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Waterborne binder and food-contact waterborne printing ink prepared by using waterborne binder

A technology of water-based ink and binder, which is applied in the ink field to achieve the effects of increasing the polymerization reaction rate, increasing the initiation efficiency, and increasing the contact area

Active Publication Date: 2018-08-17
GUANGDONG YINGKE GRP CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0006] The third object of the present invention is to provide a food-contact water-based ink, which has no organic solvent residue, is non-toxic to the human body, is more environmentally friendly, and solves the problem that existing water-based inks on the market have adverse effects on consumers' health.

Method used

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  • Waterborne binder and food-contact waterborne printing ink prepared by using waterborne binder
  • Waterborne binder and food-contact waterborne printing ink prepared by using waterborne binder
  • Waterborne binder and food-contact waterborne printing ink prepared by using waterborne binder

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0048] A water-based binder, comprising the following raw materials in parts by weight:

[0049]

[0050] Each part of the emulsifying monomer is prepared by the following method: stirring 20 parts of acrylic monomer, 50 parts of styrene monomer, 0.5 part of emulsifier, and 20 parts of water at a temperature of 30°C to obtain the emulsifying monomer.

[0051] Each part of the modified rosin is prepared from the following steps:

[0052] (1) Heat 50 parts of rosin to 180°C, then add 15 parts of maleic anhydride, and react at 180°C for 2 hours to obtain System A;

[0053] (2) Raise the temperature of System A to 200°C, then dropwise add 20 parts of monomers containing double bonds and hydroxyl groups, 20 parts of monomers containing double bonds and amino groups, 0.5 parts of polymerization inhibitor and 0.5 parts of zinc oxide, and then raise the temperature to 220°C Insulate for 1 hour to obtain system B;

[0054] (3) Raise the temperature of system B to 270° C., add 10 p...

Embodiment 2

[0072] A water-based binder, comprising the following raw materials in parts by weight:

[0073]

[0074] Each part of the emulsifying monomer was prepared by the following method: stirring 70 parts of styrene monomer, 5 parts of emulsifier, and 30 parts of water at 45° C. to obtain the emulsifying monomer.

[0075] Each part of the modified rosin is prepared from the following steps:

[0076] (1) Heat 60 parts of rosin to 190°C, then add 20 parts of maleic anhydride, and react at 190°C for 3 hours to obtain System A;

[0077] (2) Raise the temperature of system A to 210°C, then dropwise add 25 parts of monomers containing double bonds and hydroxyl groups, 5 parts of polymerization inhibitors and 5 parts of zinc oxide, and then raise the temperature to 240°C for 2 hours to obtain system B;

[0078] (3) Raise the temperature of system B to 285°C, add 15 parts of polyols, then cool down to 180°C and discharge to obtain the modified rosin.

[0079] The monomer containing dou...

Embodiment 3

[0097] A water-based binder, comprising the following raw materials in parts by weight:

[0098]

[0099] Each part of the emulsifying monomer is prepared by the following method: 20 parts of acrylic monomer, 70 parts of styrene monomer, 4 parts of emulsifier, and 25 parts of water are stirred at a temperature of 40° C. to obtain the emulsifying monomer.

[0100] Each part of the modified rosin is prepared from the following steps:

[0101] (1) Heat 55 parts of rosin to 185°C, then add 18 parts of maleic anhydride, and react at 185°C for 2.5 hours to obtain System A;

[0102] (2) Raise the temperature of system A to 210°C, then dropwise add 23 parts of monomers containing double bonds and amino groups, 4 parts of polymerization inhibitors, and 4 parts of zinc oxide, and then raise the temperature to 230°C for 1.5 hours to obtain system B;

[0103] (3) Raise the temperature of system B to 275°C, add 12 parts of polyol, then cool down to 175°C and discharge to obtain the mod...

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Abstract

The invention relates to the technical field of printing ink, and particularly relates to a waterborne binder and food-contact waterborne printing ink prepared by using the waterborne binder. The waterborne binder comprises the following raw materials in parts by weight: 15-20 parts of modified rosin, 5-15 parts of starch, 0.5-5 parts of emulsifying monomers, 0.5-5 parts of an initiator, 0.1-2 parts of a pH regulator and 40-60 parts of water, wherein each part of the emulsifying monomers is prepared by the following method: stirring 70-90 parts of acrylic monomers and / or styrene monomers, 0.5-5 parts of an emulsifier and 20-30 parts of water at a temperature of 30-45 DEG C to obtain the emulsifying monomers. According to the waterborne binder, the harm of the use of organic solvents to thehealth of human bodies is avoided, and compared with the existing waterborne acrylic resin, the waterborne binder is more environmentally friendly and is harmless to the human bodies.

Description

technical field [0001] The invention relates to the technical field of inks, in particular to a water-based binder and a food-contact water-based ink prepared by using the same. Background technique [0002] Water-based ink is called ink for short. It is mainly made of water-soluble resin, organic pigment, solvent and related additives through compound grinding. Packaging and printing products. [0003] However, most of the water-based inks used in packaging and printing products currently use water-based acrylic resins as binders, and most of the inks currently used in my country contain petroleum distillates, benzene and its derivatives, or toxic and corrosive ketones, etc. Organic solvents, in the production process, have caused harm to the health of workers. If they are used as food packaging inks and are in direct contact with food, the migration and penetration of small molecular organics will have a negative impact on the health of consumers, especially for Children a...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C09D11/08C09D11/14C09D11/033
CPCC09D11/033C09D11/08C09D11/14
Inventor 刘润林连坤鹏金伟师
Owner GUANGDONG YINGKE GRP CO LTD
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