Low eutectic shale inhibitor, and preparation method and application thereof
A shale inhibitor and eutectic technology, applied in the field of drilling fluid inhibitors, can solve the problems of high biological toxicity, great impact on drilling fluid rheology, poor compatibility, etc., and achieve simple synthesis, low raw material prices, and good inhibition performance effect
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[0015] Choline chloride (analytical pure) and urea (analytical pure) were purchased from Sinopharm Chemical Reagent Co., Ltd. A eutectic shale inhibitor, prepared by stirring and heating choline chloride and urea at a molar ratio of 1:2 in an oil bath at 80-100°C for 2-4 hours, until the reaction mixture becomes a transparent liquid, and prepares 1wt% reaction Product (CU-DES) in deionized water.
[0016] The proton spectrum result of embodiment product (CU-DES) is as follows:
[0017] 1 H NMR(40℃):-Me 3 ,9H,s,3.42; α-CH 2 ,2H,m,3.73;β-CH 2 ,2H,m,4.18; OH,1H,v.broad,5.50;NH 2 ,8H,broad,6.24
[0018] Infrared spectrum picture as figure 1 As shown, at 3500~3000cm -1 There is a broad absorption peak at , which is the characteristic peak of a series of intermolecular hydrogen bonds (including C-H, N-H, O-H bonds, etc.) formed after the fusion of choline chloride and urea, among which 3380cm -1 It is the stretching vibration peak of N-H; 1681cm -1 It is the stretching vib...
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