Carbon fiber prepreg and preparation method thereof

A carbon fiber prepreg, carbon fiber technology, applied in the field of polymer materials and their preparation, can solve the problems of increased production difficulty, non-uniform materials, complex production processes, etc., and achieves suitable temperature control, simple production process steps, and product mechanical properties. excellent effect

Inactive Publication Date: 2017-09-01
JIANGSU ZHAOJUN NEW MATERIAL CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

CN201310515677.4 provides a prepreg that is stored at room temperature and the cured material is mechanically stable, but the normal temperature storage time of the carbon fiber prepreg currently produced needs to be further improved
In addition, another difficulty in improving the room temperature storage time of carbon fiber prepreg is that after the formula is changed, the production difficulty increases, the components after the formula adjustment cannot achieve continuous production, and the produced materials are not uniform
[0003] The applicant has been committed to the research of carbon fiber prepreg, and already has the production practice and theoretical basis of carbon fiber prepreg, such as 201610338104.2 (a preparation method of high-strength carbon fiber prepreg), which discloses that the applicant prepares carbon fiber prepreg related components in the material, such as liquid epoxy resin, solid epoxy resin, curing agent and accelerator, etc., but the applicant still encountered the following problems when researching carbon fiber prepregs that can be stored at room temperature: When it comes to resin ratio and resin type, even small-scale adjustments and replacement of resins with similar structures will have a great impact on the product’s gelling performance and final cured performance, and the adjusted formula cannot be mass-produced; The impregnation itself has extremely high requirements on material performance and the complexity of the production process, which caused the applicant to greatly affect the overall performance and production cycle of the material when adjusting its formula

Method used

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  • Carbon fiber prepreg and preparation method thereof
  • Carbon fiber prepreg and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0026] Example 1: Stir 10kg each of novolac epoxy resin NPCN-704, liquid bisphenol A epoxy resin NPEL-128 and solid bisphenol A epoxy resin NPES-901 at 80°C, and after mixing completely, a mixed solution A is obtained ; Add 0.9kg of curing agent dicyandiamide 100S to the mixed solution A, and stir evenly at 70°C to obtain the mixed solution B, add 0.15kg accelerator UR700 to the mixed solution B, and stir evenly at 70°C to obtain Mixed solution C, the viscosity of mixed solution C is 10000cps, take 2kg of mixed solution C and solidify at 150°C for 2 hours to obtain an epoxy resin cast body, and measure the performance of the epoxy resin cast body. Put the remaining mixed liquid C in the glue coating machine, check the weight per square meter of the film with an infrared instrument, and lower the temperature of the film to room temperature through the cooling plate to obtain the film, and put the film from the prepreg machine up and down Lead out from the rubber film roll, and ...

Embodiment 2

[0027] Example 2: Stir 10kg of novolac epoxy resin 638S, 20kg of liquid bisphenol A epoxy resin NPEL-128 and 10kg of solid bisphenol A epoxy resin NPES-901 at 90°C, and after mixing completely, a mixed solution A is obtained; Add 1.5kg of curing agent dicyandiamide 100SF to mixed solution A, and stir evenly at 80°C to obtain mixed solution B, add 0.83kg accelerator modified imidazole PN40 to mixed solution B, and stir evenly at 80°C , to obtain the mixed solution C, the viscosity of the mixed solution C is 20000cps, take 2kg of the mixed solution C and cure it at 150°C for 2h to obtain the epoxy resin cast body, and measure the performance of the epoxy resin cast body. Put the remaining mixed liquid C in the glue coating machine, check the weight per square meter of the film with an infrared instrument, and lower the temperature of the film to room temperature through the cooling plate to obtain the film, and put the film from the prepreg machine up and down Lead out from the ...

Embodiment 3

[0028] Example 3: Stir 10kg of novolac epoxy resin 638S, 15kg of liquid bisphenol A epoxy resin NPEL-128 and 10kg of solid bisphenol A epoxy resin NPES-901 at 85°C. After mixing completely, a mixed solution A is obtained; Add 2.8kg of curing agent dicyandiamide DDA-5 to mixed solution A, stir evenly at 75°C to obtain mixed solution B, add 1.1kg accelerator modified imidazole PN50 to mixed solution B, and stir at 75°C After uniformity, the mixed solution C was obtained. The viscosity of the mixed solution C was 40,000 cps. Take 2kg of the mixed solution C and cure it at 150°C for 2 hours to obtain an epoxy resin cast body, and measure the performance of the epoxy resin cast body. Put the remaining mixed liquid C in the glue coating machine, check the weight per square meter of the film with an infrared instrument, and lower the temperature of the film to room temperature through the cooling plate to obtain the film, and put the film from the prepreg machine up and down Lead out...

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PUM

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Abstract

The invention discloses carbon fiber prepreg and a preparation method thereof. The carbon fiber prepreg is mainly prepared from components as follows: epoxy resin, a curing agent, an accelerant and carbon fibers, wherein epoxy resin is prepared from novolac epoxy resin, liquid bisphenol A epoxy resin and solid bisphenol A epoxy resin in a mass ratio being 1:(1-2):1. The carbon fiber prepreg can be stored for more than 12 months at the normal temperature and can be widely applied to the fields of fishing tackles, sports apparatus, sporting goods, aerospace and the like.

Description

technical field [0001] The invention relates to a polymer material and a preparation method thereof, in particular to a carbon fiber prepreg and a preparation method thereof. Background technique [0002] Carbon fiber prepreg is a composite material made of carbon fiber yarn, epoxy resin and other materials, which are processed by coating, hot pressing, cooling, laminating, coiling and other processes, also known as carbon fiber prepreg; carbon fiber prepreg Prepregs are widely used in fishing tackle, sports equipment, sporting goods, aerospace and other fields. At present, long-term storage of carbon fiber prepregs requires low-temperature storage, which increases its application cost. CN201310515677.4 provides a prepreg that is stored at room temperature and has a mechanically stable cured product, but the normal temperature storage time of the currently produced carbon fiber prepreg needs to be further improved. In addition, another difficulty in improving the room tempe...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L63/00C08K7/06C08J5/24
CPCC08L63/00C08J5/24C08J2363/00C08J2463/00C08L2205/025C08L2205/03C08K7/06
Inventor 鲁平才杨智明
Owner JIANGSU ZHAOJUN NEW MATERIAL CO LTD
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