Method for preparing high-stability arsenic fixing minerals through adjusted and controlled growth process
A high-stability, mineral-based technology, applied in protection devices against harmful chemicals, etc., to achieve mild reaction conditions, high stability, and small BET specific surface area
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Embodiment 1
[0040] The main components in the arsenic solution include: As 60g / L, Sb 1.1g / L, Pb 235ppm, Sn 38.5ppm, Te24.4ppm, NaOH 30g / L.
[0041] A kind of preparation method of highly stable arsenic-fixed mineral, comprises the following steps: arsenic-containing solution adopts the method for catalytic oxidation to As 3+ Oxidized to As 5+, the control conditions are, the oxygen flow rate is 5L / min, adding KMnO 4 As a catalyst, the molar ratio of As / Mn is controlled at 10:1, and the temperature of the catalytic oxidation system is controlled at 90°C. The results show that As 3+ The conversion rate was 98.45%.
[0042] Adjust the pH value of the oxidized solution to 1.5, and add CaO and Ca(OH) in a continuous feeding mode 2 As an arsenic precipitating agent, the Ca / As molar ratio is 5, the settling time is 6 hours, and the reaction temperature is 60° C. to generate calcium arsenate. Synthesis of arsenic-fixing minerals adopts a regulated growth method. The control conditions are to ...
Embodiment 2
[0044] The main components in the arsenic solution include: As 76g / L, Sb 0.8g / L, Pb 96.7ppm, Sn 27.5ppm, Te38.7ppm, NaOH 25g / L.
[0045] A kind of preparation method of highly stable arsenic-fixed mineral, comprises the following steps: arsenic-containing solution adopts the method for catalytic oxidation to As 3+ Oxidized to As 5+ , the control conditions are, oxygen flow rate is 10L / min, adding KMnO 4 As a catalyst, the molar ratio of As / Mn is controlled at 40:1, and the temperature of the catalytic oxidation system is controlled at 30°C. The results show that As 3+ The conversion rate is 92.31%;
[0046] Adjust the pH value of the oxidized solution to 2, and add CaO and Ca(OH) in a continuous feeding mode 2 As the arsenic precipitating agent, the Ca / As molar ratio is 8, the settling time is 8 hours, and the reaction temperature is 90° C. to generate calcium arsenate. Synthesis of arsenic-fixing minerals adopts a regulated growth method. The control conditions are to add...
Embodiment 3
[0048] The main components in the arsenic solution include: As 50g / L, Sb 1.8g / L, Pb 186ppm, Sn 34.7ppm, Te27.8ppm, NaOH 5g / L.
[0049] A kind of preparation method of highly stable arsenic-fixed mineral, comprises the following steps: arsenic-containing solution adopts the method for catalytic oxidation to As 3+ Oxidized to As 5+ , the control conditions are, oxygen flow rate is 1L / min, adding KMnO 4 As a catalyst, the molar ratio of As / Mn is controlled at 20:1, and the temperature of the catalytic oxidation system is controlled at 120°C. The results show that As 3+ The conversion rate is 89.36%
[0050] Adjust the pH value of the oxidized solution to 1.5, and add CaO and Ca(OH) in a continuous feeding mode 2 As the arsenic precipitating agent, the Ca / As molar ratio is 5, the settling time is 5 hours, and the reaction temperature is 60° C. to generate calcium arsenate. Synthesis of arsenic-fixing minerals adopts a regulated growth method. The control conditions are to add ...
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