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A kind of preparation method of self-catalytic functional nanometer quantum wire

A functional nanometer and quantum wire technology, applied in the fields of nanotechnology, nanotechnology, nanotechnology for materials and surface science, etc., can solve problems such as pollution, avoid impurity pollution, high purity, high and medium wave infrared light conversion efficiency and stability effects

Active Publication Date: 2020-02-14
JIANGHAN UNIVERSITY
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

Furthermore, InAsSb NWs with the entire Sb range were obtained by Au-catalyzed CBE, and although Au catalysts have demonstrated the ability to synthesize Sb-rich InAsSb NWs, it is believed that catalyst-induced impurity contamination leads to the degradation of the resulting NWs.

Method used

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  • A kind of preparation method of self-catalytic functional nanometer quantum wire
  • A kind of preparation method of self-catalytic functional nanometer quantum wire
  • A kind of preparation method of self-catalytic functional nanometer quantum wire

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Embodiment 1

[0031] The steps of the preparation method of the self-catalytic functional nanometer quantum wire are as follows:

[0032] Using liquid In to dissolve Sb at 0°C to obtain alloy droplets with a mass percentage of Sb of 1% for later use;

[0033] a. In MBE equipment, add In-Sb alloy droplets on the Si substrate in the growth chamber and activate at 200°C for 40 minutes to generate nucleation sites (the amount of In-Sb alloy droplets added per 1 cm 2 Si substrate corresponds to 4 mg), after the activation is completed, the growth chamber is kept at 150°C for 10 minutes;

[0034] b. Keep the growth chamber at 150°C, open the valves of the evaporation sources In, As, and Sb leading to the growth chamber and control the equivalent partial pressure ratio of each beam to grow nanowires. After 20 minutes of growth, close all the shutters of the evaporation sources at the same time to obtain InAsSb nanowires. Quantum wire; during growth, the equivalent partial pressure ratios of Sb, I...

Embodiment 2

[0037] Using liquid In to dissolve Sb at -5°C to obtain alloy droplets with a mass percentage of Sb of 2% for later use;

[0038] a. In MBE equipment, add In-Sb alloy droplets on the Si substrate in the growth chamber and activate at 250°C for 60 minutes to generate nucleation sites (the amount of In-Sb alloy droplets added per 1cm 2 Si substrate corresponds to 5 mg), after the activation is completed, the growth chamber is kept at 180°C for 15 minutes;

[0039] b. Insulate the growth chamber at 270°C, open the valves of the evaporation sources In, As and Sb leading to the growth chamber, and control the equivalent partial pressure ratio of each beam to grow nanowires. After 60 minutes of growth, close all the shutters of the evaporation sources at the same time to obtain InAsSb Nano quantum wire; during growth, the equivalent partial pressure ratios of Sb, In, and As beams are controlled to be 5%, 1%, and 94%, respectively, and the total pressure of the growth chamber is 0.1M...

Embodiment 3

[0042] The steps of the preparation method of the self-catalytic functional nanometer quantum wire are as follows:

[0043] Using liquid In to dissolve Sb at 10°C to obtain alloy droplets with a mass percentage of Sb of 3% for later use;

[0044] a. In MBE equipment, add In-Sb alloy droplets on the Si substrate in the growth chamber and activate at 300°C for 90 minutes to generate nucleation sites (the amount of In-Sb alloy droplets added per 1cm 2 Si substrate corresponds to 7 mg), after the activation is completed, the growth chamber is kept at 200 ° C for 20 min;

[0045] b. Insulate the growth chamber at 360°C, open the valves of the evaporation sources In, As, and Sb leading to the growth chamber and control the equivalent partial pressure ratio of each beam to grow nanowires. After 80 minutes of growth, close all the shutters of the evaporation sources at the same time to obtain InAsSb Nano quantum wire; control the equivalent partial pressure ratios of Sb, In, and As bea...

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Abstract

The invention discloses a method for preparing a self-catalyzed functional nanometer quantum wire, which is characterized in that the steps are: a. In MBE equipment, add In-Sb alloy droplets on the Si substrate of a growth chamber to activate and generate nucleation sites; b. Open the valves of the evaporation sources In, As and Sb leading to the growth chamber to grow the nanowires, and close all the evaporation sources at the same time after the growth is completed, to obtain InAsSb nanometer quantum wires. The creative use of droplet-assisted growth technology for activation to generate nucleation sites does not require the addition of expensive catalysts such as Au, thereby avoiding impurity pollution and making the prepared semiconductors high in purity; high-quality InAsSb nano-quantum wires are prepared, and the Sb growth As high as 16%, the obtained quantum wire has high mid-wave infrared light conversion efficiency and stability.

Description

technical field [0001] The invention relates to the technical field of nanometer materials, in particular to a method for preparing self-catalyzed functional nanometer quantum wires. Background technique [0002] InAsSb one-dimensional (1D) nanowires (NWs) have attracted considerable attention in the past few years due to the unique intrinsic properties of the alloy and the advantages of 1D nanostructures. On the one hand, alloys of InAsSb have tunable narrow bandgap energy, high thermal conductivity, small electronic effective mass, long carrier lifetime (~850 nanoseconds, and 3.0 microseconds at 250K, high electron mobility (at 300K Greater than >3×10 4 cm / Vs), and different mobility differences between electrons and holes. On the other hand, the unique 1D structure offers many benefits in device applications, such as enhanced light absorption, long carrier diffusion length, and enhanced carrier collection efficiency, etc. Furthermore, nanowires with complete and fac...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): B22F9/12B22F1/00H01L31/0304H01L31/0352B82Y40/00B82Y30/00
CPCH01L31/03046H01L31/035227B82Y30/00B82Y40/00B22F9/12B22F1/07B22F1/0547
Inventor 刘翠赵金星兰倩曹元成
Owner JIANGHAN UNIVERSITY