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Preparation of array-shaped tio by catalytic oxidation of pure ti by sodium tetraborate 2 Methods

A catalytic oxidation, sodium tetraborate technology, applied in nanotechnology for materials and surface science, metal material coating process, nanotechnology, etc., can solve the problems of expensive thin film area, restricted, etc. Ease of operation, simple preparation equipment and process results

Inactive Publication Date: 2019-08-06
HENAN UNIV OF SCI & TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

As for electron beam evaporation and magnetron sputtering, expensive vacuum equipment is required and the film area is limited

Method used

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  • Preparation of array-shaped tio by catalytic oxidation of pure ti by sodium tetraborate <sub>2</sub> Methods
  • Preparation of array-shaped tio by catalytic oxidation of pure ti by sodium tetraborate <sub>2</sub> Methods
  • Preparation of array-shaped tio by catalytic oxidation of pure ti by sodium tetraborate <sub>2</sub> Methods

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0027] A kind of sodium tetraborate catalyzed oxidation of pure Ti prepares the method of arrayed TiO2:

[0028] (1) Surface pretreatment of pure Ti substrate (pure titanium sheet)

[0029] The titanium rod with a purity of 99.99% is taken, and it is cut into samples of the required size (10x20x1mm) by a wire cutting machine. After being polished with No400, No600, No800, and No1000 sandpaper in sequence, electrolytic polishing is performed. Put the sample in acetone solution and ultrasonically clean it for 10-20 minutes to remove surface oil and wear debris, then rinse it with distilled water, put it in acetone solution and wipe it with absorbent cotton for later use;

[0030] (2) Screen the anhydrous sodium tetraborate with a purity of 99.5% to 20 μm with a sample sieve, put it into a sample belt, mark it, and store it dry.

[0031] (3) Preparation of TiO by catalytic oxidation of sodium tetraborate 2

[0032] The anhydrous sodium tetraborate fine powder screened in (2) i...

Embodiment 2

[0034] Catalytic Oxidation of Pure Ti with Sodium Tetraborate to Prepare Array-like TiO 2 Methods:

[0035] (1) Surface pretreatment of pure Ti substrate (pure titanium sheet)

[0036] The titanium rod with a purity of 99.99% is taken, and it is cut into samples of the required size (10x20x1mm) by a wire cutting machine. After being polished with No400, No600, No800, and No1000 sandpaper in sequence, electrolytic polishing is performed. Put the sample in acetone solution and ultrasonically clean it for 10-20 minutes to remove surface oil and wear debris, then rinse it with distilled water, put it in acetone solution and wipe it with absorbent cotton for later use;

[0037] (2) Screen the anhydrous sodium tetraborate with a purity of 99.5% to 20-100 μm with a sample sieve, put it into a sample belt, mark it, and store it in a dry place.

[0038] (3) Preparation of TiO by catalytic oxidation of sodium tetraborate 2

[0039]The anhydrous sodium tetraborate fine powder screene...

Embodiment 3

[0041] Catalytic Oxidation of Pure Ti with Sodium Tetraborate to Prepare Array-like TiO 2 Methods:

[0042] (1) Surface pretreatment of pure Ti substrate (pure titanium sheet)

[0043] The titanium rod with a purity of 99.99% is taken, and it is cut into samples of the required size (10x20x1mm) by a wire cutting machine. After being polished with No400, No600, No800, and No1000 sandpaper in sequence, electrolytic polishing is performed. Put the sample in acetone solution and ultrasonically clean it for 10-20 minutes to remove surface oil and wear debris, then rinse it with distilled water, put it in acetone solution and wipe it with absorbent cotton for later use;

[0044] (2) Screen anhydrous sodium tetraborate with a purity of 99.5% to 20-100 μm with a sampling sieve, put it into a sample belt, mark it, and store it dry.

[0045] (3) Preparation of TiO by catalytic oxidation of sodium tetraborate 2

[0046] The anhydrous sodium tetraborate fine powder screened in (2) is ...

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Abstract

The invention relates to a method for preparing arrayed TiO2 by catalytic oxidizing of pure Ti sodium tetraborate. A pure titanium rod is sliced and electrochemically polished, anhydrous sodium tetraborate fine powder is spread on a pure titanium slice which is then put into a crucible, and then the crucible is put into a muffle furnace to be heated up to 500-800 DEG C, heat is preserved for 3-7 h, and heating is stopped; and when the furnace temperature is reduced to the room temperature, the pure titanium slice is taken out of the aluminum oxide crucible, and arrayed TiO2 is obtained after cleaning. According to the method for preparing arrayed TiO2 by catalytic oxidizing of the pure Ti sodium tetraborate, the process is simple, the requirement for equipment is low, the prepared TiO2 is distributed in an arrayed shape evenly, after biological activating of the surface, high combining of a bioactive layer and a Ti substrate can be realized, and the problem of implanting failure caused by coating shedding of a Ti substrate implanting material during the implanting process is solved.

Description

technical field [0001] The invention relates to the technical field of preparation of nano-titanium oxide, in particular to the catalytic oxidation of pure Ti sodium tetraborate to prepare array-like TiO 2 Methods. Background technique [0002] Titanium and titanium alloys have become biomedical materials for bone tissue repair and replacement due to their excellent biocompatibility and mechanical adaptability. Titanium and its alloys are biologically inert materials in nature, and there is only a mechanical fit with bone, rather than a strong chemical osseointegration. In order to make its surface biologically active, people use many methods to modify its surface to prepare bioactive coatings to meet the requirements of organisms on the mechanical and biological properties of materials. In situ growth of TiO 2 The method to enhance the bonding strength of bioactive coatings and titanium substrates is a very effective method. Currently commonly used TiO 2 Coating method...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C23C8/12C23C8/02B82Y30/00B82Y40/00
CPCB82Y30/00B82Y40/00C23C8/02C23C8/12
Inventor 逯峙王广欣王亚明尾坂明羲闫焉服邓舜兰
Owner HENAN UNIV OF SCI & TECH