Catalyst for direct production of low carbon olefins from syngas
A low-carbon olefin and synthesis gas technology, applied in physical/chemical process catalysts, heterogeneous catalyst chemical elements, hydrocarbon production from carbon oxides, etc., can solve the problem of low catalyst selectivity, avoid structural instability and Inactivation, selectivity-enhancing effect
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Embodiment 1
[0071] Weigh equivalent to 50 grams of WO 3 Dissolve the ammonium metatungstate in water to obtain 100 grams of impregnating liquid, mix the impregnating liquid with 50 grams of alumina (20-60 mesh), steam at 80°C under stirring until no visible liquid is found, dry at 120°C for 12 hours, and dry at 550°C °C in an air atmosphere for 5 hours to obtain a catalyst.
[0072] The catalyst composition and evaluation results are shown in Table 1.
Embodiment 2
[0074] Weigh equivalent to 50 grams of WO 3 and MnO 2 Ammonium metatungstate and manganese nitrate (wherein the atomic ratio of W and Mn is 100:70) were dissolved in water to obtain 100 grams of impregnating solution, which was mixed with 50 grams of alumina (20-60 mesh) and stirred for 80 °C until there is no visible liquid, dried at 120 °C for 12 hours, and calcined in an air atmosphere at 550 °C for 5 hours to obtain the catalyst.
[0075] The catalyst composition and evaluation results are shown in Table 1.
Embodiment 3
[0080] Weigh equivalent to 50 grams of WO 3 Ammonium metatungstate of CuO and copper nitrate hexahydrate (where the atomic ratio of W and Cu is 100:70) are dissolved in water to obtain 100 grams of impregnation solution, and the impregnation solution is mixed with 50 grams of alumina (20-60 mesh) , steamed at 80°C under stirring until no visible liquid was found, dried at 120°C for 12 hours, and calcined at 550°C for 5 hours in an air atmosphere to obtain a catalyst.
[0081] The catalyst composition and evaluation results are shown in Table 1.
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