A dry etching pretreatment method and copper pillar bumps prepared by the method
A pretreatment and dry engraving technology, used in semiconductor/solid-state device manufacturing, semiconductor/solid-state device components, semiconductor devices, etc., can solve problems such as high cost and long copper oxide cycle, and achieve zero damage, low cost, and wide range. The effect of the application foreground
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Embodiment 1
[0044] see figure 1 , the present invention provides a dry etching pretreatment method, comprising the following steps:
[0045] S1. Provide a chip with copper pillars, and there is a solder layer above the copper pillars;
[0046] S2, placing the chip in a vacuum reaction chamber, and performing dry etching pretreatment with an oxidizing gas, so that copper oxide is formed on the outer surface of the copper pillar;
[0047] S3. Reflowing the solder layer at high temperature to form solder bumps.
[0048] In the method of the present invention, before high-temperature reflow, a step of dry engraving pretreatment process is added to oxidize the side wall of the copper pillar, so as to prevent solder bumps from flowing after high-temperature reflow, and improve the reliability and stability of the chip.
[0049] As an example, the oxidizing gas is oxygen. Of course, it can also be other gases that can oxidize copper without affecting the process.
[0050] As an example, in t...
Embodiment 2
[0056] In this embodiment, the intervention method provided by the present invention includes the following steps:
[0057] (1) providing a chip with copper pillars, and there is a solder layer above the copper pillars;
[0058] (2) placing the chip in a vacuum reaction chamber, and performing dry etching pretreatment with an oxidizing gas mixed with an inert gas, so that copper oxide is formed on the outer surface of the copper pillar;
[0059] (3) reflowing the solder layer at high temperature to form solder bumps.
[0060] As an example, in the step (2), the inert gas is argon, that is, the mixed gas is argon and oxygen, oxygen is used for the copper oxide column, and argon will not affect the process, that is, copper The structure of each part of the stud bump will not undergo chemical reaction and zero etching.
[0061]It should be noted that the ratio of the argon and oxygen is arbitrary, and the flow rates of the argon and oxygen are not limited during the dry-burning...
Embodiment 3
[0064] The difference between this embodiment and embodiment 2 is that in the step (2) of the dry etching pretreatment method, the inert gas is preferably nitrogen, that is, the mixed gas is nitrogen and oxygen. The ratio of the nitrogen and oxygen is arbitrary, and during the dry-burning pretreatment process, the flow rates of the nitrogen and oxygen are the same or different.
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