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Anti-blue-ray/color-changeable difunctional coating optical material and preparation method thereof

An optical material and anti-blue light technology, applied in the field of light-absorbing materials, can solve problems such as damage

Active Publication Date: 2019-02-15
JIANGSU SHIKEXINCAI CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

It can be widely used in automobile windows, optical protective glass, LED light protective film, mobile phone protective screen, eye protection equipment and other fields to solve the damage caused by harmful light to human eyes

Method used

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  • Anti-blue-ray/color-changeable difunctional coating optical material and preparation method thereof
  • Anti-blue-ray/color-changeable difunctional coating optical material and preparation method thereof
  • Anti-blue-ray/color-changeable difunctional coating optical material and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0062] Example 1: Preparation of anti-blue light nanocomposite microspheres, anti-blue light coating solution, anti-blue light optical glass, anti-blue light / color-changing dual-function optical glass and anti-blue light / color-changing dual-function optical resin material

[0063] (1) Preparation of anti-blue light nanocomposite microspheres:

[0064] 1. Add 80g of sodium acetate to 1000g of pure water, gradually raise the temperature to 100°C, after turning into a transparent sodium acetate aqueous solution, add 130g of nano-titanium oxide, stir for 20 minutes, cool to room temperature, the reaction solution gradually precipitates in layers, and solid-liquid filtration After separation and washing, add 1500g of ethanol, then stir and add 50g of ultraviolet absorber UV-P, stir for 20 minutes, let stand for 50 minutes, filter and collect the precipitate, and dry to obtain titanium oxide modified nanomaterials;

[0065] Figure 5 It is the transmission electron microscope TEM i...

Embodiment 2

[0084] Example 2: Preparation of anti-blue light nanocomposite microspheres, anti-blue light coating solution, anti-blue light optical glass, anti-blue light / color-changing dual-function optical glass and anti-blue light / color-changing dual-function optical resin material

[0085] (1) Preparation of anti-blue light nanocomposite microspheres:

[0086] Add 95g of sodium acetate to 1000g of pure water, gradually raise the temperature to 100°C, after turning into a transparent sodium acetate aqueous solution, add 180g of nano-titanium oxide, stir for 20 minutes, cool to room temperature, the reaction solution is gradually layered and precipitated, separated by solid-liquid filtration, After washing, add 1700g of ethanol, then stir and add 36g of ultraviolet absorber UV-P, stir for 25 minutes, let stand for 50 minutes, filter and collect the precipitate, dry to obtain titanium oxide modified nanomaterials;

[0087] Take 7g titanium oxide modified nanomaterials, 4.2g isophorone dii...

Embodiment 3

[0097] Example 3: Preparation of anti-blue light nanocomposite microspheres, anti-blue light coating solution, anti-blue light optical glass, anti-blue light / color-changing dual-function optical glass and anti-blue light / color-changing dual-function optical resin material

[0098] (1) Preparation of anti-blue light nanocomposite microspheres:

[0099] Add 75g of sodium acetate to 1000g of pure water, gradually raise the temperature to 100°C, after turning into a transparent sodium acetate aqueous solution, add 100g of nano-titanium oxide, stir for 20 minutes, cool to room temperature, the reaction solution is gradually layered and precipitated, separated by solid-liquid filtration, After washing, add 1300g of ethanol, then stir and add 28g of ultraviolet absorber UV-P, stir for 20 minutes, let stand for 50 minutes, filter and collect the precipitate, and dry to obtain titanium oxide modified nanomaterials;

[0100] Take 7g of titanium oxide modified nanomaterials, 7g of m-xyly...

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Abstract

The invention provides an anti-blue-ray / color-changeable difunctional coating optical material and a preparation method thereof. The difunctional coating optical material comprises an optical base material, an anti-blue-ray coating and a photochromic coating. The anti-blue-ray coating is doped with polyurethane / light absorber / titanium oxide nano composite microspheres, each polyurethane / light absorber / titanium oxide nano composite microsphere has a three-layered composite core-shell structure, the core is a titanium oxide nano microsphere, the middle layer is a light absorber, and the shell ispolyurethane. The barrier spectral range of the anti-blue-ray coating is expanded to a blue-ray spectral range from an ultraviolet spectral range, and under the condition of maintaining high transmittance, the anti-blue-ray / color-changeable difunctional coating optical material has a property of absorbing blue rays in different wave bands in a distinguished manner. The anti-blue-ray coating is matched with the photochromic coating material, functions of the anti-blue-ray coating and the photochromic coating material are integrated, the transmittance can be automatically adjusted according tointensity of light, brightness is controllable by selective transmitting of beneficial light and stopping of harmful light, and thus, light is transmitted as needed.

Description

technical field [0001] The invention belongs to the technical field of light-absorbing materials, and in particular relates to an optical material with specific absorption for different wavelengths in the 280-450nm spectral region and a preparation method thereof. Background technique [0002] As we all know, ultraviolet rays can damage human eyes. In addition, blue light in visible light can also cause damage to eyes. As part of visible light, blue light has extremely high energy, and its wavelength range is between 400 and 500nm. With the widespread popularization of electronic products such as computers, mobile phones, and ipads, unnatural light with blue light as the main body will cause irreversible damage to human eyes. Damage, causing dry eyes, fatigue, tearing, accelerated myopia, macular area disease and other problems. According to the orange warning issued by the World Health Organization (WHO) at the end of 2009: the potential invisible threat of blue light to h...

Claims

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Application Information

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IPC IPC(8): C09D175/04C09D7/62
CPCC08K2003/2241C08K2201/011C09D175/04C09D7/62C08K9/10C08K3/22
Inventor 王明华沈秋雨邹永存张凌张鹤军乔振安纪立军范为正司云凤刘洋郑永华
Owner JIANGSU SHIKEXINCAI CO LTD
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