The invention relates to the technical field of organic sulfur removal, in particular to an environment-friendly sulfur removal agent and a removal technology thereof. The environment-friendly sulfurremoval agent is prepared from triazine derivatives, an anti-scaling agent and an activating agent in a certain ratio, wherein in percent by volume, the triazine derivatives accounts for 65-90%, the anti-scaling agent accounts for 1-30%, the activating agent accounts for 5-10%, the triazine derivatives react with organic sulfur, the anti-scaling agent is used for inhibiting scaling of high-hardness gas field water, the organic sulfur is insoluble in water, and the triazine derivatives are water soluble, so that the activating agent is used for quickening reaction between the triazine derivatives and the organic sulfur, and products after reaction are soluble in water. A filling technology adopts spray filling, the filling is carried out by adopting a spraying mode behind a sulfur removal tower in a gas field with high sulfur content, spray filling is directly carried out at the wellhead in a gas field with low sulfur content, and the average particle size during filling is less than 40microns. Compared with the traditional sulfur removal agent, the novel environment-friendly sulfur removal agent has the characteristics of high filling efficiency, no toxicity, no harm, no secondarypollution and applicability of products to industrial production.