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Rice weeding composition containing metamifop

A technology containing oxazolam and a herbicidal composition, which is applied in the directions of herbicides, algicides, biocides, animal repellents, etc., and can solve problems such as non-weed biological hazards, unfavorable weeding, soil pollution and the like , to achieve outstanding effects, improve efficiency, and adapt to a wide range of effects

Inactive Publication Date: 2019-02-01
安徽圣丰生化有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

In the past century, herbicides have been used to effectively control many weeds, but the extensive use of chemical agents has also caused a series of problems, such as the emergence of herbicide-resistant weed plants, soil pollution, water quality degradation, and the use of non-weeds. The harm of grass organisms, etc., is not conducive to weeding

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0019] The invention provides a technical solution: a rice herbicidal composition containing fenpyramid, comprising the following formula: fenfenpyr and cyhalofop-methyl, mixed in a certain proportion, and the formula consists of the following weight 5-13 parts by mass of fenflufen, 10-20 parts by mass of cyhalofop-ethyl.

[0020] According to the above-mentioned technical scheme, the preparation method of cyhalofop-methyl is 1) etherification reaction: add acid binding agent, organic base and phase transfer catalyst in the aprotic organic solvent, then add (R)-2-(4 -Hydroxyphenoxy)propionic acid, then add 3,4-difluorobenzonitrile, heat to 60-90°C, keep warm for 2-4 hours, remove the solvent after the reaction, cool down to room temperature, add water to dissolve, and use acid Adjust the pH to 3-5, stir, precipitate solids, and filter to obtain the intermediate (R)-2-[4-(2-fluoro-4-nitrile)-phenoxy]-propionic acid; wherein, (R) - The molar ratio of 2-(4-hydroxyphenoxy)propion...

Embodiment 2

[0023] The invention provides a technical solution, a rice herbicidal composition containing fenpyramid, which comprises the following formula composition: fenpyrid, bisfluben and pyrazosulfuron-methyl, which are mixed in a certain proportion to form the composition. The formula is made of the following raw materials in parts by weight: 5-13 parts by weight of fenpyramid, 4-8 parts by weight of bispyribac, and 6-11 parts by weight of closulfuron-methyl.

[0024] According to the above-mentioned technical scheme, the preparation method of clopyrazosulfuron-methyl comprises the following steps:

[0025] Step 1: 1-methyl-5-sulfonamido-4-pyrazolecarboxylic acid ethyl ester is first hydrolyzed under alkaline conditions to obtain 1-methyl-5-sulfonamido-4-pyrazolecarboxylic acid sodium, and then in Acidification and neutralization under acidic conditions to obtain 1-methyl-5-sulfonamido-4-pyrazolecarboxylic acid;

[0026] Step 2: Methylating the 1-methyl-5-sulfonamido-4-pyrazolecarb...

Embodiment 3

[0030] The invention provides a technical solution, a rice herbicidal composition containing fenpyramid, which comprises the following formula: fenpyral, cyhalofop-ethyl and quinclorac are mixed in a certain proportion to form the composition. The formula is prepared from the following raw materials in parts by weight: 5-13 parts by weight of fenfluramide, 10-20 parts by weight of cyhalofop-ethyl, and 5-10 parts by weight of quinclorac.

[0031] According to the above-mentioned technical scheme, the preparation method of cyhalofop-methyl is 1) etherification reaction: add acid binding agent, organic base and phase transfer catalyst in the aprotic organic solvent, then add (R)-2-(4 -Hydroxyphenoxy)propionic acid, then add 3,4-difluorobenzonitrile, heat to 60-90°C, keep warm for 2-4 hours, remove the solvent after the reaction, cool down to room temperature, add water to dissolve, and use acid Adjust the pH to 3-5, stir, precipitate solids, and filter to obtain the intermediate ...

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PUM

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Abstract

The invention discloses a rice weeding composition containing metamifop, wherein the rice weeding composition comprises a primary active ingredient and a secondary active ingredient. The primary active ingredient comprises 5-13 parts by mass of metamifop. The secondary active ingredient is selected from 10-20 parts by mass of cyhalofop-butyl, 4-8 parts by mass of bispyribac-sodium, 5-10 parts by mass of quinclorac, 6-11 parts by mass of halosulfuron-methyl, and 4-12 parts by mass of chlorofluoroacetic acid, and the second active ingredient can be an active substance: cyhalofop-butyl, or a mixture of two active substances: bispyribac-sodium and halosulfuron-methyl, cyhalofop-butyl and quinclorac, and chlorofluoroacetic acid and halosulfuron-methyl. The invention relates to the field of pharmaceutical compounds. The rice weeding composition containing metamifop which is safe to rice can effectively prevent and eliminate main weeds in paddy fields, such as barnyard grass, moleplant seed,common crabgrass herb and eleusine indica, is mainly used for weeding in transplanting and direct broadcasting paddy fields, and can effectively solve the problems in the prior art.

Description

technical field [0001] The invention relates to the field of pharmaceutical compounds, in particular to a rice herbicidal composition containing fenpyramid. Background technique [0002] There are 30,000 species of weeds widely distributed in the world, and about 1,800 species cause different degrees of damage to crops every year. The annual crop yield reduction due to weed damage is as high as 9.7%. Herbicides can make weeds occur completely or selectively. Dead agents, also known as herbicides, are a class of substances used to destroy or inhibit plant growth. Commonly used herbicides are organic compounds, which can be widely used to control harmful plants such as weeds, shrubs, and trees in farmland, orchards, flower nurseries, grasslands and non-cultivated land, railway lines, rivers, reservoirs, warehouses, etc. Over the past century, herbicides have been used to effectively control many weeds, but the extensive use of chemical agents has also caused a series of probl...

Claims

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Application Information

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IPC IPC(8): A01N43/76A01N39/04A01N43/54A01N43/42A01N47/36A01N43/40A01P13/00
CPCA01N39/04A01N43/40A01N43/42A01N43/54A01N43/76A01N47/36
Inventor 李冰清李玉洁
Owner 安徽圣丰生化有限公司