Heat-resistant and flame-resistant PVC (Polyvinyl Chloride) injection molding material

A technology of injection molding and PVC resin, applied in the field of PVC materials, can solve the problems of poor flame retardancy, prone to dripping, dripping ignition, etc., to avoid the decline of heat resistance and flame retardancy, good heat resistance and flame retardancy, The effect of excellent injection molding performance

Inactive Publication Date: 2018-10-26
ZHEJIANG WELLSCOM PLASTIC CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0005] In order to solve the existing technology, the cable industry usually uses PVC as the insulating pipe on the outside of the cable, but due to the own shortcomings of PVC resin, its flame retardancy is poor, and it will release a large amount of hydrogen chloride gas when burning on the flame, hydrogen chloride gas It has certain toxicity and corrosiveness, and it will automatically extinguish due to its "self-extinguishing" after it leaves the flame, but it is still prone to dripping, causing dripping and ignition. It is also very easy to decompose in a high temperature environment, causing discoloration and releasing toxic hydrogen chloride gas at the same time. As the temperature rises, the speed of its decomposition and release of hydrogen chloride gas will be further accelerated, and it will inevitably be used as an insulating pipe on the outside of the cable for a long time. Working under conditions, and there is a certain probability of being exposed to open flames, so ordinary PVC materials are difficult to meet the needs of the existing industry. The invention provides a heat-resistant and flame-retardant PVC injection molding

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0030] A kind of heat-resistant and flame-retardant PVC injection molding material, its preparation raw material includes the following substances in parts by weight:

[0031] 100 parts by weight of PVC resin, 25 parts by weight of epoxy modified silicone resin, 15 parts by weight of corundum powder, 15 parts by weight of composite filler, 10 parts by weight of dioctyl phthalate, 7 parts by weight of stearic acid, 5:1 : 5 parts by weight of tribasic lead sulfate, dibasic lead phosphite and dibasic lead stearate in 2 mass ratios, 2 parts by weight of EMI resin and 15 parts by weight of oxidized polyvinyl alcohol.

[0032] Wherein the composite filler is a modified silica filler, and the modified silica filler is prepared by the following method:

[0033] 1) placing the nanometer mesoporous silica in 3 times the weight of tetrahydrofuran for ultrasonic oscillation, the ultrasonic oscillation power is 70kW, and the time is 10min, to obtain a suspension;

[0034]2) Add 0.2 times ...

Embodiment 2

[0036] A kind of heat-resistant and flame-retardant PVC injection molding material, its preparation raw material includes the following substances in parts by weight:

[0037] 120 parts by weight of PVC resin, 35 parts by weight of epoxy-modified silicone resin, 40 parts by weight of corundum powder, 35 parts by weight of composite filler, 1:1 mass ratio of dioctyl phthalate and dioctyl terephthalate 15 parts by weight, 12 parts by weight of sodium stearate, 12 parts by weight of isooctyl dithioglycolate di-n-octyltin, 6 parts by weight of EMI resin and 22 parts by weight of oxidized polyvinyl alcohol.

[0038] Wherein the composite filler is a modified silica filler, and the modified silica filler is prepared by the following method:

[0039] 1) placing the nano-mesoporous silica in 5 times the weight of THF for ultrasonic oscillation, the ultrasonic oscillation power is 85kW, and the time is 15min, to obtain a suspension;

[0040] 2) Add 0.5 times by weight of nano-mesoporo...

Embodiment 3

[0042] A kind of heat-resistant and flame-retardant PVC injection molding material, its preparation raw material includes the following substances in parts by weight:

[0043] 110 parts by weight of PVC resin, 28 parts by weight of epoxy modified silicone resin, 28 parts by weight of corundum powder, 23 parts by weight of composite filler, 11 parts by weight of dioctyl phthalate, 9 parts by weight of barium stearate, dimethyl 7 parts by weight of isooctyl tin dimercaptoacetate, 3 parts by weight of EMI resin and 18 parts by weight of oxidized polyvinyl alcohol.

[0044] Wherein the composite filler is a modified silica filler, and the modified silica filler is prepared by the following method:

[0045] 1) placing the nanometer mesoporous silica in 3 times the weight of tetrahydrofuran for ultrasonic oscillation, the ultrasonic oscillation power is 75kW, and the time is 15min, to obtain a suspension;

[0046] 2) Add 0.5 times by weight of nano-mesoporous silica as an organic f...

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PUM

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Abstract

The invention relates to the field of PVC (Polyvinyl Chloride) materials, in particular to a heat-resistant and flame-resistant PVC injection molding material. The heat-resistant and flame-resistant PVC injection molding material is prepared from the following raw materials in parts by weight: 100 to 120 parts of PVC resin, 25 to 35 parts of epoxy modified organosilicone resin, 15 to 40 parts of alundum powder, 15 to 35 parts of composite filler, 10 to 15 parts of plasticizer, 7 to 12 parts of lubricant, 5 to 12 parts of thermal stabilizer, 2 to 6 parts of flow modifier and 15 to 22 parts of oxidized polyvinyl alcohol.

Description

technical field [0001] The invention relates to the field of PVC materials, in particular to a heat-resistant and flame-retardant PVC injection compound. Background technique [0002] In the prior art, the cable industry usually uses PVC as the insulating pipe on the outside of the cable. However, due to the disadvantages of PVC resin itself, its flame retardancy is poor, and it will release a large amount of hydrogen chloride gas when it burns on the flame. Hydrogen chloride gas has a certain Due to its "self-extinguishing" property, it will automatically extinguish after it leaves the flame, but it is still prone to dripping, causing dripping and ignition. It is also very easy to decompose in the environment, produce discoloration and release toxic hydrogen chloride gas at the same time, and the speed of its decomposition and release of hydrogen chloride gas will be further accelerated as the temperature rises. When used as an insulating pipe on the outside of the cable, i...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L27/06C08L83/04C08L29/04C08L25/12C08K13/06C08K3/22C08K9/06C08K7/26C08K5/12
CPCC08L27/06C08K2003/2227C08K2201/011C08L2201/02C08L2201/08C08L2205/035C08L83/04C08L29/04C08L25/12C08K13/06C08K3/22C08K9/06C08K9/08C08K7/26C08K5/12
Inventor 赵亚琼
Owner ZHEJIANG WELLSCOM PLASTIC CO LTD
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