improving tenacity and aging performance

Active Publication Date: 2018-08-31
宁波同创强磁材料有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0002] The intrinsic coercive force of rare earth permanent magnets requires a large amount of heavy rare earths such as dysprosium, and the addition of heavy rare earths seriously affects the phenomenon of magnet remanence
At present, there are two techniques for improving the intrinsic coercive force of rare earth magnets. The first is a common process, which is achieved by adding a large amount of heavy rare earth elements such as dysprosium to the formula, but heavy rare earths have a greater impact on the remanence of magnets. reduced side effects
The second is through the Dysprosium infiltration process. Heavy rare earth powders such as Dysprosium Oxide and Dysprosium Fluoride are added to the heating system or applied to the product, and the Heavy Rare Earths such as Dysprosium are gradually penetrated into the surface of the magnet through high temperature, thereby improving the magnet’s performance. Intrinsic coercivity, but the process has high heating temperature (900-1000°C), long time, easy deformation of the product, easy oxidation of the surface, and low utilization rate of heavy rare earth powders such as dysprosium oxide and dysprosium fluoride (only <10%) and other shortcomings

Method used

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  • A processing technology for improving the intrinsic coercive force of rare earth permanent magnets
  • A processing technology for improving the intrinsic coercive force of rare earth permanent magnets
  • A processing technology for improving the intrinsic coercive force of rare earth permanent magnets

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0020] A batch of N48 products was produced using the non-heavy rare earth formula, and a batch of 35AH products with a heavy rare earth content of 10% were produced using the heavy rare earth formula.

[0021] 1. Ingredients:

[0022]

[0023] 2. Melting: First, the surface of the copper roller of the vacuum melting furnace is polished, and then various high-purity raw materials are directly mixed according to the formula weight requirements, and then put into the vacuum quick-setting melting furnace, and the vacuum quick-setting melting furnace is evacuated to below At 0.1 Pa, start heating and melting. When the material in the furnace turns red, fill it with argon and raise the temperature. The melting temperature is 1440°C until the raw material is completely melted. After 10 minutes of refining, pouring is carried out. The cooling water of the copper roller during pouring The temperature is 10°C and then the power is turned off, and the flakes are released from the ove...

Embodiment 2

[0041] Use the heavy rare earth formula to produce a batch of 48M products with a heavy rare earth content of 0.5%, and use the heavy rare earth formula to produce a batch of 38EH products with a heavy rare earth content of 7%.

[0042] 1. Ingredients:

[0043]

[0044] 2. Melting: First, the surface of the copper roller of the vacuum melting furnace is polished, and then various high-purity raw materials are directly mixed according to the formula weight requirements, and then put into the vacuum quick-setting melting furnace, and the vacuum quick-setting melting furnace is evacuated to below At 4Pa, start heating and melting. When the material in the furnace turns red, fill in argon and raise the temperature. The melting temperature is 1450°C until the raw materials are completely melted. After 11 minutes of refining, pouring is carried out. The cooling water temperature of the copper roller during pouring It is 12°C and then turn off the power, and when the flakes are lo...

Embodiment 3

[0063] The N48, 35AH and 48M three kinds of materials that embodiment 1 and embodiment 2 prepare are respectively processed into the black flake that magnetization direction thickness is less than 10mm, and three kinds of material black flake surfaces are cleaned and cross mixed and put into airtight container (N48 and The 48M black sheet materials are not adjacent, and are separated by 35AH black sheet materials), and then put into the vacuum heating chamber, and the vacuum is pumped to 5.0*10 -2 Below Pa, then heat to 820°C for 10 hours, and then temper at 530°C for 3.5 hours, then cool to 50°C with the furnace and then come out of the furnace.

[0064] Then the two materials were tested according to the provisions of GB / T3217 permanent magnet (hard magnetic) material magnetic test method, and the magnetic properties are shown in Table 7.

[0065] Table 7

[0066]

[0067] It can be seen from Table 7 that the Hcj of N48 and 48M increased by 3.21KOe and 3.11KOe respective...

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Abstract

The invention relates to a processing technology for raising rare earth permanent magnet intrinsic coercive force, and the processing technology mainly comprises the steps of mixing a rare earth permanent magnet product black sheet I at least comprising <5% heavy rare earth and a rare earth permanent magnet product black sheet II comprising >=5% heavy rare earth by intersecting; then sintering and tempering. <{EN2}>According to the processing technology, no extra heavy rare earth like dysprosium will be added; the characteristics of the magnet that the heavy rare earth elements in the magnet can be easily precipitated, diffused and volatilized at a high temperature and after multi-time tempering are used; the intrinsic conercive force of the rare earth permanent magnet is raised; the remanent magnetism of the magnet won't be reduced and no heavy rare earth is wasted; at the same time, the deformation rate and the aged performance of the product are greatly raised.

Description

technical field [0001] The invention relates to a processing technology for improving the magnetic performance of a rare earth permanent magnet, in particular to a processing technology for improving the intrinsic coercive force of a rare earth permanent magnet. Background technique [0002] A large amount of heavy rare earths such as dysprosium is needed to increase the intrinsic coercive force of rare earth permanent magnets, and the addition of heavy rare earths seriously affects the phenomenon of magnet remanence. At present, there are two techniques for improving the intrinsic coercive force of rare earth magnets. The first is a common process, which is achieved by adding a large amount of heavy rare earth elements such as dysprosium to the formula, but heavy rare earths have a greater impact on the remanence of magnets. reduced side effects. The second is through the Dysprosium infiltration process. Heavy rare earth powders such as Dysprosium Oxide and Dysprosium Fluo...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): H01F41/02
CPCH01F41/0253H01F41/0293
Inventor 范逢春张子祥谢鼎福赵红良
Owner 宁波同创强磁材料有限公司