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Zymoid test paper used for detecting hydrogen peroxide and preparation method and application thereof

A technology of hydrogen peroxide and test paper, which can be applied to measurement devices, analysis by chemical reaction of materials, and material analysis by observing the impact on chemical indicators, which can solve the problems of interference color development, long preparation or measurement time, and test methods Cumbersome and other problems to achieve the effect of reducing usage and improving accuracy

Inactive Publication Date: 2018-04-17
WUHAN POLYTECHNIC UNIVERSITY
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0005] The purpose of the present invention is to solve the problems existing in the prior art, such as long preparation or measurement time, large errors, high requirements on the concentration of hydrogen peroxide, cumbersome test methods, unsuitability for detection of low-residual hydrogen peroxide, and excessive self-color interference with color development. And other issues

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0038] Detection of hydrogen peroxide (400mg / L) in aqueous solution: Cut the qualitative filter paper into strips with a width of 6mm and a length of 80mm. Take 10mg iron-based MIL-88NH 2 Disperse the enzyme-like catalyst into 10 mL of acetone, disperse ultrasonically, and continue to configure a 0.2 mg / mL 3,3',5,5'-tetramethylbenzidine in propanol solution as the developer solution. Take 50 μL of the catalyst dispersion and apply it on the cut test paper, dry it in a vacuum at 50°C, evenly spread 50 μL of the developer solution on the dry test paper, and dry it under vacuum at 50°C to obtain the prepared enzyme-like test paper. The loading amount of the obtained enzyme-like test paper iron-based MIL series metal organic framework material is 0.05 mg, and the loading amount of the color developer is 0.01 mg.

[0039] In order to detect different concentrations of hydrogen peroxide solution, first configure 100mg / L, 200mg / L, 400mg / L, 600mg / L, 800mg / L, 1000mg / L gradient concentrati...

Embodiment 2

[0041] Detection of hydrogen peroxide (20mg / mL) in aqueous solution: Cut the qualitative filter paper into strips with a width of 6mm and a length of 80mm. Disperse 30 mg of iron-based MIL-100 enzyme catalyst into 10 mL of acetone, disperse ultrasonically, and continue to configure a 2 mg / mL 3,3',5,5'-tetramethylbenzidine dimethyl sulfoxide solution as a display Toner solution. Take 50μL of catalyst dispersion and smear it on the cut test paper, dry it under vacuum at 40℃, evenly smear 50μL of the developer solution on the dry test paper, and dry it under vacuum at 40℃ to obtain the prepared enzyme-like test paper. The loading amount of the obtained enzyme-like test paper iron-based MIL series metal organic framework material is 0.15mg, and the loading amount of the color developer is 0.1mg.

[0042] In order to detect different concentrations of hydrogen peroxide solution, first configure 1mg / L, 5mg / L, 10mg / L, 30mg / L, 50mg / L, 100mg / L gradient concentration of hydrogen peroxide ...

Embodiment 3

[0044] Detection of hydrogen peroxide (4mg / L) in aqueous solution: Cut the qualitative filter paper into strips with a width of 6mm and a length of 80mm. Disperse 30 mg of iron-based MIL-101 type enzyme catalyst into 10 mL of acetone, disperse ultrasonically, and continue to configure a methanol solution of o-phenylenediamine with a concentration of 10 mg / mL as the developer solution. Take 50μL of catalyst dispersion and smear it on the cut test paper, dry it under vacuum at 40℃, evenly smear 50μL of the developer solution on the dry test paper, and dry it under vacuum at 40℃ to obtain the prepared enzyme-like test paper. The loading amount of the obtained enzyme-like test paper iron-based MIL series metal organic framework material is 0.15mg, and the loading amount of the color developer is 0.5mg.

[0045] In order to detect different concentrations of hydrogen peroxide solution, first configure 0.5mg / L, 2mg / L, 5mg / L, 10mg / L, 25mg / L gradient concentration of hydrogen peroxide so...

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Abstract

The invention discloses zymoid test paper used for detecting hydrogen peroxide and a preparation method and application thereof. The zymoid test paper is a piece of test paper carrying an iron-based MIL series metal organic framework material and a color developing agent. The preparation method comprises the following steps: (1) preparation of an iron-based MIL series metal organic framework material dispersion liquid; and (2) preparation of a color developing agent solution. The iron-based MIL series metal organic framework material adopted by the invention is commonly grey white to faint yellow, and relatively shallow color can reduce interference to color developing of the test paper, so that test accuracy can be improved. Test proves that the test paper prepared according to the technical scheme of the invention can develop color of hydrogen peroxide with concentration as low as 0.5mg / L.

Description

Technical field [0001] The invention belongs to the field of test materials, and more specifically, relates to an enzyme-like test paper for detecting hydrogen peroxide and a preparation method and application thereof. Background technique [0002] Hydrogen peroxide is the common name for hydrogen peroxide solution, and hydrogen peroxide is a green oxidant with excellent performance. Food grade hydrogen peroxide is widely used in food processing. For example, use hydrogen peroxide to bleach shark fins and pistachios, sterilize milk and milk products, sterilize drinking water, and can be used as a protein improver such as starch and milk. The standardized use of hydrogen peroxide can effectively increase the storage time of food. However, many illegal vendors add hydrogen peroxide to food in daily life. In order to improve the appearance of food, some small food processing plants often use high-concentration industrial-grade hydrogen peroxide to bleach food, leaving residues The...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): G01N21/78G01N21/77
CPCG01N21/78G01N21/77G01N2021/7759
Inventor 秦振华李建芬程群鹏闫俊涛兰奎史训旺
Owner WUHAN POLYTECHNIC UNIVERSITY