A method for rapid passivation of soil cadmium based on the principle of complexation and redistribution of amino acids
A soil and complexation technology, applied in the restoration of contaminated soil, etc., can solve the problems of soil compaction and acidification, and the high cost of Cd-contaminated farmland soil, and achieve the effects of fast passivation speed, friendly environmental response, and simple method
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Embodiment 1
[0036] Glycine (structure such as figure 1 Shown, purchased from Aladdin Reagent Company) after being prepared as a glycine solution, added to the soil contaminated by Cd. The physical and chemical properties of the soil are listed in Table 1.
[0037] Table 1 Basic physical and chemical properties of the tested soil
[0038]
[0039] Investigate the rapid (3h) passivation of Cd in typical polluted farmland soil by adding amino acid.
[0040] Two treatments, CK (control) and TA (glycine), were respectively set up, and each treatment had 12 repetitions. Take by weighing the fresh soil for testing that is equivalent to air-dried soil weight 30g (the soil for testing is sampled from the plow layer soil with a thickness of 20cm), and put it into a 100mL polytetrafluoroethylene beaker. Match the concentration of glycine to 750mg N kg -1 Add soil, and use deionized water to adjust to 60% of the maximum field water holding capacity of the soil; the control treatment is to add ...
Embodiment 2
[0045] This example further investigates the passivation degree of glycine addition on Cd pollution in typical farmland soil.
[0046] Select 3 repetitions in the two treatment groups of CK (contrast) and TA (glycine) involved in Example 1, and carry out sampling and determination of effective Cd content at 6 and 12 hours after the start of the experiment respectively, and other operating steps are the same as in Example 1 .
[0047] The results are shown in Table 3 and figure 2 As shown, after adding glycine for 6 and 12 hours, CaCl 2 -Cd decreased by 16%, 27%, respectively.
[0048] The passivation effect of table 3 glycine to polluted soil after treatment
[0049] time (h) CaCl 2 -Cd (mg kg -1 )
Embodiment 3
[0051] This example further investigates the passivation degree of glycine addition involved in Example 2 on Cd pollution in typical farmland soil.
[0052] Three replicates of the two treatment groups CK (control) and TA (glycine) involved in Example 1 were selected, and samples were taken to determine the effective Cd content 24 and 48 hours after the start of the experiment, respectively.
[0053] The results are shown in Table 4. After adding glycine for 24 and 48 hours, CaCl 2 -Cd decreased by 30%, 65%, respectively.
[0054] The passivation effect of table 4 glycine to polluted soil after treatment
[0055] time (h) CaCl 2 -Cd (mg kg -1 )
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