CO2-enriched amine solution regeneration energy consumption reducing novel catalytic desorber

A technology of amine solution and desorption tower, which is applied in the field of new catalytic desorption tower, can solve the problems of small gas-liquid-solid three-phase contact area, catalyst utilization efficiency, low efficiency of catalytic desorption system, poor gas-liquid mass transfer performance, etc., and achieve catalytic desorption Excellent performance, low cost, low cost effect

Inactive Publication Date: 2019-02-19
HUNAN UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

Professor Idem of the University of Regina in Canada proposed a method of mixing solid acid catalysts and inert particles and packing them in random piles in a traditional CO2 desorption tower. However, this packing method has poor gas-liquid m

Method used

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  • CO2-enriched amine solution regeneration energy consumption reducing novel catalytic desorber
  • CO2-enriched amine solution regeneration energy consumption reducing novel catalytic desorber
  • CO2-enriched amine solution regeneration energy consumption reducing novel catalytic desorber

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Embodiment 1

[0027] The catalytic desorption device of the present invention is used to carry out catalytic desorption of 5M monoethanolamine (MEA) with a rich liquid load of 0.5mol / mol amine. The composition of the catalytic desorption tower is as follows, the tower body is made of stainless steel, the inner diameter of the tower is 35mm, the packing height is 0.6m, and the packing is structured packing; the height of the two catalyst reactors is 0.3m, and the mass ratio of the catalyst to the amine solution is 1 / 80. The solid acid catalyst used is HZSM-5, γ-Al 2 o 3 And SAPO-34 molecular sieve catalyst. The heating medium is heat conduction oil, the desorption temperature is 95°C, and the solution flow rate is 6m 3 / m 2 .

[0028] Solvent desorption energy consumption (Q reg , kJ / kg CO 2 ) is calculated from two parts, that is, the reboiler heat load (H reb ,kJ / h) and CO 2 Gas mass flow rate (m CO2 , kg / h) ratio.

[0029]

[0030] Among them, H loss : System energy loss, kJ...

Embodiment 2

[0043] Use the catalytic desorption device of the present invention to the 6M monoethanolamine (MEA) and 4-(diethylamino)-2-butanol (DEAB) mixed amine solution (molar ratio is 5 : 1) Carry out catalytic desorption, for comparative study, carry out blank desorption (that is, rich amine solution does not flow through catalytic reactor) to the rich solution loading is 0.5mol / mol amine5M MEA. Desorption tower structure is identical with embodiment 1. The solid acid catalyst used is HZSM-5, γ-Al 2 o 3 and HZSM-5 / γ-Al 2 o 3 mixed catalyst. The heating medium is tap water, the desorption temperature is set at 95°C, and the solution flow rate is 6m 3 / m 2 . Solvent desorption energy consumption (Q reg , kJ / kg CO 2 ) is calculated from two parts, that is, the reboiler heat load (H reb ,kJ / h) and CO 2 Gas mass flow rate (m CO2 , kg / h) ratio, its calculation method is the same as example 1.

[0044] The experimental results show that each catalyst can greatly reduce the enri...

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Abstract

The invention discloses a CO2-enriched amine solution regeneration energy consumption reducing novel catalytic desorber. Compared with traditional desorbers, the CO2-enriched amine solution regeneration energy consumption reducing novel catalytic desorber introduces a catalytic reactor into a traditional CO2 desorption process without changing the technical process, the pipe layout, the heating manner and the like of the traditional desorbers; the catalytic reactor is filled with solid catalysts, CO2-enriched amine solution enters into the catalytic reactor via the bottom of the catalytic reactor under the action of a pump, and through full contact between the catalysts and the CO2-enriched amine solution, the performance of the catalysts can be maximized. The CO2-enriched amine solution regeneration energy consumption reducing novel catalytic desorber is mainly composed of the catalytic reactor and a packed tower; introduction of acid catalysts accelerates the regeneration rate of theCO2-enriched amine solution, reduces the regeneration temperature and accordingly achieves the aim of high-efficiency and low-energy-consumption regeneration of the CO2-enriched amine solution. The CO2-enriched amine solution regeneration energy consumption reducing novel catalytic desorber is higher in catalytic performance than existing catalytic desorbers and the traditional desorbers.

Description

technical field [0001] The invention relates to a novel catalytic desorption tower for the regeneration of carbon dioxide-enriched amine solution. Background technique [0002] In recent years, due to the extensive use of fossil energy such as coal, oil, and natural gas, the greenhouse effect has become increasingly serious, and the global climate change caused by it has threatened the survival and development of human beings, while carbon dioxide (CO 2 ) is one of the most important greenhouse gases. [0003] Existing carbon capture technologies mainly include three technologies: pre-combustion capture, oxygen-enriched combustion capture and post-combustion capture. Among them, post-combustion capture technology is the most mature and widely used carbon capture technology. Post-combustion carbon capture technology There are mainly chemical absorption method, physical adsorption method and membrane separation method. In the chemical solvent absorption method, organic amine...

Claims

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Application Information

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IPC IPC(8): B01D53/14
CPCB01D53/1425B01D53/1475B01D2252/204
Inventor 梁志武张晓文黄玉飞
Owner HUNAN UNIV
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