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PVC modified material for fireproof ceiling and preparing method thereof

A modified material and ceiling technology, which is applied in the field of PVC modified materials for fire-resistant ceilings and its preparation, can solve the problems of poor elasticity and anti-mildew effect, poor fire and flame retardancy, and poor thermal stability, and achieve good elasticity and anti-corrosion Mildew effect, excellent impact resistance, excellent processability

Inactive Publication Date: 2017-09-22
广东祺龙科技有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0002] Polyvinyl chloride (PVC) is one of the earliest industrialized and widely used general-purpose thermoplastics. It has light weight, high strength, insulation, flame retardancy, corrosion resistance, It has the advantages of excellent comprehensive performance, low price and wide source of raw materials; but it also has the following disadvantages: 1. Poor toughness, easy to be brittle when impacted, so it cannot be used as a structural material. In addition, the brittleness of polyvinyl chloride is greatly affected by temperature. Large, the lower limit of general PVC products is -15°C, and the lower limit of soft PVC is -30°C; 2. Poor thermal stability, it begins to decompose HCl at 100°C, and decomposes more rapidly when it is higher than 150°C. The melting temperature of PVC is about 210°C; 3. The viscosity of PVC is extremely high and its fluidity is extremely poor, which limits its use to a certain extent.
[0003] However, the existing PVC materials for fire-resistant ceilings have defects such as poor fire-proof and flame-retardant properties, and poor elasticity and mildew-proof effects, which limit their use to a certain extent.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0072] A kind of PVC modified material for fireproof ceiling, described PVC modified material for fireproof ceiling comprises the raw material of following weight portion:

[0073] PVC resin 80 parts

[0074] 40 parts plasticizer

[0075] Light calcium carbonate 10 parts

[0076] 8 parts of heavy calcium carbonate

[0077] Fire retardant 4 parts

[0078] Magnesium oxide 3 parts

[0079] 3 parts heat stabilizer

[0080] Elastic modifier 2 parts

[0081] Antifungal agent 0.6 parts

[0082] 0.6 parts of external lubricant.

[0083] The PVC resin is an ethylene-based PVC resin with an average degree of polymerization of 1000.

[0084] The plasticizer is a mixture composed of diisopropyl cyclohexane-1,2-dicarboxylate, trioctyl trimellitate and epoxidized soybean oil in a weight ratio of 2:1:0.4.

[0085] The light calcium carbonate has a particle size of 10 μm and has been modified by a higher fatty acid salt; the heavy calcium carbonate has a particle size of 100 μm and h...

Embodiment 2

[0096] A kind of PVC modified material for fireproof ceiling, described PVC modified material for fireproof ceiling comprises the raw material of following weight portion:

[0097] PVC resin 90 parts

[0098] 44 parts plasticizer

[0099] Light calcium carbonate 11 parts

[0100] 9 parts of heavy calcium carbonate

[0101] Fire retardant 5 parts

[0102] Magnesium oxide 4 parts

[0103] Heat stabilizer 4 parts

[0104] Elastic modifier 2.5 parts

[0105] Antifungal agent 0.7 parts

[0106] 0.7 part of external lubricant.

[0107] The PVC resin is an ethylene-based PVC resin with an average degree of polymerization of 1200.

[0108] The plasticizer is a mixture composed of diisopropyl cyclohexane-1,2-dicarboxylate, trioctyl trimellitate and epoxidized soybean oil in a weight ratio of 2.5:1:0.5.

[0109]The light calcium carbonate has a particle size of 20 μm and has been modified by a higher fatty acid salt; the heavy calcium carbonate has a particle size of 200 μm and...

Embodiment 3

[0120] A kind of PVC modified material for fireproof ceiling, described PVC modified material for fireproof ceiling comprises the raw material of following weight portion:

[0121] PVC resin 100 parts

[0122] Plasticizer 48 parts

[0123] 12.5 parts of light calcium carbonate

[0124] 10 parts of heavy calcium carbonate

[0125] Fire retardant 6 parts

[0126] Magnesium oxide 5 parts

[0127] Heat stabilizer 5 parts

[0128] Elasticity Modifier 3 parts

[0129] Antifungal agent 0.8 parts

[0130] 0.8 part of external lubricant.

[0131] The PVC resin is an ethylene-based PVC resin with an average degree of polymerization of 1500.

[0132] The plasticizer is a mixture composed of diisopropyl cyclohexane-1,2-dicarboxylate, trioctyl trimellitate and epoxidized soybean oil in a weight ratio of 3:1:0.6.

[0133] The light calcium carbonate has a particle size of 30 μm and has been modified by a high-grade fatty acid salt; the heavy calcium carbonate has a particle size of...

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Abstract

The invention relates to the technical field of PVC modified materials, in particular to a PVC modified material for a fireproof ceiling and a preparing method thereof. The PVC modified material for the fireproof ceiling is prepared from, by weight, 80-120 parts of PVC resin, 40-56 parts of a plasticizer, 10-15 parts of light calcium carbonate, 8-12 parts of heavy calcium carbonate, 4-8 parts of a fireproof flame retardant, 3-7 parts of magnesium oxide, 3-7 parts of a heat stabilizer, 2-4 parts of an elastic modifying agent, 0.6-1.0 part of a mildew-proof agent and 0.6-1.0 part of an external lubricant. The PVC modified material for the fireproof ceiling is good in fireproof flame retardant effect, also has the good elasticity and mildew-proof effect, and is environmentally friendly, excellent in temperature resistance and weather resistance, high in strength and excellent in impact resistance, processing performance and comprehensive performance.

Description

technical field [0001] The invention relates to the technical field of PVC modified materials, in particular to a PVC modified material for a fireproof ceiling and a preparation method thereof. Background technique [0002] Polyvinyl chloride (PVC) is one of the earliest industrialized and widely used general-purpose thermoplastics. It has the advantages of light weight, high strength, insulation, flame retardancy, corrosion resistance, excellent comprehensive performance, low price and wide source of raw materials; but also There are the following disadvantages: 1. The toughness is poor, and it is easy to be brittle when impacted, so it cannot be used as a structural material. In addition, the brittleness of polyvinyl chloride is greatly affected by temperature. The lower limit of general PVC products is -15°C. The lower limit of use of PVC is -30°C; 2. Poor thermal stability, it begins to decompose HCl at 100°C, and decomposes more rapidly when it is higher than 150°C, and...

Claims

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Application Information

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IPC IPC(8): C08L27/06C08L91/00C08L25/06C08L33/04C08L91/06C08L23/30C08L61/00C08L67/00C08L23/08C08L23/12C08L23/14C08K13/06C08K9/04C08K3/26C08K5/3492C08K5/521C08K3/22C08K5/098C08K5/12C08K3/38C08K3/40C08K3/34C08K9/08C08K5/20C08K7/10C08K7/08C08K7/14B29C47/92B29C48/92
CPCC08L27/06B29C48/92B29C2948/92704C08K2003/2227C08K2003/265C08K2003/387C08K2201/003C08K2201/014C08L2201/02C08L2205/025C08L2205/035C08L2205/16C08L2205/242C08L91/00C08L25/06C08L33/04C08L91/06C08L23/30C08K13/06C08K9/04C08K3/26C08K5/34922C08K5/521C08K3/22C08K5/098C08K5/12C08L61/00C08L67/00C08L23/0815C08L23/12C08L23/14C08K3/38C08K3/40C08K3/34C08K3/346C08K9/08C08K3/2279C08K5/20C08K7/10C08K7/08C08K7/14
Inventor 宁建华
Owner 广东祺龙科技有限公司
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