Preparation method of membrane electrode and fuel cell

A membrane electrode and electrode technology, applied in fuel cells, battery electrodes, circuits, etc., can solve the problems of reducing battery performance, not improving the phase interface of the catalytic layer in essence, and increasing the thickness of the membrane electrode itself, so as to achieve small thickness, The effect of reducing the mass transfer resistance of the phase interface and the simple preparation method

Active Publication Date: 2018-05-08
UNIV OF SCI & TECH OF CHINA
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Problems solved by technology

Although this method improves the adhesion of the catalytic layer on the anion exchange membrane, the increase of the transition layer does not substantially improve the phase interface problem in the catalytic layer, and the increase of the transition layer increases the thickness of the membrane electrode itself, which It has a negative effect on the conduction of ions and will reduce the performance of the battery

Method used

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  • Preparation method of membrane electrode and fuel cell
  • Preparation method of membrane electrode and fuel cell
  • Preparation method of membrane electrode and fuel cell

Examples

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Embodiment 1

[0037] Dissolve 1g of brominated polyphenylene ether in 20mL of isopropanol at room temperature, stir well to obtain a uniform solution, then add 0.9g of dimethylaminoethyl methacrylate, react for 48 hours, and obtain a uniform coating solution after complete reaction ; The coating solution is coated on a glass plate, and dried at 50° C. to obtain an anion exchange membrane. Cut the anion exchange membrane to a size of 25cm 2 .

[0038] Dissolve 0.5g of brominated polyphenylene ether in 10mL of isopropanol at room temperature, stir well to obtain a uniform solution, then add 0.45g of dimethylaminoethyl methacrylate, react for 48 hours, and precipitate in water after complete reaction Filter to obtain anion exchange resin.

[0039] Weigh 0.02g each of the 60%Pt / C catalyst and the 60%PtRu / C catalyst with a weight content of 0.02g, respectively add 1.05g of isopropanol as a solvent, ultrasonicate for 60min, and then add 5wt% of the alcoholic solution of the above-mentioned anio...

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Abstract

The present invention provides a preparation method of a membrane electrode. The method comprises the following steps: coating a catalyst paste on the two surfaces of an anion exchange membrane and then performing cross-linking treatment to obtain a basic film-coated electrode; placing the basic film-coated electrode between a cathode gas diffusion layer and an anode gas diffusion layer and then performing heat pressing to obtain the membrane electrode. The catalyst paste contains an anion exchange resin, and the anion exchange resin have groups capable of performing cross-linking, wherein thecomposition of the anion exchange resin is identical with the composition of the anion exchange membrane. According to the preparation method of the membrane electrode, the composition of the anion exchange membrane is identical with the composition of the anion exchange resin in a catalyst layer, and the anion exchange membrane and the anion exchange resin all have groups capable of performing cross-linking. A whole cross-linking type film-coated electrode is formed by performing cross-linking treatment on the anion exchange membrane and the catalyst layer, the prepared membrane electrode byusing a post cross-linking method has high mechanical strength, and the mass transfer resistance of OH<-> between the anode and cathode catalyst layers and the anion exchange membrane in the membraneelectrode is also reduced.

Description

technical field [0001] The invention relates to the technical field of batteries, in particular to a method for preparing a membrane electrode and a fuel cell. Background technique [0002] In recent years, energy crisis and environmental pollution have become a major problem facing mankind. Fuel cells have been extensively studied due to their advantages of no pollution and high energy efficiency, among which ion-exchange membrane fuel cells are the representative. In the previous decade, proton exchange membrane fuel cell (PEMFC) became the mainstream research object among ion exchange membrane fuel cells, which benefited from its high energy density. However, the ion-exchange membrane and noble metal catalyst used in proton exchange membrane fuel cell (PEMFC) are expensive, which greatly limits its application. [0003] Major anion exchange membrane fuel cells (AEMFC) have received great attention in recent years, and it is expected to become a substitute for proton exc...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): H01M4/88H01M8/1004
CPCH01M4/881H01M4/8828H01M4/8875H01M8/1004Y02E60/50
Inventor 吴亮梁铣徐铜文徐迈
Owner UNIV OF SCI & TECH OF CHINA
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