Methanol diesel oil and preparation method thereof

A diesel and methanol technology, applied in the petroleum industry, fuel and other directions, can solve the problems of poor ignition, easy to knock, easy to block the oil filter, etc., to achieve the effect of improving ignition performance, not easy to knock, and enhancing stability

Inactive Publication Date: 2018-11-30
桂林茂兴新能源科技有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Due to the huge difference in the polarity and physical and chemical properties of methanol and diesel, methanol diesel has the following disadvantages: 1. Methanol is very polar, and its affinity with water is more than 100 times that of diesel, so methanol diesel is very water resistant. Poor, the allowable moisture content is only 0.5%, and the methanol and diesel will separate after water; 2. The closed flash point of methanol is much lower than that of diesel, only 11-12 ° C, so the flash point of methanol-diesel blended fuel is low; 3. The cetane number of methanol is only 3 to 5, which leads to poor cetane number of methanol diesel, poor ignition, unstable engine operation, and prone to knocking; 4. Methanol diesel belongs to the microemulsion system and becomes emulsion when it meets water , the droplet particles are larger, the oil filter is easy to be blocked due to the liquid resistance effect, and the emulsion formed after encountering water is left for a long time, and the methanol and diesel oil will be stratified, and the water resistance is poor.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0019] Formula: commercial diesel 60%, industrial methanol (99%) 30%, water 5%, modifier 4.97%, KBr 0.03%;

[0020] The modifier consists of the following raw materials in parts by weight: 5 parts of methyl tert-butyl ether, 1 part of isobutanol, 5 parts of isoamyl nitrate, 5 parts of diethylene glycol dialkyl ether, 1 part iron, 1 part oleic acid.

[0021] The preparation method is as follows: mix the diesel oil, methanol, water, modifying agent and KBr in the formulated quantity, and vibrate under 1KHz ultrasonic wave for 3s to obtain the product.

[0022] The methanol diesel has a flash point of 47°C, a cetane number of 56, a density of 0.85g / m3 (20°C), and can be stored stably at -20°C to 40°C for one year without delamination.

Embodiment 2

[0024] Formula: commercial diesel 85%, industrial methanol (99%) 5%, water 1%, modifier 8.99%, KBr 0.01%;

[0025] The modifier consists of the following raw materials in parts by weight: 10 parts of methyl tert-butyl ether, 20 parts of isobutanol, 15 parts of isoamyl nitrate, 10 parts of diethylene glycol dialkyl ether, 5 parts of iron, 5 parts of oleic acid.

[0026] The preparation method is as follows: mix the diesel oil, methanol, water, modifier and KBr in the formulated quantity, and vibrate under 10KHz ultrasonic waves for 10s to obtain the product.

[0027] The methanol diesel has a flash point of 52°C, a cetane number of 60, a density of 0.86g / m3 (20°C), and can be stored stably at -20°C to 40°C for one year without delamination.

Embodiment 3

[0029] Formula: commercial diesel 75%, industrial methanol (99%) 20%, water 3.985%, modifier 1%, KBr 0.015%;

[0030] The modifier consists of the following raw materials in parts by weight: 8 parts of methyl tert-butyl ether, 15 parts of isobutanol, 10 parts of isoamyl nitrate, 8 parts of diethylene glycol dialkyl ether, 3 parts of iron, 2 parts of oleic acid.

[0031] The preparation method is as follows: mix the diesel oil, methanol, water, modifier and KBr in the formulated amount, and vibrate under 5KHz ultrasonic waves for 5s to obtain the product.

[0032] The methanol diesel has a flash point of 49°C, a cetane number of 59, a density of 0.86g / m3 (20°C), and can be stored stably at -20°C to 40°C for one year without delamination.

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Abstract

The invention provides methanol diesel oil, which is prepared from the following ingredients in percentage by weight: 60 to 85 percent of diesel oil, 5 to 30 percent of methyl alcohol, 1 to 5 percentof water, 1 to 10 percent of modifying agents and 0.01 to 0.03 percent of KBr. According to a preparation method, the diesel, the methyl alcohol, the water, the modifying agents and the KBr accordingto the recipe quantity are uniformly mixed; the materials are put under the ultrasonic waves being 1 to 10kHz to be vibrated for 3 to 10s to obtain a finished product. The prepared methanol diesel oilhas the advantages that the storage stability is high; the water resistant capability is high; the flash point is high; the cetane number is high; the low-temperature starting performance is good.

Description

technical field [0001] The invention belongs to the field of fuel technology, and in particular relates to methanol diesel and a preparation method thereof. Background technique [0002] With the rapid development of the global economy, the demand for oil in countries around the world is increasing day by day, but oil is a non-renewable energy source, and the world's oil reserves are decreasing year by year. The shortage of oil has become a long-term pressure restricting the development of the world economy. At present, the main purpose of petroleum is to produce gasoline and diesel for use in internal combustion engines. However, due to the low combustion efficiency of internal combustion engines, a large amount of fine dust containing carbon-containing substances in the exhaust gas is suspended in the air, resulting in serious environmental pollution. Sulfur dioxide produced after combustion , polycyclic benzene carcinogens have caused great harm to human health. [0003]...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C10L1/02
CPCC10L1/02C10L2230/22
Inventor 谭政刘亭君文志峰陆秀华罗丹汝侯昭君
Owner 桂林茂兴新能源科技有限公司
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