Active polyacrylate copolymer based pour point depressant for crude oil with high solidifying point and preparation method of pour point depressant
A technology of polyacrylate and crude oil pour point depressant, applied in chemical instruments and methods, drilling composition and other directions, can solve the problems of large difference in performance of high pour point crude oil, different pour point depressant effects, etc.
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Embodiment 1
[0012] Add 15 grams of octadecyl acrylate and 30 grams of xylene to a four-necked flask equipped with a thermometer, a stirrer and a condenser, and dissolve the octadecyl acrylate below 70°C, followed by adding 0.94 grams of glycidyl methacrylate, Mix 0.65 grams of maleic anhydride and 0.57 grams of vinyl acetate, add 0.34 grams of azobisisobutyronitrile, then feed nitrogen into the reaction system, and open condensed water, raise the temperature to 95 ° C, and keep the temperature for 6 hours. The solution was cooled to room temperature, an appropriate amount of methanol was added, filtered, and the filter cake was vacuum-dried at 50°C to obtain the pour point depressant 1 for high pour point crude oil.
Embodiment 2
[0014] Add 15 grams of octadecyl acrylate and 30 grams of xylene to a four-necked flask equipped with a thermometer, a stirrer and a condenser, and dissolve the octadecyl acrylate below 70°C, followed by adding 1.88 grams of glycidyl methacrylate, 0.57 g of vinyl acetate, mixed evenly, added 0.523 g of dibenzoyl peroxide, then passed nitrogen into the reaction system, and opened condensed water, raised the temperature to 90 ° C, kept the reaction for 6 hours, cooled the reaction solution to room temperature, added Appropriate amount of methanol was filtered, and the filter cake was vacuum-dried at 50°C to obtain the pour point depressant 2 for high pour point crude oil.
Embodiment 3
[0016] Add 15 grams of octadecyl acrylate and 30 grams of xylene to a four-necked flask equipped with a thermometer, a stirrer and a condenser, and dissolve the octadecyl acrylate below 70°C, followed by adding 1.41 grams of glycidyl methacrylate, 0.97 grams of maleic anhydride, mixed evenly, added 0.35 grams of azobisisobutyronitrile, then passed nitrogen into the reaction system, and opened condensed water, raised the temperature to 95 ° C, kept the reaction for 6 hours, cooled the reaction solution to room temperature, added Take an appropriate amount of methanol, filter, and vacuum-dry the filter cake at 50°C to obtain the pour point depressant 3 for high pour point crude oil.
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