Method for smelting high-phosphorus molten iron to produce steel with converter end point P less than or equal to 0.01% by adopting slagless material

A converter end point, slag material technology, applied in the direction of manufacturing converters, improving process efficiency, etc., can solve the problems of reduced metal yield, increased dephosphorization difficulty, poor dephosphorization effect, etc. Set and produce fast-paced effects

Active Publication Date: 2019-01-29
UNIV OF SCI & TECH BEIJING
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  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] At present, the dephosphorization process of converter mainly includes single slag method, double slag method and double-combination method. Generally speaking, for high-phosphorus molten iron with P≥0.15%, double-slag and double-combination process should be used for dephosphorization when smelting low-phosphorus steel However, due to the need for furnace and slag dumping during the smelting process, the production rhythm is slow, and sometimes the control is not good, and the metal yield will be reduced.
The single slag method can improve production efficiency, but for molten iron with low silicon content and high phosphorus content, the low silicon content leads to slow slag melting in the early stage, which cannot make good use of the good thermodynamic conditions of low temperature dephosphorization in the early stage, resulting in poor dephosphorization effect in the early stage. Increased the difficulty of dephosphorization

Method used

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  • Method for smelting high-phosphorus molten iron to produce steel with converter end point P less than or equal to 0.01% by adopting slagless material

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0034] Load 109.8t of low-silicon and high-phosphorus hot metal and 16t of scrap steel into the 120t converter with a nominal tonnage of 120t. Among them, the weight percentage of elements in the molten iron is P: 0.190%, Si: 0.148% , C: 4.296%, the molten iron temperature is 1260℃, and the amount of slag remaining is 100%.

[0035] Within 4 minutes of the blowing process, the primary slag material mixed with lime, dolomite and returned slag is added to the converter. The primary slag material added is: lime 8.5kg / t molten steel, dolomite 8.5kg / t Liquid steel; After blowing oxygen for about 4 minutes, according to the slagging situation, add lime 4.2kg / t molten steel and pellets 2.5kg / t molten steel; add new slag material 23.7kg / t molten steel in total;

[0036] In the blowing process, the high-low-high-low gun position control mode is specifically as follows: the gun position is first reduced to 1.9m within 3 minutes of blowing, and the slag is rapidly reduced, and then about 1.6m...

Embodiment 2

[0042] Load 115.4t of low-silicon and high-phosphorus hot metal and 21t of scrap steel into the 120t converter with a nominal tonnage of 120t. Among them, the weight percentage of elements in the molten iron is P: 0.147% and Si: 0.198%. , C: 4.289%, molten iron temperature is 1270℃, slag retention is 50% half slag.

[0043] Within 4 minutes of the blowing process, the primary slag material mixed with lime, dolomite, and returned slag is added to the converter. The primary slag material added is: 11.9kg / t molten steel lime and 5.1kg / t dolomite Molten steel, return slag 4.5kg / t molten steel; after blowing oxygen for about 4 minutes, add 8.6kg / t molten steel with lime according to the slagging situation; add new slag material 25.6kg / t molten steel in total;

[0044] In the blowing process, the high-low-high-low gun position control mode is specifically as follows: the gun position is first reduced to 1.95m within 3 minutes of blowing, and the slag is quickly reduced, and then about 1....

Embodiment 3

[0050] The 120t nominal tonnage converter is charged with 120.0t of low-silicon and high-phosphorus hot metal and 20t of scrap steel without pre-treating treatment. The weight percentage of elements in the molten iron is P: 0.168% and Si: 0.258%. , C: 4.432%, the molten iron temperature is 1230℃, and the amount of slag remaining is 100%.

[0051] Within 4 minutes of the blowing process, a primary slag material mixed with lime, dolomite and returned slag is added to the converter. The primary slag material added is: lime 19.4kg / t molten steel and dolomite 16.5kg / t Liquid steel, return slag 4.7kg / t molten steel; after blowing oxygen for about 4 minutes, add 9.1kg / t molten steel with lime, 1.7kg / t molten steel with dolomite, and 1.5kg pellets according to the slagging situation. / t molten steel; a total of 48.2kg / t molten steel is added with new slag material;

[0052] The high-low-high-low gun position control mode used in the blowing process is specifically as follows: the gun posi...

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Abstract

The invention belongs to the technical field of converter steelmaking processes, and particularly relates to a method for smelting high-phosphorus molten iron to produce steel with converter end pointP less than or equal to 0.01% by adopting slagless material. The method comprises the following steps that loading low-silicon high-phosphorus molten iron and steel scrap which are not subjected to triple-removal pretreatment into a converter, a single-slag method is adopted to carry out blowing, a slagging material is added twice in a blowing process and a gun position control mode of high, low, high and low is adopted in the blowing process, and oxygen supply and nitrogen supply are carried out in the blowing process; after the blowing is completed, the steel is discharged, slag splashingis carried out after the steel is discharged, slag is reserved after the slag splashing, and is used for smelting in the next furnace. According to the method, on the premise that lime consumption ofa steel liquid is less than or equal to 30 kg/t, and the consumption of the new slag material is less than or equal to 50 kg/t, dephosphorizing of the molten iron with the following components, by weight, 0.14-0.26% and Si, 0.15-0.20% of P is carried out until P is less than or equal to 0.01%, and a dephosphorization rate is larger than or equal to 94%, so that the problem that low-phosphorus steel is smelted by a low-silicon high-phosphorus molten iron with the few slag material in the single-slag method is solved.

Description

Technical field [0001] The invention belongs to the technical field of converter steelmaking technology, and specifically relates to a method for producing converter end-point P≤0.01% steel by smelting high-phosphorus hot metal with less slag material. Background technique [0002] The blast furnace reduces the silicon content in the molten iron ≤ 0.6%, on the one hand, it can increase the output, on the other hand, it can also reduce the coke ratio, which brings huge economic benefits to the enterprise. At the same time, with the gradual decrease of high-quality low-phosphorus ore and the sharp increase in its price, companies have increased the use of high-phosphorus ore to reduce production costs, resulting in an increase in the proportion of high-phosphorus molten iron, which has seriously affected the converter’s low-phosphorus molten steel. Production restricts the production of high-quality low-phosphorus products. Under the premise of reducing production costs, improving...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C21C5/28C21C7/064
CPCC21C5/28C21C7/064Y02P10/20
Inventor 闫威李晶戴雨翔宋沈杨
Owner UNIV OF SCI & TECH BEIJING
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