Rice weeding composition containing metamifop
A technology containing oxazolam and a herbicidal composition, which is applied in the directions of herbicides, algicides, biocides, animal repellents, etc., and can solve problems such as non-weed biological hazards, unfavorable weeding, soil pollution and the like , to achieve outstanding effects, improve efficiency, and adapt to a wide range of effects
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Embodiment 1
[0019] The invention provides a technical solution: a rice herbicidal composition containing fenpyramid, comprising the following formula: fenfenpyr and cyhalofop-methyl, mixed in a certain proportion, and the formula consists of the following weight 5-13 parts by mass of fenflufen, 10-20 parts by mass of cyhalofop-ethyl.
[0020] According to the above-mentioned technical scheme, the preparation method of cyhalofop-methyl is 1) etherification reaction: add acid binding agent, organic base and phase transfer catalyst in the aprotic organic solvent, then add (R)-2-(4 -Hydroxyphenoxy)propionic acid, then add 3,4-difluorobenzonitrile, heat to 60-90°C, keep warm for 2-4 hours, remove the solvent after the reaction, cool down to room temperature, add water to dissolve, and use acid Adjust the pH to 3-5, stir, precipitate solids, and filter to obtain the intermediate (R)-2-[4-(2-fluoro-4-nitrile)-phenoxy]-propionic acid; wherein, (R) - The molar ratio of 2-(4-hydroxyphenoxy)propion...
Embodiment 2
[0023] The invention provides a technical solution, a rice herbicidal composition containing fenpyramid, which comprises the following formula composition: fenpyrid, bisfluben and pyrazosulfuron-methyl, which are mixed in a certain proportion to form the composition. The formula is made of the following raw materials in parts by weight: 5-13 parts by weight of fenpyramid, 4-8 parts by weight of bispyribac, and 6-11 parts by weight of closulfuron-methyl.
[0024] According to the above-mentioned technical scheme, the preparation method of clopyrazosulfuron-methyl comprises the following steps:
[0025] Step 1: 1-methyl-5-sulfonamido-4-pyrazolecarboxylic acid ethyl ester is first hydrolyzed under alkaline conditions to obtain 1-methyl-5-sulfonamido-4-pyrazolecarboxylic acid sodium, and then in Acidification and neutralization under acidic conditions to obtain 1-methyl-5-sulfonamido-4-pyrazolecarboxylic acid;
[0026] Step 2: Methylating the 1-methyl-5-sulfonamido-4-pyrazolecarb...
Embodiment 3
[0030] The invention provides a technical solution, a rice herbicidal composition containing fenpyramid, which comprises the following formula: fenpyral, cyhalofop-ethyl and quinclorac are mixed in a certain proportion to form the composition. The formula is prepared from the following raw materials in parts by weight: 5-13 parts by weight of fenfluramide, 10-20 parts by weight of cyhalofop-ethyl, and 5-10 parts by weight of quinclorac.
[0031] According to the above-mentioned technical scheme, the preparation method of cyhalofop-methyl is 1) etherification reaction: add acid binding agent, organic base and phase transfer catalyst in the aprotic organic solvent, then add (R)-2-(4 -Hydroxyphenoxy)propionic acid, then add 3,4-difluorobenzonitrile, heat to 60-90°C, keep warm for 2-4 hours, remove the solvent after the reaction, cool down to room temperature, add water to dissolve, and use acid Adjust the pH to 3-5, stir, precipitate solids, and filter to obtain the intermediate ...
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