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Concentrating and tar removing method of biomass gasification liquid (bamboo vinegar)

A processing method and technology of bamboo vinegar liquid are applied in the processing field of concentrating and detaring, and can solve problems such as affecting product promotion, bamboo vinegar liquid cannot be formed into large-tonnage consumer goods, and bamboo vinegar liquid has low content of active ingredients.

Inactive Publication Date: 2017-05-10
ZHEJIANG FORESTRY UNIVERSITY
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0005] Bamboo vinegar contains a certain amount of tar, which forms a serious smoky taste, which makes most people feel disgusted. Therefore, all kinds of sanitary products used in people's living environment are generally disgusted by the smoky taste and affect product promotion;
[0006] The content of active ingredients in bamboo vinegar is too low, for example, the content of natural organic acids is generally no more than 10%, and the content of 10-30% is generally required for herbicides, so bamboo vinegar can not be used directly for herbicides because of insufficient content. kills weeds, making weed control less effective;
[0007] The low content of active ingredients in bamboo vinegar directly affects the packaging cost of the product. Generally, the packaging cost per ton is more than 1,000 yuan, and the average logistics cost is also close to 1,000 yuan. The cost of such packaging and logistics is far higher than the value of bamboo vinegar itself. Higher than the acceptable price in the market, thus causing bamboo vinegar to be unable to form a marketable product
[0008] In short, because bamboo vinegar contains a certain amount of tar, which produces an unpleasant smoky taste, and the content of active ingredients is too low, resulting in low activity and high packaging and transportation costs, bamboo vinegar cannot be used as a large-tonnage consumer product.

Method used

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  • Concentrating and tar removing method of biomass gasification liquid (bamboo vinegar)
  • Concentrating and tar removing method of biomass gasification liquid (bamboo vinegar)
  • Concentrating and tar removing method of biomass gasification liquid (bamboo vinegar)

Examples

Experimental program
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Effect test

example 1

[0041] 1) Put 100 parts of bamboo vinegar into the enamel reaction kettle, then slowly add Ca(OH)2 (or CaO) into it and stir to dissolve completely until PH=6, record the amount of inorganic alkali added as 4 parts; 2) Distillation atmospheric pressure distillation for the first time, till 10% that distillate accounts for the ratio of bamboo vinegar liquid is 10 parts, distillate is discharged as waste water; The inorganic acid HCl (10.665 parts (37% hydrochloric acid aqueous solution), the calculation method is calculated according to the following method

[0042] Ca(OH)2+2HCl=CaCl2+2H2O;

[0043] 74 73

[0044] 4 x = ? X=73*4 parts / 74=3.946 parts (effective content)=10.665 parts (37% hydrochloric acid aqueous solution)

[0045] 2) The second distillation is at normal pressure until the distillation is complete (i.e. no distillate is produced), and the distillate is collected, which is concentrated bamboo vinegar.

[0046] 3) Washing and filtering, that is, distilling the...

example 2

[0049]1) Put 100 parts of bamboo vinegar into the enamel reaction kettle, then slowly add NaOH therein and stir to dissolve completely until PH=7, record the amount of adding inorganic alkali as 4 parts; 2) Distill for the first time at atmospheric pressure, 20% of the ratio of the bamboo vinegar liquid that the distillate accounts for is 20 parts, and the distillate is discharged as waste water; 3) acidification reaction, under the situation of constantly stirring, gradually adds the mineral acid HCl (9.865 parts of ( 37% hydrochloric acid aqueous solution), the calculation method is calculated according to the following method

[0050] NaOH+HCl=NaCl+H2O

[0051] 40 36.5

[0052] 4 x = ? X=36.5*4 parts / 40=3.65 parts (effective content)=9.865 parts (37% hydrochloric acid aqueous solution)

[0053] 2) The second distillation is at normal pressure until the distillation is complete (i.e. no distillate is produced), and the distillate is collected, which is concentrated bamboo...

example 3

[0057] 1) Put 100 parts of bamboo vinegar into the enamel reaction kettle, then slowly add NaOH therein and stir to dissolve completely until PH=7, record the amount of adding inorganic alkali as 4 parts; 2) Distill for the first time at atmospheric pressure, 30% that distillate accounts for the ratio of bamboo vinegar liquid till 30 parts, distillate is discharged as waste water; 3) acidification reaction, under the situation of constantly stirring, gradually add the inorganic acid HCl (7.046 parts of 37% hydrochloric acid aqueous solution), the calculation method is calculated according to the following method

[0058] KOH+HCl=KCl+H2O

[0059] 56 36.5

[0060] 4 x = ? X=36.5*4 parts / 56=2.61 parts (effective content)=7.046 parts (37% hydrochloric acid aqueous solution)

[0061] 2) The second distillation is at normal pressure until the distillation is complete (i.e. no distillate is produced), and the distillate is collected, which is concentrated bamboo vinegar.

[0062]...

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Abstract

The invention discloses a concentrating and tar removing method of biomass gasification liquid (bamboo vinegar) and belongs to the field of natural product deep processing. The bamboo vinegar contains a certain amount of tar which generates an odorous smoked smell and is low in activity and high in packaging and transportation cost due to low effective component content, so that the bamboo vinegar cannot become large-tonnage consumer goods. In order to solve the marketization difficulty above with a technical manner, the concentrating and tar removing method includes: using neutralizing reaction, first distillation, acidizing reaction and second distillation to perform concentration and tar removing on the bamboo vinegar; using washing and filtering and third distillation to separate the bamboo vinegar. The concentrating and tar removing method has the advantages that the organic acid content of the bamboo vinegar is increased to above 95%, the tar removing rate is above 95%, and the concentrating times can be the optional one of 1-95 times.

Description

technical field [0001] The invention relates to a processing method for concentrating and removing tar from bamboo vinegar, which is used for refining bamboo vinegar and belongs to the field of natural product processing, in particular to a processing method for concentrating and removing tar. Background technique [0002] Biomass gasification liquid is a brown liquid substance that is condensed at room temperature from the gas collected after pyrolysis of plant materials and their processing residues. At present, there are mainly bamboo vinegar, wood vinegar and grass vinegar. "Biomass gasification liquid (bamboo vinegar liquid)" in the present invention is defined as bamboo vinegar liquid (a by-product obtained by pyrolysis of bamboo processing residues). At present, in the process of processing bamboo into corresponding bamboo charcoal, due to the high-efficiency production of modern machines, the by-product produced in the production process, a biomass gasification liqui...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C10C5/00
CPCC10C5/00Y02E50/10
Inventor 马建义
Owner ZHEJIANG FORESTRY UNIVERSITY
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