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A kind of automobile three-way catalytic converter catalyst

A three-way catalytic converter and catalyst technology, applied in the direction of physical/chemical process catalysts, metal/metal oxide/metal hydroxide catalysts, chemical instruments and methods, etc., can solve the problems of sensation, reaction, understanding, memory impairment, weakening , Harm the central nervous system and other problems, to achieve the effect of ensuring high temperature aging resistance, enhancing oxidation conversion ability, and enhancing conversion efficiency

Active Publication Date: 2019-06-18
安徽新态环保科技有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, with the increase of the number of automobiles, the air pollution caused by automobile exhaust has become increasingly serious, and has become one of the main sources of pollution in large cities. The main pollutants in automobile exhaust are carbon monoxide (CO), hydrocarbons (HC) and nitrogen Oxygen compounds (NOx), in which carbon monoxide enters the blood circulation through the respiratory tract, and forms carboxyhemoglobin after affinity with hemoglobin, thereby weakening the function of blood to transport oxygen to various tissues, endangering the central nervous system, and causing people's feelings, reactions, understanding, and memory. In severe cases, it will endanger the blood circulation system and cause life-threatening

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0015] Embodiment 1: a kind of automobile three-way catalyst catalyst, the honeycomb carrier specification is Ф106mm×120mm, the pore density is 600cpsi, the pore wall thickness is 4.3mil, and the volume is 1.06L; Pd and Rh 10g are attached to the first half of the honeycomb carrier / ft 3 The mass ratio is 1:3 coating, and the second half is attached with Pt and Pd 10g / ft 3 The mass ratio is 1:3 coating, as the lower coating; the upper coating Pd, Rh 50g / ft is attached to the lower coating 3 The mass ratio is 1:7 coating. The composition of the zirconium solid solution A attached to the lower layer is: 20wt% ZrO 2 , 20wt% Al 2 O 3 , 23wt% CeO 2 , 2wt% TiO 2 and 2wt% La 2 O 3 ; Pd and Rh in the upper layer coating are attached to the cerium zirconium solid solution B, and the composition of the cerium zirconium solid solution B is: 35wt% ZrO 2 , 25wt% Al 2 O 3 , 15wt% CeO 2 , 2wt% TiO 2 and 2wt% of Y 2 O 3 , Pr 6 O 11 .

[0016] The preparation method of the au...

Embodiment 2

[0020] Embodiment 2: a kind of automobile three-way catalyst catalyst, the honeycomb carrier specification is Ф106mm×120mm, the pore density is 600cpsi, the pore wall thickness is 4.3mil, and the volume is 1.06L; Pd and Rh 10g are attached to the first half of the honeycomb carrier / ft 3 The mass ratio is 1:2 coating, and the second half is attached with Pt and Pd 10g / ft 3 The mass ratio is 1:2 coating, as the lower coating; the upper coating Pd, Rh 50g / ft is attached to the lower coating 3 The mass ratio is 1:4 coating. The composition of the zirconium solid solution A attached to the lower layer is: 25wt% ZrO 2 , 25wt% Al 2 O 3 , 25wt% CeO 2 , 3wt% TiO 2 and 2.5wt% Pr 6 O 11 , Nd 2 O 3 ; Pd and Rh in the upper coating are attached to the cerium-zirconium solid solution B, and the composition of the cerium-zirconium solid solution B is: 38wt% ZrO 2 , 28wt% Al 2 O 3, 17wt% CeO 2 , 2.4wt% TiO 2 and 2.5wt% La 2 O 3 .

[0021] The preparation method of the autom...

Embodiment 3

[0025] Embodiment 3: a kind of automobile three-way catalyst catalyst, the honeycomb carrier specification is Ф106mm×120mm, the pore density is 600cpsi, the pore wall thickness is 4.3mil, and the volume is 1.06L; Pd and Rh 10g are attached to the first half of the honeycomb carrier / ft 3 The mass ratio is 1:2.5 coating, and the second half is attached with Pt and Pd 10g / ft 3 The mass ratio is 1:2.5 coating, as the lower coating; the upper coating Pd, Rh 50g / ft is attached to the lower coating 3 The mass ratio is 1:5.5 coating. The composition of the zirconium solid solution A attached to the lower layer is: 25wt% ZrO 2 , 25wt% Al 2 O 3 , 25wt% CeO 2 , 3wt% TiO 2 and 2.5wt% Pr 6 O 11 , Nd 2 O 3 ; Pd and Rh in the upper coating are attached to the cerium-zirconium solid solution B, and the composition of the cerium-zirconium solid solution B is: 38wt% ZrO 2 , 28wt% Al 2 O 3 , 17wt% CeO 2 , 2.4wt% TiO 2 and 2.5wt% La 2 O 3 , also contains BaO 2 , SrO, TiO 2 : B...

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PUM

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Abstract

The present invention discloses an automobile three-way catalytic converter catalyst comprising a honeycomb support. The automobile three-way catalytic converter catalyst is characterized in that the front half section of the honerycomb support is loaded with a coating with a mass ratio of Pd to Rh being 1:(1-5); the rear half section of the honeycomb support is loaded with a coating with a mass ratio of Pt to Pd being 1:(1-5) as a lower coating; and an upper coating with a mass ratio of Pd to Rh being 1:(2-8) is attached to the lower coating. The catalyst is in a coating structure that the lower layer is subjected to twice subsection attaching, the upper layer is subjected to one attaching, Pt , Pd and Rh are respectively attached onto different areas according to a certain ratio with reasonable control, selective catalytic conversion function is achieved, and combination of different coatings of rare earth and transition metal complex oxides is matched, so that the oxygen storage capacity is met, the high activity of catalytic reduction on oxynitrides and the high temperature aging capacity of active components of noble metals are ensured.

Description

technical field [0001] The invention relates to the technical field of automobile three-way catalytic converters, in particular to an automobile three-way catalytic converter catalyst. Background technique [0002] With the development of society, the advancement of science and technology, and the continuous improvement of people's living standards, automobiles have become the mainstream means of transportation and are widely used. However, with the increase in the number of cars, the air pollution caused by car exhaust has become more and more serious, and it has become one of the main pollution sources in large cities. The main pollutants in car exhaust are carbon monoxide (CO), hydrocarbons (HC) and nitrogen. Oxygen compounds (NOx), in which carbon monoxide enters the blood circulation through the respiratory tract, and forms carboxyhemoglobin after binding with hemoglobin, thereby weakening the function of blood to transport oxygen to various tissues, harming the central...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): B01J23/63F01N3/28B01D53/92
CPCB01D53/922B01J23/63F01N3/2803F01N2570/10F01N2570/12F01N2570/14Y02A50/20Y02T10/12
Inventor 肖飞龙仰春华刁节超
Owner 安徽新态环保科技有限公司
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