High-performance water-proof mildew-proof coating and preparation method thereof
A waterproof and mildew-proof, high-performance technology, applied in the direction of anti-fouling/underwater coatings, polyether coatings, coatings, etc., can solve the problem of lack of anti-mildew and antibacterial, affecting the service life, weather resistance, and flame retardancy of architectural waterproof coatings And poor water resistance and other problems, to achieve the effect of excellent antibacterial performance, high strength, excellent weather resistance
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Embodiment 1
[0067] Mix 7 grams of talcum powder, 7 grams of ammonium dichromate, 2 grams of Portland cement, 8 grams of alkylphenol polyoxyethylene ether phosphate, 7 grams of KH-5607 grams, polyquaternium modified sulfonated polyetheramine-overrun 8 grams of polypyrrolene copolymer, 2 grams of 2-naphthylamine-5-sulfonic acid, 19 grams of deionized water and 2 grams of dimethyl sulfoxide were added into the mixer and mixed fully for 18 minutes, and then the material was discharged, and the stirring rate was 300 rpm;
[0068] The preparation method of described polyquaternium modified sulfonated polyetheramine-hyperbranched polypyrrole copolymer is:
[0069] (1) Preparation of polyquaternium salt
[0070] In a 1000ml dry three-neck flask, add 0.1mol of 1,12-dibromododecane, 0.092mol of 1,4-dimethylpiperazine and 80ml of solvent dimethyl sulfoxide, and react at 50°C for 5 hours, Then add 0.0025mol of N-methylimidazole and 0.0025mol of N-methylmorpholine, and react at 50°C for 5 hours, the...
Embodiment 2
[0082] Mix 7 grams of talcum powder, 7 grams of ammonium dichromate, 2 grams of Portland cement, 8 grams of alkylphenol polyoxyethylene ether phosphate, 7 grams of KH-5607, polyquaternium modified polyetheramine-hyperbranched poly Add 8 grams of pyrolone copolymer, 2 grams of 2-naphthylamine-5-sulfonic acid, 19 grams of deionized water and 2 grams of dimethyl sulfoxide into the mixer and mix thoroughly for 18 minutes, then the material is discharged, and the stirring speed is 300 rpm / Minute;
[0083] The preparation method of described polyquaternary ammonium salt modified polyether amine-hyperbranched polypyrrole copolymer is:
[0084] (1) Preparation of polyquaternium salt
[0085] In a 1000ml dry three-neck flask, add 0.1mol of 1,12-dibromododecane, 0.092mol of 1,4-dimethylpiperazine and 80ml of solvent dimethyl sulfoxide, and react at 50°C for 5 hours, Then add 0.0025mol of N-methylimidazole and 0.0025mol of N-methylmorpholine, and react at 50°C for 5 hours, then distil...
Embodiment 3
[0095] 7 grams of talcum powder, 7 grams of ammonium dichromate, 2 grams of Portland cement, 8 grams of alkylphenol polyoxyethylene ether phosphate, 7 grams of KH-5607 grams, sulfonated polyetheramine-hyperbranched polypyrrole copolymer 8 grams, 2 grams of 2-naphthylamine-5-sulfonic acid, 19 grams of deionized water and 2 grams of dimethyl sulfoxide were added to the mixer and mixed thoroughly for 18 minutes, then the material was discharged, and the stirring rate was 300 rpm;
[0096] The preparation method of described sulfonated polyetheramine-hyperbranched polypyrrole copolymer is:
[0097] (1) Preparation of amino-terminated polyetheramine
[0098] Add 95 grams of epoxy resin E51, 0.26 mol of benzylamine and 700 grams of dimethyl sulfoxide in sequence to a 1000 mL dry three-necked bottle, protect with nitrogen and magnetically stir; after stirring at room temperature for 1 hour, heat up to 95°C for 6 hours , After the reaction, cool down to room temperature, and quickly ...
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