Exhaust gas purification catalyst
一种废气净化、催化剂的技术,应用在物理/化学过程催化剂、催化剂活化/制备、金属/金属氧化物/金属氢氧化物催化剂等方向,能够解决没有研究压力损失、废气净化性能下降、废气净化性能降低等问题,达到优化废气净化性能的效果
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[0070] Hereinafter, the present invention will be described in more detail using examples. However, the technical scope of the present invention is not limited by these examples.
[0071] 1. OSC material
[0072] As the OSC material, ceria-zirconia (CeO 2 -ZrO 2 ) composite oxides.
[0073] Preparation of Ceria-Zirconia Composite Oxide (Pyrochlore ZC) with Pyrochlore Structure
[0074] will be CeO 2 49.1 g of a 28% by weight aqueous cerium nitrate solution in terms of ZrO 2 After dissolving 54.7 g of an aqueous zirconyl nitrate solution of 18% by weight in conversion and a commercially available surfactant in 90 mL of ion-exchanged water, 1.2 times the equivalent of NH was added to the anion. 3 In 25% by weight of ammonia water, a coprecipitate was generated, and the obtained coprecipitate was filtered and washed. Next, the obtained coprecipitate was dried at 110° C., and then fired at 500° C. in the air for 5 hours to obtain a solid solution of cerium and zirconium. T...
Embodiment 1、2 and comparative example 5
[0092] In Examples 1, 2, and Comparative Example 5, pyrochlore ZC was added to the slurry 2 for forming the upper layer of the catalyst coating so that the capacity relative to the substrate was 30 g / L, 50 g / L, and 70 g / L, respectively. Each catalyst was obtained in the same manner as in Comparative Example 4 except for the amount of L.
Embodiment 3、4 and comparative example 7
[0094] In Examples 3, 4, and Comparative Example 7, pyrochlore ZC was added to the slurry 2 for forming the catalyst coating layer of the upper layer, so that the capacity relative to the base material became 30 g / L, 50 g / L, and 70 g / L, respectively. Each catalyst was obtained in the same manner as in Comparative Example 6 except for the amount of L.
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