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Antistatic treatment technology of glass beads for reflective film

A technology of glass microbeads and processing technology, which is applied in the field of antistatic processing technology of glass microbeads for reflective films, can solve problems such as affecting the performance of reflective films, agglomeration of glass microbeads, affecting product quality, etc., and achieves excellent antistatic properties, The effect of improving reflective performance and quality, improving mechanical properties and weather resistance

Inactive Publication Date: 2017-11-03
HEFEI DINGLIANG OPTICAL TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] At present, the transfer method is widely used in the production process of reflective film, and the first process is to plant beads. Due to the high surface energy and surface charge of glass beads, their dispersion is poor, which is not conducive to the formation of a single layer of dense and uniform distribution. The glass bead layer is easy to cause the glass beads to agglomerate and overlap, which will affect the performance of the reflective film and thus affect the product quality

Method used

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Experimental program
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Effect test

Embodiment Construction

[0019] An antistatic treatment process of glass beads for reflective film, comprising the following specific steps:

[0020] (1) Screening of glass beads:

[0021] Carry out flotation on the glass beads to remove some fragments and impurities caused by the exfoliated beads during production and transportation, and vacuum dry at 93°C to remove the moisture adsorbed on the surface;

[0022] (2) Surface modification treatment:

[0023] Add the above screened glass microspheres to distilled water according to the volume ratio of solid-to-liquid ratio of 1:10, after ultrasonic dispersion for 30 minutes, add sodium dodecylbenzenesulfonate, and react at a low speed of 25 rpm for 4 After 1 hour, add 10% NaOH solution to adjust the pH to 3;

[0024] (3) Coating treatment:

[0025] Place the above reaction solution in an oil bath, heat up to 100°C, use a constant pressure dropping funnel to control the flow of the reaction solution, and slowly add 100g / L of Ti(SO 4 ) 2 The solution...

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Abstract

The invention discloses an antistatic treatment technology of glass beads for a reflective film. According to the antistatic treatment technology disclosed by the invention, the Zeta potential on the surfaces of the glass beads which are treated by using an anionic surfactant is increased, and the surfaces have positive charges and have different charges with TiO2.nH2O, so that cladding of titanium dioxide on the glass beads can be effectively promoted, charges loaded on hollow glass beads are basically and completely neutralized, so that the glass beads have good antistatic property, a single glass bead layer which is uniformly distributed can be easily formed, and the reflective property and the quality of the reflective film prepared by the glass beads are obviously increased; meanwhile, due to the introduction of the titanium dioxide, the mechanical performance and the weather resistance of the reflective film can be effectively increased, the antifouling ability of the reflective film can be increased, and negative effects caused by dust, oil stains and the like can be prevented from being brought for the use of the reflective film.

Description

technical field [0001] The invention relates to a material of reflective glass microspheres, in particular to an antistatic treatment process of glass microspheres for reflective film. Background technique [0002] Retro-reflective materials can be simply called reflective materials. As a new type of material, reflective materials are mainly used in traffic signs. By adding reflective elements on the surface of the corresponding materials, the light can return in the same way to achieve the purpose of reflection; Under this condition, the reflective material achieves a visual effect hundreds of times more eye-catching than other non-reflective materials. [0003] The main raw materials used in reflective materials include resins, pigments, glass beads, etc., and any raw material is very important to the performance of reflective products. Among them, the bonding resin must have good construction performance and excellent bonding ability. For glass beads, it is required to h...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C03C17/25C03C23/00
CPCC03C17/25C03C23/0095
Inventor 范春平
Owner HEFEI DINGLIANG OPTICAL TECH
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