Method for preparing aluminum-based super-hydrophobic surface through one-step method

A super-hydrophobic surface, aluminum-based technology, applied in the coating process of metal materials, etc., can solve the problems of raw materials harmful to the human body, expensive equipment, rough structure, etc., and achieve the preparation of less harsh experimental conditions, low equipment requirements, and low cost Effect

Active Publication Date: 2018-03-06
HARBIN INST OF TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] The purpose of the present invention is to overcome the problems of harsh conditions, expensive equipment, and harmful raw materials in the prior art, and provide a method for preparing an aluminum-based superhydrophobic surface in one step. In this method, metal aluminum is put into an aqueous solution of sodium chloride and In the mixed solution of perfluorotetradecanoic acid alcohol solution, hydrothermal synthesis is carried out in a hydrothermal reactor to obtain an aluminum-based superhydrophobic surface with a rough structure and low surface energy

Method used

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specific Embodiment approach 1

[0016] Specific embodiment one: what this embodiment records is a kind of method for preparing aluminum-based superhydrophobic surface by one-step method, and the concrete steps of described method are as follows:

[0017] Prepare sodium chloride aqueous solution and perfluoromyristic acid ethanol solution, mix the two solutions and pour them into a hydrothermal reaction kettle, control the temperature at 150-180°C, and then sand the pure aluminum sheet after ultrasonic cleaning Put it into a hydrothermal reaction kettle, seal it and place the hydrothermal reaction kettle in a constant temperature box. After a period of reaction, take out the aluminum sheet, wash and dry it to obtain an aluminum-based superhydrophobic surface with a micro-nano structure.

[0018] Al produced by the reaction of aluminum with water at high temperature 2 o 3 Or AlOOH, when the reaction time is 40min, 2-5μm flake structure begins to appear on the aluminum surface, and the contact angle to water r...

specific Embodiment approach 2

[0019] Specific embodiment two: a one-step method for preparing an aluminum-based superhydrophobic surface described in specific embodiment one, the mass fraction of the sodium chloride aqueous solution is 0.5%-3.5%.

specific Embodiment approach 3

[0020] Specific embodiment three: a one-step method for preparing an aluminum-based superhydrophobic surface described in specific embodiment two, the mass fraction of the perfluorotetradecanoic acid ethanol solution is 0.5%-3%.

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Abstract

The invention provides a method for preparing aluminum-based super-hydrophobic surface through a one-step method and belongs to the technical field of metal surface treatment. The method comprises thefollowing steps: preparing a sodium chloride water solution and a perfluorotetradecanoic acid ethanol solution; after mixing the two solutions, pouring the mixed solution into a hydrothermal reactionkettle; then vertically putting a pure aluminum sheet which is subjected to sand paper grinding and ultrasonic washing into the hydrothermal reaction kettle; after sealing, putting the hydrothermal reaction kettle into a constant-temperature box; after reacting for a period of time, taking out the aluminum sheet; and washing and drying to obtain the aluminum-based super-hydrophobic surface with amicro-nano structure. The method provided by the invention has the advantages of simple preparation and easiness for operation; the requirements on equipment are low, expensive equipment is not needed and experiment conditions are not harsh; large-area and low-cost preparation of the aluminum-based super-hydrophobic surface can be realized; the contact angle with water reaches 160 degrees and therolling angle is about 3 degrees; and the prepared aluminum-based super-hydrophobic surface has the characteristics of self cleaning, icing prevention, resistance reduction and the like.

Description

technical field [0001] The invention belongs to the technical field of metal surface treatment, and in particular relates to a method for preparing an aluminum-based superhydrophobic surface in one step. Background technique [0002] Surface wettability is a very important property of solid surface, which plays a very important role in industry, agricultural production and human's daily life. In the past ten years, inspired by the superhydrophobic properties of the surface of lotus leaves, people have carried out a lot of experimental explorations on the preparation and properties of superhydrophobic surfaces. Studies have shown that super-hydrophobic surfaces have excellent properties such as self-cleaning, anti-corrosion, drag reduction, anti-frosting, and antibacterial. , as well as water transport vehicles to reduce water resistance and reduce energy consumption have very broad application prospects. It is precisely because of these excellent properties of superhydroph...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C23C22/05C23C22/73
CPCC23C22/05C23C22/73
Inventor 张海峰刘晓为脱艳景陈伟平
Owner HARBIN INST OF TECH
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