A kind of environment-friendly sulfur removal agent and removal process

A removal and process technology, applied in the field of environmental protection desulfurizer and removal process, can solve the problems of large amount of solvent filling and poor dispersion effect, and achieve the effect of high filling efficiency, reduced usage, and wide application.

Active Publication Date: 2019-11-19
CHINA PETROLEUM ENG & CONSTR +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] At present, in the existing filling process of oil and gas fields, pumps are generally used to inject directly into the pipeline, so that the injected chemical solvent can be freely dispersed with the flow direction of the produced liquid and natural gas to achieve sulfur dissolution, but this method has a large output When the dispersion effect is poor, a large amount of solvent needs to be added to achieve the same effect. Therefore, the spray injection process can quickly realize the dispersion of chemical solvents during pipeline filling, which not only improves chemical solvents and high salinity and organic solvents. Sulfur binding area and can improve the efficiency of chemical solvents

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0020] Mix triazine derivatives 1, 3, 5-s-triazine solution and aminotrimethylene phosphonic acid uniformly at a ratio of 17:3 by volume, and add methyl sulfide (mainly Exist in the gas phase) and the production liquid device, measured after a period of time, the removal rate of methyl sulfide in the gas phase was 42.8%, the removal rate of methyl sulfide in the liquid phase was 44.3%, and the scale inhibition rate was 96.5%. The COD value of the product measured by potassium permanganate is 359ppm, which meets the third-level standard of GB8978 sewage comprehensive discharge. The removal rate of methyl sulfide in the gas phase is 43.4% in the spray method, 44.5% in the liquid phase, and the scale inhibition rate is 96.4%. The measured product COD The value is 332ppm.

[0021] Triazine derivatives 1, 3, 5-s-triazine solution and aminotrimethylene phosphonic acid are uniformly mixed according to the volume percentage of 17:3. Gas phase) and produced liquid device, measured aft...

Embodiment 2

[0023] Mix triazine derivatives 1, 3, 5-s-triazine solution, aminotrimethylene phosphonic acid and ethylenediaminetetraacetic acid according to volume percentage 17:2:1 and mix evenly. The form of injection is added to the device containing methyl sulfide (mainly in the gas phase) and the production liquid. After measurement, the removal rate of methyl sulfide in the gas phase is 51.3%, while the removal rate of methyl sulfide in the liquid phase reaches 99.7% %, the scale inhibition rate reached 91.0%, and the COD value of the product measured with potassium permanganate was 67ppm after filling; with the same ratio, the injection containing methyl sulfide (mainly in the gas phase) and the extracted In the liquid device, it has been measured: the removal rate of methyl sulfide in the gas phase is 99.9%, the removal rate of methyl sulfide in the liquid phase is 99.8%, and the scale inhibition rate is 90.9%. After filling, it is measured with potassium permanganate The COD value...

Embodiment 3

[0027]Mix triazine derivatives 1, 2, 4-triazine solution, aminotrimethylene phosphonic acid and sodium ethylenediamine tetraacetate according to the volume percentage of 15:4:1 and mix evenly. Filling into the device containing methyl sulfide and production fluid, it is determined that the removal rate of methyl sulfide in the gas phase is 51.3%, the removal rate of methyl sulfide in the liquid phase reaches 99.8%, and the scale inhibition rate reaches 97.5%. After filling, measure the COD value of the product with potassium permanganate to be 61ppm; triazine derivatives 1,2,4-triazine solution, aminotrimethylene phosphonic acid and sodium ethylenediaminetetraacetic acid are in the same proportion, using The form of spray injection is added to the device containing methyl sulfide and production fluid. After measurement: the removal rate of methyl sulfide in the gas phase is 99.8%, the removal rate of methyl sulfide in the liquid phase is 99.8%, and the scale inhibition rate It...

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Abstract

The invention relates to the technical field of organic sulfur removal, in particular to an environment-friendly sulfur removal agent and a removal technology thereof. The environment-friendly sulfurremoval agent is prepared from triazine derivatives, an anti-scaling agent and an activating agent in a certain ratio, wherein in percent by volume, the triazine derivatives accounts for 65-90%, the anti-scaling agent accounts for 1-30%, the activating agent accounts for 5-10%, the triazine derivatives react with organic sulfur, the anti-scaling agent is used for inhibiting scaling of high-hardness gas field water, the organic sulfur is insoluble in water, and the triazine derivatives are water soluble, so that the activating agent is used for quickening reaction between the triazine derivatives and the organic sulfur, and products after reaction are soluble in water. A filling technology adopts spray filling, the filling is carried out by adopting a spraying mode behind a sulfur removal tower in a gas field with high sulfur content, spray filling is directly carried out at the wellhead in a gas field with low sulfur content, and the average particle size during filling is less than 40microns. Compared with the traditional sulfur removal agent, the novel environment-friendly sulfur removal agent has the characteristics of high filling efficiency, no toxicity, no harm, no secondarypollution and applicability of products to industrial production.

Description

technical field [0001] The invention relates to the technical field of organic sulfur removal, in particular to an environment-friendly sulfur removal agent and a removal process. Background technique [0002] Organic sulfur is an organic compound mainly composed of methyl sulfide and ethyl sulfide, which is highly volatile, highly toxic and odorous, and insoluble in water. In gas wells in sour gas fields or highly sour gas fields, highly volatile organic sulfur mostly exists in the gas phase (natural gas) as small solid particles, and a small amount is dispersed in the liquid phase of the production fluid. Since organic sulfur is insoluble in water, it is very It is difficult to remove, which not only affects the separation and treatment of natural gas, but also the hydrogen sulfide produced in the post-treatment process of organic sulfur will cause cracks in pipelines and equipment, etc., which not only increases the cost of treatment but also increases the risk, so in the...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C10L3/10C10G29/20
CPCC10G29/205C10G2300/1033C10G2300/207C10L3/103
Inventor 上官昌淮杜磊陈勇彬崔磊张仁勇马含悦吴限魏爱霞王伟郭军
Owner CHINA PETROLEUM ENG & CONSTR
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