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Dry-method shock cooling removal and recovery method for arsenic in metallurgical gas

A technology of smelting flue gas and quenching, applied in separation methods, chemical instruments and methods, gas treatment, etc., can solve the problems of complex technology, generation of dirty acid, large investment in dirty acid treatment, etc., and achieve the effect of simple arsenic removal process

Active Publication Date: 2018-06-22
KUNMING UNIV OF SCI & TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The wet arsenic removal process is simple, but it will produce dirty acid, which requires large investment and complex technology

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0013] The outlet temperature of the waste heat boiler in a copper smelter is 400°C, and the arsenic content in the flue gas is 1200-1800 mg / m 3 , the dust concentration is 18-22 g / m 3 , the flue gas volume is 10000 m 3 / h; the flue gas is introduced into the high-temperature resistant ceramic filter dust collector, the outlet temperature after dust removal is 370°C, and the content of arsenic in the flue gas is 1200-1800 mg / m 3 , the dust concentration is 5-12 mg / m 3 ;The flue gas after dedusting enters from the bottom of the circulating fluidized bed, and the bottom of the fluidized bed is a funnel bin;

[0014] The fluidized bed particle medium is concrete particles, and the medium particles are continuously transported from the lower end of the circulating fluidized bed to the heat exchanger for cooling during the heat exchange process, and then added to the upper part of the circulating fluidized bed after cooling for flue gas cooling.

[0015] After the concrete parti...

Embodiment 2

[0017] The outlet temperature of waste heat boiler in a non-ferrous metal smelter is 380 ℃, and the content of arsenic in the flue gas is 2300-2500 mg / m 3 , the dust concentration is 20-25 g / m 3 , the flue gas volume is 8000 m 3 / h. The flue gas is introduced into the high-temperature resistant ceramic filter dust collector, the outlet temperature after dust removal is 365°C, and the content of arsenic in the flue gas is 2300-2500 mg / m 3 , the dust concentration is 10-15 mg / m 3 . The flue gas after dedusting enters from the bottom of the circulating fluidized bed, and the bottom of the fluidized bed is a funnel bin;

[0018] The granular medium of the fluidized bed is quartz sand. During the heat exchange process, the medium particles are continuously transported from the lower end of the circulating fluidized bed to the heat exchanger for cooling. After cooling, they are added to the upper part of the circulating fluidized bed for flue gas cooling.

[0019] After the qua...

Embodiment 3

[0021] The outlet temperature of waste heat boiler in a non-ferrous metal smelter is 380 ℃, and the content of arsenic in the flue gas is 1200-1500 mg / m 3 , the dust concentration is 18-30 g / m 3 , the flue gas volume is 15000 m 3 / h. The flue gas is introduced into the high-temperature resistant ceramic filter dust collector, the outlet temperature after dust removal is 370°C, and the arsenic content in the flue gas is 1200-1500 mg / m 3 , the dust concentration is 10-15 mg / m 3 . The flue gas after dedusting enters from the bottom of the circulating fluidized bed, and the bottom of the fluidized bed is a funnel bin.

[0022] The fluidized bed particle medium is alumina particles, and the medium particles are continuously transported from the lower end of the circulating fluidized bed to the heat exchanger for cooling during the heat exchange process, and then added to the upper part of the circulating fluidized bed after cooling for flue gas cooling.

[0023] After the flue...

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Abstract

The invention discloses a dry-method shock cooling removal and recovery method for arsenic in metallurgical gas. The dry-method shock cooling removal and recovery method comprises the steps: deeply removing dust in the metallurgical gas; making the dust-removed smoke enter from the lower part of a circulating fluidized bed; carrying out shock cooling on arsenious smoke by means of a granular medium in the circulating fluidized bed to make the smoke to be cooled to 120 DEG C or below within 1-3s; after cooling, making the smoke flow out of the top of the fluidized bed; collecting arsenic at thebottom of the fluidized bed; and further purifying or discharging the arsenic removed smoke, wherein the granular medium is delivered to a heat exchanger for cooling after being heated in a fluidizedbed shock cooling process and is delivered to the fluidized bed again after being cooled so as to be recycled. The method is simple in process, capable of realizing full-dry-method arsenic removal, in addition, arsenic removal and collection devices are integrated, and the granular medium for shock cooling arsenic removal is recycled.

Description

technical field [0001] The invention relates to a method of cooling arsenic-containing smelting flue gas by using solid matter to realize arsenic removal and arsenic collection by dry quenching, which belongs to the industrial waste gas pollution control technology. Background technique [0002] my country's non-ferrous metal smelting capacity and output rank first in the world. Non-ferrous metals are an important part of my country's national production. Among them, copper, gold, zinc and other non-ferrous metal minerals are associated with arsenic compounds, and the smelting flue gas produced during the smelting process contains high Arsenic, mainly in the form of diarsenic trioxide (white arsenic). On the one hand, the presence of arsenic in smelting flue gas has adverse effects on subsequent processes such as acid production and metal refining, and the existence of arsenic in flue gas is a serious problem for flue gas emission standards and pollution control. The removal...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): B01D53/00C22B7/02C22B30/04
CPCB01D53/00C22B7/02C22B30/04B01D2258/025B01D2258/0283Y02P10/20
Inventor 宁平瞿广飞马懿星田森林张秋林冯权莉孙鑫
Owner KUNMING UNIV OF SCI & TECH