High-vicat anticorrosion high-strength CPVC (chlorinated polyvinyl chloride) plate and preparation method thereof

A corrosion-resistant, high-vicat technology, applied to high-strength CPVC sheets and their preparation, corrosion-resistant, high-vicat fields, can solve problems such as high prices, limited promotion and use, and late start of CPVC research and development, and achieve good market competition The effect of power and price concessions

Inactive Publication Date: 2017-09-19
山东高信化学股份有限公司 +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Developed countries such as Europe, America, Japan and the Middle East have applied a large number of CPVC materials to the chemical industry, which has achieved good results; my country is also a large chemical country. At present, metal, cement, enamel and conventional plastic rubber materials are mainly used in the industry, and CPVC materials are rarely used. This is mainly because CPVC materials are mainly imported, and the price is high, which limits wide-scale application. However, domestic manufacturers started late in the research and development of CPVC, and the quality of CPVC resin and formulation materials produced is poor. It is difficult to meet the requirements of industrial production, which limits this. Promote the use of materials

Method used

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  • High-vicat anticorrosion high-strength CPVC (chlorinated polyvinyl chloride) plate and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0043] Embodiment 1, a kind of high-vicat, corrosion-resistant, high-strength CPVC sheet material, the Vicat softening temperature of described CPVC sheet material is at 112

[0044] ℃, the tensile strength is 52MPa, and the heat distortion temperature is 110℃.

[0045] The CPVC plate is composed of the following raw materials in parts by weight:

[0046] CPVC resin: 100 parts of CPVC resin with a chlorine content of 70% and a degree of polymerization of 600;

[0047] PVC resin S-700, 5 parts;

[0048] Heat stabilizer: 5 parts of calcium-zinc composite stabilizer;

[0049] Auxiliary stabilizer: 1.2 parts of epoxidized soybean oil;

[0050] 1 part of pentaerythritol stearate;

[0051] External lubricant: 1.4 parts of Fischer-Tropsch wax;

[0052] Internal lubricant: 1.3 parts of stearic acid;

[0053] Processing aid: ACR401, 1.8 parts;

[0054] Impact modifier: 3 parts of MBS resin;

[0055] Filler: 5 parts of white carbon black;

[0056] Pigment: 0.03 parts of carbon ...

Embodiment 2

[0058] Embodiment 2, a kind of high-vicat, corrosion-resistant, high-strength CPVC sheet material, the Vicat softening temperature of described CPVC sheet material is at 118

[0059] ℃, the tensile strength is 58MPa, and the heat distortion temperature is 114℃.

[0060] The CPVC plate is composed of the following raw materials in parts by weight:

[0061] CPVC resin: 100 parts of CPVC resin with a chlorine content of 71% and a degree of polymerization of 600;

[0062] PVC resin S-700, 5 parts;

[0063] Heat stabilizer: 5 parts of rare earth composite stabilizer;

[0064] Auxiliary stabilizer: 0.5 part of epoxidized soybean oil;

[0065] 1.2 parts of pentaerythritol stearate;

[0066] External lubricant: 2.5 parts of PE wax;

[0067] Internal lubricant: 1 part of OPE wax;

[0068] Processing aid: ACR401, 2 parts;

[0069] Impact modifier: CPE135A, 5 parts;

[0070] Filler: 3 parts of titanium dioxide.

[0071] The CPVC resin is prepared by combining an initiator and ul...

Embodiment 3

[0072] Embodiment 3, a high-Vicat, corrosion-resistant, high-strength CPVC plate, the Vicat softening temperature of the CPVC plate is 120°C, the tensile strength is 61MPa, and the heat distortion temperature is 116°C.

[0073] The CPVC plate is composed of the following raw materials in parts by weight:

[0074] CPVC resin: 100 parts of CPVC resin with a chlorine content of 72% and a degree of polymerization of 600;

[0075] PVC resin S-700, 10 parts;

[0076] Heat stabilizer: 3 parts of calcium-zinc composite stabilizer, 3 parts of rare earth composite stabilizer;

[0077] Auxiliary stabilizer: 0.8 parts of epoxidized soybean oil;

[0078] 2 parts of pentaerythritol stearate;

[0079] External lubricant: 1 part of PE wax;

[0080] Internal lubricant: 1 part of calcium stearate;

[0081] Processing aid: ACR201, 1.5 parts;

[0082] Impact modifier: impact-resistant ASA, 1.5 parts;

[0083] Filler: 6 parts of white carbon black;

[0084] Pigment: 0.06 parts of carbon bl...

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Abstract

The invention discloses a high-vicat anticorrosion high-strength CPVC (chlorinated polyvinyl chloride) plate, having vicat softening point of between 110-120 DEG C, tensile strength of 52-61 MPa and thermal deformation temperature of 108-116 DEG C; the plate is prepared from, by weight, 80-100 parts of CPVC resin, 5-20 parts of PVC resin, 4-6 parts of a thermal stabilizer, 0.5-2 parts of an auxiliary stabilizer, 1-2 parts of pentaerythritol stearate, 1-4 parts of an external lubricant, 1-4 parts of an internal lubricant, 0.5-3.5 parts of a processing aid, 2-5 parts of an impact modifier, 3-8 parts of filling material, and 0-0.08 part of a pigment. The CPVC material produced herein is 10-30% lower in cost than abroad like products; all the other aids are commercially available materials, having low price; by integrated calculation, the plate is 20-40% lower in cost than abroad formulations, and is approximately the same as the abroad formulations in performance; therefore, the plate has high market competitiveness.

Description

technical field [0001] The invention belongs to the field of polymer materials, and in particular relates to a high-vicat, corrosion-resistant, high-strength CPVC plate and a preparation method thereof. Background technique [0002] Many acidic, alkaline, and high-salt liquids and solids are produced in the chemical production process. Many of these substances contain a lot of heat, so special devices are required for storage or transfer of these substances. At present, the storage devices in the chemical production process are mainly composed of stainless steel, glass fiber reinforced plastics, enamel, cement and other engineering plastics or rubber-lined materials. Stainless steel materials are not corrosion-resistant and have a short service life, and the rust produced will affect product quality; the comprehensive performance of glass fiber reinforced plastics Good, but it is brittle at low temperature, and it will produce a lot of pollution during construction, which wi...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L27/24C08L27/06C08L91/00C08L33/04C08L51/04C08L23/06C08K13/02C08K5/09C08K5/103C08K3/36C08K3/04C08K3/22C08K5/098
CPCC08L27/24C08L2205/02C08L2205/035C08L2205/025C08L2201/08C08K2003/2241C08L27/06C08L91/00C08L33/04C08L51/04C08K13/02C08K5/09C08K5/103C08K3/36C08K3/04C08L91/06C08L23/06C08L23/286C08K3/22C08K5/098
Inventor 张悦金胜波肖斌蒋连海李胜华孟祥昊
Owner 山东高信化学股份有限公司
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