Adhesive composition and structure
A composition and adhesive technology, applied in the direction of adhesives, conductive adhesives, structural connections of printed circuits, etc., can solve the problems of low activation energy, difficulty in storage stability near normal temperature, etc. The effect of reducing and excellent storage stability
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[0112] Hereinafter, the present invention will be described more specifically with reference to Examples and Comparative Examples. However, the present invention is not limited to the following examples.
[0113] (synthesis of polyurethane)
[0114] In a separable flask equipped with a reflux cooler, a thermometer, and a stirrer, 1000 parts by mass of polypropylene glycol (manufactured by Wako Pure Chemical Industries, Ltd., number-average molecular weight Mn=2000) and 4000 parts by mass of After methyl ethyl ketone (solvent), it stirred at 40 degreeC for 30 minutes, and prepared the reaction liquid. After raising the temperature of the reaction liquid to 70°C, 0.0127 parts by mass of dimethyltin laurate (catalyst) was added. Next, to this reaction liquid, a solution prepared by dissolving 125 parts by mass of 4,4'-diphenylmethane diisocyanate in 125 parts by mass of methyl ethyl ketone was added dropwise over 1 hour. Then, the stirring was continued at the above temperatur...
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