A kind of plant fungicide composition and preparation method thereof
A technology of plant fungicides and compositions, applied in botany equipment and methods, fungicides, plant growth regulators, etc., which can solve problems such as inability to disinfect tree holes and eubacterial infections
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[0028] The preparation method of described modified chitosan comprises the following steps:
[0029] (1) Diquaternary ammonium salt containing imidazole heterocycle: add epichlorohydrin to the reactor, heat up to 75°C, slowly add long-chain alkyl tertiary amine dropwise, after the dropwise addition, stir for 0.5h, cool down to 55°C, Add acetonitrile, then add 1-hydroxyethyl-2-methyl-5-nitroimidazole in 3 times, keep warm for 8 hours, cool down to room temperature, concentrate under reduced pressure to obtain a crude imidazole-containing heterocyclic bis-quaternary ammonium salt, add acetone Stir for 0.5h, concentrate under reduced pressure to obtain a heterocyclic diquaternary ammonium salt containing imidazole; The molar ratio of imidazole is 1:0.64:0.7; the weight ratio of the epichlorohydrin to the acetonitrile and the acetone is 1:6:4;
[0030] (2) Modified chitosan: add chitosan, mass fraction in reactor and be 2% acetic acid solution, stir 1h described chitosan and desc...
Embodiment 1
[0057] The plant fungicide composition comprises 10 parts of plant growth regulators, 60 parts of fungicides, 15 parts of insecticides, 90 parts of film-forming agents, 45 parts of nutrients, 0.2 parts of modified chitosan, and 100 parts of water; , the modified chitosan is a chitosan grafted bis-quaternary ammonium salt containing an imidazole heterocycle, and the raw materials for the preparation of the bis-quaternary ammonium salt containing an imidazole heterocycle include 1-hydroxyethyl-2-methyl- 5-nitroimidazole, epichlorohydrin, long-chain alkyl tertiary amine, and described long-chain alkyl tertiary amine is dodecylbenzylmethyl tertiary amine; Described plant growth regulator is indole acetic acid, benzyl Aminopurine, the weight ratio of the indole acetic acid and the benzylaminopurine is 1:1.2; the bactericide is berberine, chlorothalonil, and the weight ratio of the berberine and the chlorothalonil is 1:0.3; the insecticide is pyrethrin; the film-forming agent is pol...
Embodiment 2
[0067]The plant fungicide composition comprises 10 parts of plant growth regulators, 60 parts of fungicides, 15 parts of insecticides, 90 parts of film-forming agents, 45 parts of nutrients, 0.05 parts of modified chitosan, and 100 parts of water; , the modified chitosan is a chitosan grafted bis-quaternary ammonium salt containing an imidazole heterocycle, and the raw materials for the preparation of the bis-quaternary ammonium salt containing an imidazole heterocycle include 1-hydroxyethyl-2-methyl- 5-nitroimidazole, epichlorohydrin, long-chain alkyl tertiary amine, and described long-chain alkyl tertiary amine is dodecylbenzylmethyl tertiary amine; Described plant growth regulator is indole acetic acid, benzyl Aminopurine, the weight ratio of the indole acetic acid and the benzylaminopurine is 1:1.2; the bactericide is berberine, chlorothalonil, and the weight ratio of the berberine and the chlorothalonil is 1:0.3; the insecticide is pyrethrin; the film-forming agent is pol...
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