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Preparation method of multi-component covering modified zinc oxide

A zinc oxide, multi-component technology, applied in the preparation of multi-component coated modified zinc oxide, in the field of rubber products such as tires, can solve the problems of affecting product performance, slow sublimation and volatilization, polluting the environment, etc., to achieve product stability High, no three waste discharge, long storage time

Inactive Publication Date: 2018-07-27
安徽固瑞特新材料科技有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, zinc oxide will slowly sublimate and volatilize above 90°C, polluting the environment and affecting product performance

Method used

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  • Preparation method of multi-component covering modified zinc oxide

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0050] 4kg solid content is 20% alkyd resin and 4kg solid content is 10% amino resin, 2kg solid content is 10% m-phenylenediamine m-PDA MPD to add in the mixing tank by metering tank, 5kg solid content is 10% % silica powder suspension was added to the mixing tank and mixed evenly for later use. Add 10kg of zinc oxide powder to the mixer in advance, then add the above mixed suspoemulsion into the zinc oxide powder and mix evenly. Use a kneader mixer to mix the above materials for 10 minutes, and then roll them through a double-roller rolling machine for 3 times. The distance between the rollers is adjusted in turn to 2.5mm for the first-stage rollers, 1.8mm for the second-stage rollers, and 1.3mm for the third-stage rollers. mm; After each rolling, carry out a break-up, and adjust the axis spacing in turn to adjust the axis spacing of the first level to 22mm, the second level to 19mm, and the third level to 15mm. After being dispersed, the mixed material is granulated by a sw...

Embodiment 2

[0052] Add 1 kg of acrylic resin with a solid content of 70% and 1 kg of amino resin with a solid content of 70% into the stirring tank through a metering tank, and add 4 kg of a silicon dioxide suspension with a solid content of 50% into the stirring tank and mix evenly for use. Add 10kg of zinc oxide powder to the mixer in advance, then add the above mixed suspoemulsion into the zinc oxide powder and mix evenly. Use a coulter mixer to mix the above materials for 30 minutes, and then roll them 5 times with a double-roller roller. The distance between the rollers is adjusted in turn to 2mm for the first-stage rollers, 1.5mm for the second-stage rollers, and 1.9mm for the third-stage rollers. , the distance between the 4th grade rollers is 0.8mm, and the 5th grade roller distance is 0.5mm; after each rolling, a dispersal is carried out, and the axial distance is adjusted in turn. The distance between the shattering axes of the first stage is 13mm, the distance between the shatt...

Embodiment 3

[0054] 3 kg of hydroxyacrylic resin with a solid content of 40% and 2.5 kg of amino resin with a solid content of 40% are added to the stirring tank through a metering tank, and 5 kg of a calcium carbonate suspension with a solid content of 20% is added to the stirring tank and mixed uniformly for use. Add 10kg of zinc oxide powder to the mixer in advance, then add the above mixed suspoemulsion into the zinc oxide powder and mix evenly. Use a ribbon mixer to mix the above materials for 20 minutes, and then roll them 7 times with a three-roller roller. The roller spacing is adjusted in turn to 2mm for the first-stage rollers, 1.5mm for the second-stage rollers, and 1.9mm for the third-stage rollers. mm, the distance between the rollers of grade 4 is 0.8mm, the distance between the rollers of grade 5 is 0.5mm, the distance between the rollers of grade 6 is 0.2mm, and the distance between the rollers of grade 7 is 0.1mm; after each rolling, it is broken up once, and the distance b...

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Abstract

The invention relates to a preparation method of multi-component covering modified zinc oxide. The preparation method comprises the steps as follows: multiple film-forming agents are added to a stirring tank through a metering tank, an inorganic powder material is added to the stirring tank, and the mixture is uniformly mixed for later use; zinc oxide is added to a mixer in advance, the mixed suspension is added to zinc oxide in proportion to be mixed uniformly; the materials are mixed by the mixer, the mixed material is rolled by a roller and scattered by a scattering machine, the scattered mixed material is granulated by a swing granulator, wet granules are sent to a drying machine to be dried, the dried product is crushed by a crusher, cooled, sieved and packaged, and a finished productis obtained. The method is simple in equipment requirement, low in cost, high in safety, quick and efficient in preparation process, environmentally friendly and pollution-free, due to the covering zinc oxide, the total content of zinc oxide in a formula can be reduced effectively, the over-vulcanization of rubber products can be reduced, the processing safety can be improved, and the method hasbetter economic benefits.

Description

technical field [0001] The invention relates to a preparation method of multi-component coated modified zinc oxide, which belongs to the field of chemical products and is mainly used in industries such as rubber products such as tires. Background technique [0002] Zinc oxide is mainly used as an activator for natural rubber and synthetic rubber. The particles are small and spherical, with a large surface area, good dispersibility and good adsorption, so it can promote the vulcanization, activation and reinforcement anti-aging of rubber. It can strengthen the vulcanization process, achieve stable physical properties, improve processing safety, greatly reduce the defective rate, and improve the tear resistance and wear resistance of rubber products. However, zinc oxide will slowly sublimate and volatilize above 90°C, polluting the environment and affecting product performance. [0003] With the development of the international rubber industry, green tires have become an inev...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08K9/10C08K3/22C08L9/06
CPCC08K9/10C08K3/22C08K2003/2296C08L9/06
Inventor 邵进邵彬彬沈家锋
Owner 安徽固瑞特新材料科技有限公司