Preparation method of anti-electromagnetic radiation polyurethane foam
A technology of polyurethane foam and anti-electromagnetic radiation, applied in the field of preparation of anti-electromagnetic radiation polyurethane foam, can solve the problems of low electromagnetic shielding efficiency, poor anti-electromagnetic radiation ability, high cost, etc., achieve low cost, reduce mixing performance, and improve mechanical properties Effect
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Embodiment 1
[0037] A kind of preparation method of anti-electromagnetic radiation polyurethane foam, described preparation method comprises the following steps:
[0038] (1) Preparation of siloxane-modified phthalic anhydride polyester polyol:
[0039] (1.1) Preparation of silicone-modified polyol: Weigh 100 parts of propylene glycol in parts by weight, then add 5 parts of tetraethyl orthosilicate to it and stir evenly, then continue to add 0.5 part of glacial acetic acid and water 10 parts, and then stirred and reacted at 40°C for 2 hours, and evaporated under reduced pressure to remove the water and the small molecular substances generated by the reaction to obtain a silicone-modified polyol;
[0040](1.2) Polyester polyol prepolymerization: Weigh 100 parts of silicone-modified polyol obtained in step (1.1) and 45 parts of phthalic anhydride in parts by weight, stir evenly and raise the temperature to 135°C , after stirring and reacting for 3 hours, the prepolymerization step was compl...
Embodiment 2
[0049] A kind of preparation method of anti-electromagnetic radiation polyurethane foam, described preparation method comprises the following steps:
[0050] (1) Preparation of siloxane-modified phthalic anhydride polyester polyol:
[0051] (1.1) Preparation of silicone-modified polyol: Weigh 100 parts of propylene glycol in parts by weight, then add 10 parts of tetraethyl orthosilicate to it and stir evenly, then continue to add 2 parts of glacial acetic acid and water 15 parts, then stirred and reacted at 60°C for 5 hours, and evaporated under reduced pressure to remove the water and the small molecular substances generated by the reaction to obtain a silicone-modified polyol; (1.2) Polyester polyol prepolymerization: according to parts by weight Count and weigh 100 parts of silicone-modified polyol and 80 parts of phthalic anhydride obtained in step (1.1), stir evenly, raise the temperature to 185°C, stir and react for 5 hours until the acid value is 30mgKOH / When the prep...
Embodiment 3
[0060] A kind of preparation method of anti-electromagnetic radiation polyurethane foam, described preparation method comprises the following steps:
[0061] (1) Preparation of siloxane-modified phthalic anhydride polyester polyol:
[0062] (1.1) Preparation of silicone-modified polyol: Weigh 100 parts of propylene glycol in parts by weight, then add 8 parts of tetraethyl orthosilicate to it and stir evenly, then continue to add 1 part of glacial acetic acid and water 12 parts, and then stirred and reacted at 50°C for 3 hours, and evaporated under reduced pressure to remove the water and the small molecular substances generated by the reaction to obtain a silicone-modified polyol;
[0063] (1.2) Polyester polyol prepolymerization: Weigh 100 parts of silicone-modified polyol obtained in step (1.1) and 75 parts of phthalic anhydride in parts by weight, stir evenly and raise the temperature to 155°C , after stirring and reacting for 4 hours, the prepolymerization step was comple...
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