Composition and application thereof for catalyst removal of titanium series isoprene rubber

A technology of isoprene rubber and composition, applied in the field of polymer catalysts, can solve the problems of complex process, environmental pollution, thermal oxidation performance and processing application performance of dry rubber, large influence, etc., and achieves high removal efficiency and excellent processing and application. performance effect

Active Publication Date: 2020-12-18
CHINA PETROLEUM & CHEM CORP +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0007] The purpose of the present invention is to overcome the complex process that exists when the method of the prior art is used to remove the trace catalyst in the cis-1,4-polyisoprene and easily cause environmental pollution and the thermal oxidation performance of dry glue and The defect that greatly affects the processing and application performance provides a titanium-based product that will not pollute the environment, has a simple process, and has a good deactivation effect of the catalyst and will not greatly affect the thermal oxidation performance and processing and application performance of the dry glue. Composition and solution for catalyst removal of isoprene rubber and application thereof

Method used

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  • Composition and application thereof for catalyst removal of titanium series isoprene rubber
  • Composition and application thereof for catalyst removal of titanium series isoprene rubber
  • Composition and application thereof for catalyst removal of titanium series isoprene rubber

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Embodiment approach 1

[0028] Embodiment 1: The composition includes triisopropanolamine and N,N-di(3-aminopropyl)ethylethylamine;

Embodiment approach 2

[0029] Embodiment 2: The composition includes tetraethylenepentamine and N,N-di(3-aminopropyl)ethylethylamine;

Embodiment approach 3

[0030] Embodiment 3: The composition includes triisopropanolamine, tetraethylenepentamine and N,N-di(3-aminopropyl)ethylethylamine.

[0031] Preferably, the content weight ratio of the component A to the N,N-bis(3-aminopropyl)ethylethylamine is 1:1-10; more preferably 1:2-4. The inventors of the present invention found in research that when the content weight ratio of the component A and the N,N-bis(3-aminopropyl)ethylethylamine is controlled to be 1:2-4, the present invention can be used The removal rate of the composition is higher when removing the titanium-based isoprene rubber catalyst.

[0032] Preferably, the composition further contains a solvent, and the composition is in the form of a solution.

[0033] Preferably, the solvent is at least one selected from organic solvents and inorganic solvents; more preferably, the organic solvent is selected from at least one of paraffins, cycloalkanes and olefins, and the inorganic solvent is water. Further preferably, the solv...

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Abstract

The invention relates to the field of polymer catalysts, and discloses a composition for removing a catalyst in titanium-based isoprene rubber and an application of the composition. The composition contains a component A and N,N'-bis(3-aminopropyl)ethylenediamine, wherein, the component A is at least one selected from a group consisting of alcohol amine, aliphatic monoamine, aromatic monoamine, aromatic diamine, aromatic polyamine and compounds represented as a formula (I), and in the formula (I), the n is an integer selected from 1 to 8. With the adoption of the method provided by the invention, the catalyst in the titanium-based isoprene rubber can be removed, the removal efficiency is high, and the obtained titanium-based isoprene rubber has excellent processing and application performances.

Description

technical field [0001] The invention relates to the field of polymer catalysts, in particular to a composition for removing titanium-based isoprene rubber catalysts and a method for removing titanium-based isoprene rubber catalysts. Background technique [0002] Polyisoprene can be divided into cis-1,4-polyisoprene, trans-1,4-polyisoprene, 3,4-polyisoprene and 1,2-polyisoprene pentadiene. Among them, cis-1,4-polyisoprene is commonly known as isoprene rubber, and its microstructure is similar to natural rubber (such as Hevea, guayule). At present, isoprene rubber has been widely used in the manufacture of tires and other rubber products, and is the main substitute of natural rubber. [0003] Due to the high degree of unsaturation of cis-1,4-polyisoprene, its molecular chain is easily broken and degraded under the action of some physical and chemical factors such as oxygen, ozone, light, high temperature and ultraviolet rays. At present, Ziegler-Natta catalysts are usually ...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C08C2/04
Inventor 吕鹏飞于浩谭金枚董江舟张杰
Owner CHINA PETROLEUM & CHEM CORP
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