Sulfur-crosslinkable rubber mixture and vehicle tire
A rubber compound, cross-linked rubber technology, applied in special tires, vehicle parts, tire parts, etc., can solve the problems of rolling resistance, deterioration of winter characteristics and wear characteristics, and achieve improved wet grip characteristics, improved tear characteristics, The effect of increasing stiffness
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[0107] Production of rubber blends:
[0108] Copolymerization of 1,3-butadiene with styrene (diene polymer A)
[0109] Copolymerization was carried out in a jacketed 40 L steel reactor which was purged with nitrogen prior to addition of organic solvent, monomer, polar ligand compound, initiator compound and other components. The following components were added in the specified order: cyclohexane solvent (18 560 g); butadiene monomer (1777 g), styrene monomer (448 g) and tetramethylethylenediamine (TMEDA, 1.0 g), and The mixture was heated to 40°C and then titrated with n-butyllithium to remove traces of water or other impurities. n-BuLi (14.08 mmol) was added to the polymerization reactor to initiate polymerization. The polymerization was carried out for 20 minutes, during which the polymerization temperature was not allowed to rise above 70°C. Butadiene (1202 g) and styrene (91 g) were then added as monomers within 55 minutes. Polymerization was carried out for another 2...
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