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A one-stage plasma catalysis in-situ diffuse reflectance infrared detection device

An infrared detection device and in-situ diffuse reflection technology, applied in the direction of measuring devices, separation methods, gas treatment, etc., can solve the problems of limiting the exploration of the synergistic mechanism of plasma catalysis and the inability to realize plasma discharge, etc., and achieve the effect of safe discharge process

Active Publication Date: 2021-08-13
DALIAN NATIONALITIES UNIVERSITY
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

At present, the "one-stage" plasma discharge cannot be realized in the existing commercial in-situ diffuse reflectance cells, and there is no method of using in-situ infrared diffuse reflectance spectroscopy to analyze the surface species in the plasma catalytic reaction process, so to a great extent Limitation of the exploration of the synergistic mechanism of plasmonic catalysis

Method used

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  • A one-stage plasma catalysis in-situ diffuse reflectance infrared detection device
  • A one-stage plasma catalysis in-situ diffuse reflectance infrared detection device
  • A one-stage plasma catalysis in-situ diffuse reflectance infrared detection device

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Experimental program
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Effect test

Embodiment 1

[0019] Example 1 A "one-stage" plasma-catalyzed in-situ diffuse reflectance infrared detection device, such as figure 1 The working gas shown in 2 and 2 enters the air chamber 14 from the intake pipe 5, the end of the intake pipe is connected with the top of the window support 1 by thread 15, 2 and 3 are zinc selenide windows and 4 is a quartz window, and the lower end of the observation window is connected with the discharge tube 9 And fixed by PTFE screw 13, the end of high-voltage electrode 8 is inserted into insulating pad 12, the top of high-voltage electrode 8 is inserted from bottom to top by the end of discharge tube 9, and the top of high-voltage electrode is fixed to be equal to the top of grounding electrode, and protective tube 10 is inserted into the bottom of high-voltage electrode 8 , the insulating ring 11 is inserted into the high-voltage electrode 8 and placed on the upper end of the protective tube 10, the right side of the discharge tube 9 is open and connec...

Embodiment 2

[0021] A "one-stage" plasma-catalyzed in-situ diffuse reflection infrared detection device, one end of the inlet pipe 5 is connected to the threaded port 15 at the center of the top of the conical shell 1, the three sides of the conical shell 1 are open, and the front is inlaid with a quartz window 4 for observation Window, the left and right sides have symmetrical openings and are inlaid with zinc selenide windows 2 and 3 as infrared windows. The bottom of the conical shell 1 is in contact with the flat part of the top of the discharge tube 9, and the contact surfaces of the two parts pass through four holes penetrating the two contact surfaces. The PTFE screw 13 is fixed so that the two parts are closely connected, and the ends of different PTFE screws 13 on the same plane are sequentially connected to form a square. One end of the discharge tube 9 is connected to the bottom end of the conical shell 1, and the other end is an insulating pad 12. A fixed ring 11 is arranged par...

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Abstract

The invention relates to a one-stage plasma catalysis in-situ diffuse reflection infrared detection device. Using in situ infrared methods to understand the role of plasmas in catalytic reaction mechanisms provides a method for optimizing catalyst and plasma operating parameters. The invention provides a detailed description for the design of the infrared diffuse reflection pool for the plasma synergistic heterogeneous catalytic reaction. The working gas is introduced into the gas chamber and discharged at the catalytic bed. The discharge tube and the window support are fixed and sealed with PTFE screws. The end of the high-voltage electrode is connected to the insulating pad, inserted from the bottom of the discharge tube, and is flush with the upper surface of the catalytic bed. The detection signal passes through the window and is diffusely reflected on the surface of the sample to be tested, and then converged by the concave lens and sent to the detector. The invention can realize in-situ infrared online monitoring of a one-stage plasma catalytic reaction process, and provides an important characterization means for exploring the reaction mechanism, and meanwhile, the invention is easy to operate and has a wide application range.

Description

technical field [0001] The invention relates to the design of a "one-stage" plasma catalysis in-situ diffuse reflection infrared detection device, which mainly includes the related design of the reactor window and the one-stage plasma discharge reactor. Background technique [0002] From PM, VOCs and NO x The problem of air pollution is becoming more and more prominent, so it is imminent to develop efficient and convenient solutions. The use of electrostatic precipitating methods to treat coal-fired power plants, heating boilers and other major industrial PM pollution sources in my country has made staged progress. At the same time, catalytic combustion and microbial degradation methods have been used to purify trace VOCs in industrial waste gases. effectiveness, but for industrial NO x There is currently no effective governance plan for governance, and the research work is still in the process of exploration. The selective catalytic reduction of hydrocarbons is considered...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): G01N21/3563B01D53/86B01D53/72B01D53/56
CPCB01D53/8625B01D53/864B01D2259/818G01N21/35G01N2021/3595
Inventor 牛金海牛春杰王子文刘东平
Owner DALIAN NATIONALITIES UNIVERSITY
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