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Preparation method for cadmium, aluminium and lead ion chelating agent

A chelating agent and aluminum ion technology, which is applied in the field of analytical chemistry and environmental chemistry, can solve the problem of many synthesis steps, and achieve the effects of simple synthesis steps, convenient storage and improved efficiency

Inactive Publication Date: 2018-02-27
CHANGSHA UNIVERSITY OF SCIENCE AND TECHNOLOGY
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  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

There are many synthetic steps in the synthetic method of heavy metal chelating agent, and the synthetic chelating agent is only aimed at heavy metal, does not relate to the metal ion other than heavy metal; And for a kind of chelating agent and its application and a kind of heavy metal chelating agent these two inventions Among them, the former has a chelating effect on all metal ions, while the latter only has a chelating effect on a heavy metal ion, so the application in many aspects is not the desired effect

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  • Preparation method for cadmium, aluminium and lead ion chelating agent
  • Preparation method for cadmium, aluminium and lead ion chelating agent
  • Preparation method for cadmium, aluminium and lead ion chelating agent

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Embodiment Construction

[0022] figure 1 It is the ultraviolet absorption spectrum diagram of chelating agent and different metal ions. In order to explore the selectivity of the chelating agent to aluminum, lead, and cadmium ions, use a 1cm cuvette to pipette 3mL of the ethanol solution of the chelating agent into the cuvette each time, and add 0.05mL, 1×10 -2 mol / L metal ion (Zn 2+ , Mg 2+ 、Cr 3+ , Fe 3+ , Mn 2+ 、K + 、Ni 2+ 、Sr 2+ 、Al 3+ 、Ag + , Hg 2 + , pb 2+ 、Cu 2+ 、Cd 2+ ) salt solution, observe the changes of its UV-vis, its ultraviolet spectrum except aluminum, lead, cadmium ions, in the presence of other metal ions, the ultraviolet absorption of the chelating agent basically does not change. Therefore, it has good selectivity to these ions.

[0023] figure 2 It is the fluorescence spectrum of chelating agent and different metal ions. In order to explore the sensitivity of the chelating agent to cadmium, aluminum, and lead ions, use a 1cm cuvette to pipette 3mL of the ethan...

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Abstract

The invention discloses a preparation method for a metal ion chelating agent, belongs to the field of analytical chemistry and environment, and particularly relates to the preparation method for the metal ion chelating agent and application thereof in treatment of heavy metal ions in polluted water. The preparation method for the chelating agent comprises the following steps: reacting hydroxyacetophenone and benzaldehyde to obtain 2-hydroxylated chalcone; then, reacting the chalcone and hydrazine hydrate to obtain a target product 4,5-dihydro-3-(2-hydroxyl phenyl)-5-phenyl-1H-pyrazoline. The novel chelating agent can be used for complexing and detecting of cadmium, aluminium and lead ions; an analytical method based on the chelating agent is convenient, quick and high in sensitivity; the chelating agent can also be used for removing the cadmium, aluminium and lead ions from the polluted water, and has a good application prospect.

Description

technical field [0001] The invention belongs to the field of analytical chemistry and environmental chemistry, and specifically relates to a chelating agent, in particular to a preparation method of a cadmium, lead, and aluminum ion chelating agent and its application in the detection of aluminum ions and heavy metal ions and in environmental water treatment . Background technique [0002] Metal ions widely exist in nature, it is an important part of maintaining the osmotic balance of multiphase systems, and it is also a necessary part of a wide range of enzyme reactions. But not all metal ions are needed by organisms, such as cadmium ions and lead ions; in addition, some metal ions are needed by organisms but not as much as possible, such as aluminum ions. Cadmium is an environmental pollutant and an element not required by the human body. Excessive intake can cause human poisoning. The World Health Organization lists cadmium as a key research food pollutant; the Internat...

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Application Information

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IPC IPC(8): C07D231/06C09K11/07C09K11/06C02F1/54G01N21/64C02F101/20
CPCC02F1/54C02F2101/20C07D231/06C09K11/06C09K11/07C09K2211/1048G01N21/643
Inventor 顾婷婷曾惜陈灿陈雪娇邹武龚福春
Owner CHANGSHA UNIVERSITY OF SCIENCE AND TECHNOLOGY