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Molding resin for improving insulation performance and heat deformation temperature of outdoor electrical appliance, and preparation method thereof

A heat distortion temperature and insulation performance technology, applied in the chemical industry, can solve the problems of low tensile strength, bending strength and low hardness, and achieve the effect of improving Barcol hardness and thermal stability

Pending Publication Date: 2019-04-05
镇江利德尔复合材料有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] Unsaturated resins prepared in the prior art generally have low tensile strength, flexural strength and bus hardness, so it is necessary to improve the preparation process to improve the performance of the resin

Method used

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  • Molding resin for improving insulation performance and heat deformation temperature of outdoor electrical appliance, and preparation method thereof
  • Molding resin for improving insulation performance and heat deformation temperature of outdoor electrical appliance, and preparation method thereof
  • Molding resin for improving insulation performance and heat deformation temperature of outdoor electrical appliance, and preparation method thereof

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preparation example Construction

[0052] The present invention also discloses a method for preparing a molded resin for improving the insulation performance and thermal deformation temperature of outdoor electrical appliances, comprising the following steps:

[0053] Step 1, diol, phthalic anhydride, maleic anhydride, methyltetrahydrophthalic anhydride, antioxidant and 1 / 2 of the chelating agent are dropped into the reaction kettle in turn, and the temperature rise reaction is started, with the first When the rate of heating increases the temperature of the reactor from room temperature to the first temperature threshold, start stirring;

[0054] Among them, the first heating rate from room temperature to 120-140°C is:

[0055]

[0056] where, ψ 1 is the first heating coefficient, T 0 is room temperature, T 1_max is the maximum temperature of the first temperature threshold, T 1_min is the minimum temperature of the first temperature threshold, W O is the total mass fraction of acid anhydride, W OH Be...

Embodiment 1

[0072] The raw materials and mass parts thereof for preparing molding resin are as follows:

[0073] Step 1, 28.5 parts of a mixture of 1,2-ethanediol, 1,3-propanediol and 1,4-butanediol with a mass ratio of 1.5:8.5:1, 3 parts of phthalic anhydride, 26.5 parts of maleic anhydride part, 4 parts of methyltetrahydrophthalic anhydride, 23 parts of styrene, 0.07 part of polymerization inhibitor, 0.08 part of retarder, 0.08 part of antioxidant, 0.18 part of plasticizer, 7 parts of chelating agent;

[0074] A mixture of 1,2-ethanediol, 1,3-propanediol and 1,4-butanediol with a mass ratio of 1.5:8.5:1, phthalic anhydride, maleic anhydride, methyltetrahydrophthalic anhydride Diformic anhydride, the mixture of antioxidant 1010 and antioxidant 1076 with a mass ratio of 1.5:1, and 1 / 2 of 1,3-diketone are put into the reactor in turn, and the temperature rise reaction is started, and the reactor is heated at the first heating rate. When the temperature rises from room temperature to 120-1...

Embodiment 2

[0086] Step 1. Prepare the raw materials and parts by mass for preparing the molded resin as follows:

[0087] 37.5 parts of a mixture of 1,2-ethanediol, 1,3-propanediol and 1,4-butanediol with a mass ratio of 3.5:4.5:1, 4.5 parts of phthalic anhydride, 21.5 parts of maleic anhydride, 8.5 parts of tetrahydrophthalic anhydride, 28 parts of styrene, 0.13 parts of polymerization inhibitor, 0.41 part of retarder, 0.11 parts of the mixture of antioxidant 1010 and antioxidant 1076 with a mass ratio of 3.5:1, plasticizer 0.35 parts, 15 parts of chelating agent;

[0088] A mixture of 1,2-ethanediol, 1,3-propanediol and 1,4-butanediol with a mass ratio of 3.5:4.5:1, phthalic anhydride, maleic anhydride, methyltetrahydrophthalic anhydride Diformic anhydride, the mixture of antioxidant 1010 and antioxidant 1076 with a mass ratio of 3.5:1, and 1 / 2 of 1,3-diketone are put into the reactor in turn, and the temperature rise reaction is started, and the reactor is heated at the first heating...

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Abstract

The invention discloses molding resin for improving the insulation performance and heat deformation temperature of an outdoor electrical appliance. The molding resin comprises 28.5-37.5 parts of diol,3-4.5 parts of phthalic anhydride, 21.5-26.5 parts of maleic anhydride, 4-8.5 parts of methyltetrahydrophthalic anhydride, 23-28 parts of styrene, 0.07-0.13 part of polymerization inhibitor, 0.08-0.41 part of retarder, 0.08-0.11 of antioxidant, 0.18-0.35 part of plasticizer and 7-15 parts of chelating agent. The invention also discloses a preparation method of the molding resin for improving theinsulation performance and heat deformation temperature of the outdoor electrical appliance.

Description

technical field [0001] The invention relates to the field of chemical industry, in particular to a molded resin for improving the insulation performance and thermal deformation temperature of outdoor electrical appliances and a preparation method thereof. Background technique [0002] Polyester resin is the abbreviation of unsaturated polyester adhesive. Unsaturated polyester adhesive is mainly composed of unsaturated polyester resin, initiator, accelerator, filler, thixotropic agent and so on. A linear structure (see linear polymer) polyester resin containing -CH=CH- double bonds in the main chain, which can be mixed with ethylenic monomers, such as styrene, acrylate, vinyl acetate, etc., in Under the action of initiators and accelerators, it can be polymerized into insoluble and infusible products at room temperature. Polyester resin is a general term for polymer compounds formed by polycondensation of diols or dibasic acids or polyols and polybasic acids. Polyester res...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08G63/52C08G63/78C08L67/06C08K5/134C08K5/12
CPCC08G63/52C08G63/78C08K5/12C08K5/1345C08L67/06
Inventor 谢富平曹俊叶忠华
Owner 镇江利德尔复合材料有限公司
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