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Ultraviolet photoresponse device based on homogeneous ZnO nano core shell array and manufacturing method

A nano-core-shell and nano-array technology, which is applied in the direction of nanotechnology, nanotechnology, nanotechnology, etc. for materials and surface science, can solve problems such as high cost and complicated process, and achieve low manufacturing cost, good photoresponse, The effect of superior performance

Inactive Publication Date: 2017-10-20
DALIAN NATIONALITIES UNIVERSITY
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  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

How to further improve its performance has always been a research hotspot. The performance of ultraviolet detectors based on one-dimensional ZnO nanomaterials needs to be further improved. At present, most of the existing methods focus on surface noble metal modification, which is complicated in process and high in cost.

Method used

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  • Ultraviolet photoresponse device based on homogeneous ZnO nano core shell array and manufacturing method
  • Ultraviolet photoresponse device based on homogeneous ZnO nano core shell array and manufacturing method
  • Ultraviolet photoresponse device based on homogeneous ZnO nano core shell array and manufacturing method

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Embodiment

[0036] Firstly, 30 mM anhydrous zinc acetate was dissolved in ethanol to prepare a seed crystal solution. Place the glass substrate on a spin coater, drop the configured seed crystal solution on the surface, let it stand for 5 minutes, and spin coat at a speed of 2500 rpm for 5 minutes. Subsequently, the glass substrate on which the seed crystal was grown was placed on a rapid heating stage, and after rapid heating at 200° C. for 15 minutes, it was naturally cooled to room temperature. Then accurately weigh 0.6585g of zinc acetate and 0.4205g of hexamethylenetetramine with an electronic balance, dissolve them in 100ml of deionized water, and stir quickly to obtain a mixed solution. The glass substrate on which the seed crystal grew after the heat treatment was immersed in the mixed solution, and reacted at 90° C. for 5 hours. After the reaction, the obtained glass substrate was taken out, washed with water, and dried in air. Subsequently, 0.2195 g of zinc acetate was accurat...

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Abstract

The invention discloses an ultraviolet photoresponse device based on a homogeneous ZnO nano core shell array. The homogeneous ZnO nano core shell array layer is arranged between a glass substrate and a transparent contact electrode. The transparent contact electrode is ITO conductive glass engraved with a 0.2cm channel. The ZnO nano core shell array is composed of a ZnO nano array seed layer, a ZnO nanorod array core layer growing on the surface of the ZnO nano array seed layer and a ZnO nano flake shell layer growing on the nanorod surface. The structure layer uses the ZnO nano array as a carrier, zinc acetate and hexamethylenetetramine are adopted as raw materials, a low-temperature aqueous solution is firstly adopted to grow the ZnO nanorod array on the ZnO surface, and low-temperature ethanol solvothermal is then adopted to grow the ZnO nano flake layer structure on the nanorod array. The manufacturing method is simple, the reaction temperature is low, and the manufactured product has excellent photoresponse to ultraviolet light.

Description

technical field [0001] The invention relates to a semiconductor material. Background technique [0002] As an important wide-bandgap semiconductor material, zinc oxide material has excellent optical and electrical properties, and the ordered zinc oxide nanoarray has high specific surface area and fast electron transport ability, and it is non-toxic, raw material The cost is low and the growing method is simple. Therefore, it has become a popular material for light-emitting diodes and ultraviolet detectors in recent years, and has good application potential. [0003] The reported ZnO nanostructures are rich and colorful, mainly focusing on the research of one-dimensional vertical arrays. The ultraviolet detector nanowire arrays based on ZnO nanoarrays have a large specific surface area and can provide fast directional transport channels for carriers in recent years. to get more and more attention. How to further improve its performance has always been a research hotspot. T...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): H01L31/0296H01L31/0352H01L31/09H01L31/18B82Y30/00B82Y40/00
CPCB82Y30/00B82Y40/00H01L31/0296H01L31/035227H01L31/09H01L31/1836Y02P70/50
Inventor 于乃森何艳陈向丰齐岩
Owner DALIAN NATIONALITIES UNIVERSITY
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