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Method and device for strengthening treatment of cobalt-free diamond composite sheet

A technology of diamond composite sheet and strengthening treatment, which is applied in the direction of metal material coating process, coating, solid-state diffusion coating, etc. Problems such as the strength of the diamond composite sheet, achieve chemical stability and thermal stability, improve heat treatment efficiency, and increase practicability

Active Publication Date: 2020-06-02
BEIJING GANG YAN DIAMOND PROD CO +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Since the diamond layer and the cemented carbide layer, the diamond in the diamond layer and the binder cobalt have great differences in physical properties such as elastic modulus and expansion coefficient, the presence of cobalt in the diamond layer will cause the diamond composite sheet In the process of high temperature synthesis, a large thermal residual stress will be generated, and the heat generated during use will also increase the thermal stress, which will affect the thermal stability of the diamond compact, so that the diamond compact is used for drilling on the drill bit. When the strength and heat resistance are reduced, the composite sheet tool is easy to chip and become blunt when cutting, and the composite sheet drill bit collapses and fails, and the service life is reduced
[0005] In order to improve the impact resistance and heat resistance of the diamond composite sheet, many manufacturers remove cobalt from the diamond layer binder. Although the heat resistance and wear resistance of the diamond composite sheet can be improved after cobalt removal, the residual cobalt in the diamond layer Voids will reduce the strength of the diamond compact, thereby affecting its impact resistance

Method used

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  • Method and device for strengthening treatment of cobalt-free diamond composite sheet
  • Method and device for strengthening treatment of cobalt-free diamond composite sheet
  • Method and device for strengthening treatment of cobalt-free diamond composite sheet

Examples

Experimental program
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Effect test

Embodiment 11

[0075] The diamond composite sheet sample used in this example is a product produced by Antai Steel Research Institute, the brand name is AGT1613×2.0-SU (for oil drilling), the cobalt removal depth of the diamond layer is 1 mm, and the quantity is 20 pieces.

[0076] The specific reinforcement processing methods are as follows:

[0077] Step 1. Clean 20 pieces of ATG1613*2.0-SU diamond composite chips after decobaltization and place them in a high-temperature resistant crucible, and place them in a vacuum heat treatment furnace. Embed the diamond layer in metal titanium powder. Use metal titanium The purity of the powder is ≥99.99%, the particle size is 1000 mesh, and the thickness of the titanium powder covering layer is about 1-2mm.

[0078] Step 2, first evacuate until the pressure in the furnace reaches 5×10 -3 Below Pa, start heating and continue vacuuming, raise the temperature in the furnace to 130°C and keep it for 0.5 hours, then continue heating for 2 hours, finally...

Embodiment 12

[0083] In this example, the same diamond composite sheet sample as in Example 1.1 is used as a product produced by Antai Iron and Steel Research Institute.

[0084] Specifically, in the strengthening treatment method, the final heat preservation temperature is kept at 735°C, and the rest of the process methods are exactly the same. After ATG1613×2.0-SU is carburized and strengthened at 735°C, the average value of the test impact toughness is 360J, and the heat resistance temperature is ≥ 785°C, and the wear ratio is about 350,000.

[0085] Before the strengthening treatment, the average impact toughness of ATG1613×2.0-SU test of the cobalt-removed composite sheet was 305J, the heat-resistant temperature was 750°C, and the wear ratio was 300,000.

[0086] Compared with the cobalt-removed composite sheet ATG1613×2.0-SU before strengthening treatment, its impact toughness value has increased by 18%, the heat-resistant temperature has increased by 35°C, and the wear ratio has incr...

Embodiment 21

[0088] The diamond composite sheet sample is purchased from a domestic manufacturer, the brand is PDC1613-ZGA (for oil drilling), the cobalt removal depth of the diamond layer is 1mm, and the quantity is 10 pieces.

[0089] The specific reinforcement processing methods are as follows:

[0090] Step 1. Clean 10 pieces of PDC1613-ZGA decobaltized diamond composite sheets and place them in a high-temperature-resistant crucible, and place them in a vacuum heat treatment furnace. Embed the diamond layer in metal titanium powder. It is ≥99.99%, the particle size is 1000 mesh, and the thickness of the titanium powder covering layer is about 1-2mm.

[0091] Step 2, first evacuate until the pressure in the furnace reaches 5×10- 3 Below Pa, start heating and continue vacuuming, raise the temperature in the furnace to 140°C and keep it for 0.5 hours, then continue heating for 2 hours, finally keep the temperature in the furnace at 730°C, and the pressure in the furnace is stable at 8×10...

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Abstract

The invention provides a strengthening treatment method and device for a cobalt-removed diamond composite sheet. The strengthening treatment method is used for performing vacuum titanizing on a diamond layer of the cobalt-removed diamond composite sheet. The strengthening treatment method can effectively prevent impact resistance of the cobalt-removed diamond composite sheet from reducing, effectively improves heat stability, and prolongs the service life of the diamond composite sheet.

Description

technical field [0001] The invention belongs to the technical field of superhard composite materials, and in particular relates to a strengthening treatment method and device for a cobalt-free diamond composite sheet. Background technique [0002] Superhard composite materials refer to the composite of hard alloys such as diamond and cubic boron nitride and other matrix materials, which not only have the hardness and wear resistance of superhard materials, but also have the function of matrix materials. [0003] Diamond composite sheet is made by attaching diamond micropowder and binder to the cemented carbide substrate and synthesized by high temperature and high pressure. It not only has extremely high hardness and wear resistance, but also has the impact resistance and welding performance of cemented carbide, and is widely used. In the field of mechanical cutting tools, petroleum and geological drill bits. [0004] In the diamond layer of the diamond composite sheet, the...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C23C10/36
CPCC23C10/36
Inventor 孙延龙刘一波尹翔徐燕军
Owner BEIJING GANG YAN DIAMOND PROD CO