Preparing method of TiAl inter-metallic compound containing rare earth element Er

An intermetallic compound and rare earth element technology, which is applied in the field of preparation of TiAl intermetallic compounds, can solve the problems of reducing the room temperature plasticity of directionally solidified TiAl-based alloys and the room temperature plasticity of directionally solidified TiAl-based alloys, and achieves the effect of improving room temperature plasticity.

Active Publication Date: 2018-12-18
HARBIN INST OF TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Obtaining TiAl-based alloy columnar grain structure by directional solidification method, and making TiAl-based alloy obtain a microscopic lamellar structure parallel to the growth direction or at an angle of 45° can improve the performance of TiAl-based alloys, but due to raw materials and smelting process Because of the reason, a considerable amount of oxygen element will inevitably be introduced into the directionally solidified TiAl-based alloy matrix
These oxygen atoms dissolved in the alloy matrix will significantly reduce the room temperature plasticity of directionally solidified TiAl-based alloys
In addition, the coarse lamellar structure will also lead to the decrease of room temperature plasticity of directionally solidified TiAl-based alloys.

Method used

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  • Preparing method of TiAl inter-metallic compound containing rare earth element Er
  • Preparing method of TiAl inter-metallic compound containing rare earth element Er
  • Preparing method of TiAl inter-metallic compound containing rare earth element Er

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specific Embodiment approach 1

[0023] Specific Embodiment 1: This embodiment provides a method for preparing TiAl intermetallic compounds containing rare earth element Er. The method is carried out on a multi-functional cold crucible electromagnetically confined precise forming directional solidification equipment, and simultaneously realizes purification and refinement orientation Solidified TiAl-based alloy structure. Specific steps are as follows:

[0024] Step 1: Prepare a Ti-47Al-2Nb-2Cr-0.2Er alloy ingot with a rare earth element Er content of 0.2 at.% by vacuum induction melting. The specific operation is as follows: (1) Weigh titanium sponge, aluminum block, aluminum Niobium master alloy, chromium sheet and aluminum erbium master alloy, of which Ti-48.8 at.%, Al-47 at.%, Nb-2 at.%, Cr-2 at.%, Er-0.2 at.%; (2 ) Put the weighed raw materials into the crucible of the vacuum induction melting furnace in the order from bottom to top: titanium sponge layer, aluminum block layer, aluminum-niobium master a...

specific Embodiment approach 2

[0027] Specific implementation mode two: the difference between this implementation mode and specific implementation mode one is that, as figure 1 As shown, the multi-functional cold crucible electromagnetically constrained precise forming directional solidification equipment is composed of a forming crystallization system, a vacuum system, a motion system, an electromagnetic system, a control system and a cooling system. The forming crystallization system and the electromagnetic system are the core systems, wherein:

[0028] The control system is used to control the vacuum system, motion system, electromagnetic system and cooling system;

[0029] The cooling system is used to cool the vacuum system, motion system, electromagnetic system, and forming crystallization system;

[0030] The vacuum system, motion system, and electromagnetic system all serve the forming crystallization system, and provide the forming crystallization system with the reaction conditions required for p...

specific Embodiment approach 3

[0031] Embodiment 3: The difference between this embodiment and Embodiment 2 is that the forming crystallization system contains a water-cooled copper crucible, such as figure 2 As shown, the material of the water-cooled copper crucible is copper, the height is 100mm, and the cross-section of the inner cavity is a rectangle of 25.5mm×25.5mm. The lower end of the crucible is connected, and 12 slits divide the entire crucible into 12 sub-section structures. The sections are filled with insulating materials, and cooling water is passed through each section.

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Abstract

The invention discloses a preparing method of a TiAl inter-metallic compound containing the rare earth element Er. The method comprises the following steps: step 1, preparing a Ti-47Al-2Nb-2Cr-0.2Er alloy ingot of which the rear earth element Er content is 0.2at.%; step 2, processing the Ti-47Al-2Nb-2Cr-0.2Er alloy ingot into a round bar for directional solidification experiments; and step 3, preparing the round bar for the directional solidification experiments into a TiAl inter-metallic compound directional solidification sample containing the Er. The rare earth element Er is added into directional solidification TiAl-based alloy, oxygen atoms dissolved in the TiAl-based alloy are cleared by utilizing the rare earth element Er, the directional solidification structure is purified, and the lamellar structure of the directional solidification TiAl alloy is refined. At the same time, the directional solidification effect is not destroyed, and a great role is played on improving the room-temperature ductility of the TiAl alloy and realizing the engineering application of the TiAl alloy.

Description

technical field [0001] The invention relates to a method for synchronously purifying and refining the directional solidification TiAl-based alloy structure, in particular to a preparation method for a TiAl intermetallic compound containing rare earth element Er. Background technique [0002] In recent years, the research on TiAl-based alloys has been paid more and more attention by researchers of superalloys in various countries. TiAl-based alloys have high specific strength, high specific stiffness, and good high-temperature oxidation resistance, creep resistance and hydrogen embrittlement resistance, which are not found in general metals and alloys. They are considered to be the most likely to replace nickel and Lightweight alloys of superalloys. Obtaining TiAl-based alloy columnar grain structure by directional solidification method, and making TiAl-based alloy obtain a microscopic lamellar structure parallel to the growth direction or at an angle of 45° can improve the ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C22C14/00C22C1/03
CPCC22C1/03C22C14/00C22C30/00
Inventor 丁宏升王强陈瑞润郭景杰傅恒志
Owner HARBIN INST OF TECH
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