Flame-retardant type sponge with anti-acarid function and preparation method thereof
A flame-retardant and anti-mite technology, which is applied in the field of flame-retardant sponge and its preparation, can solve the problems such as the migration of flame retardants and the performance change of soft polyurethane foam products, and achieve good anti-mite effect, stable chemical properties, and formula reasonable effect
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Embodiment 1
[0031] S1, preparation of open-cell polyurethane sponge matrix:
[0032] a) Weigh 100g of polyether GLR-2000, 60g of xylene diisocyanate, 15g of melamine, 3g of silicone oil, 0.25g of composite catalyst, 5g of rubber and 3g of water and add them to the foaming mold; the composite catalyst is an amine catalyst and tin The composite of catalyst, and the mass ratio of amine catalyst and tin catalyst is 2:1; Described amine catalyst is any one in the dipropylene glycol solution of 70% bis(dimethylaminoethyl) ether; Described tin class catalyst selects stannous octoate for use.
[0033] b) Add 0.6g of a mixture of sodium bicarbonate and azodicarbonamide to the foaming mold, the mass ratio of sodium bicarbonate and azodicarbonamide is 1:2, heat up to 60°C, foam for 10 minutes, and cool naturally to room temperature, cooled and dried at -20°C to obtain an open-cell polyurethane sponge matrix;
[0034] S2, preparation of anti-mite flame-retardant layer:
[0035] 1) According to the...
Embodiment 2
[0040] S1, preparation of open-cell polyurethane sponge matrix:
[0041] a) Weigh 100g of polyether GPOP-36 / 30, 60g of xylene diisocyanate, 25g of melamine, 3g of silicone oil, 0.5g of composite catalyst, 6g of rubber and 3g of water into the foaming mold; the composite catalyst is amine The compounding of catalyst and tin catalyst, and the mass ratio of amine catalyst and tin catalyst is 2:1; The amine catalyst is 70% bis(dimethylaminoethyl) ether; The tin catalyst is selected from octanoic acid tin.
[0042] b) Add 2g of a mixture of sodium bicarbonate and azodicarbonamide to the foaming mold, the mass ratio of sodium bicarbonate and azodicarbonamide is 1:2, heat up to 60°C, foam for 5 minutes, and cool naturally to Room temperature, cooling and drying at -20°C to obtain an open-cell polyurethane sponge matrix;
[0043] S2, preparation of anti-mite flame-retardant layer:
[0044] 1) According to the formula, weigh 100g of water-based acrylic adhesive, 2.1g of water-based ...
Embodiment 3
[0049] S1, preparation of open-cell polyurethane sponge matrix:
[0050] a) Weigh 100g of polyether GPOP-36 / 30, 50g of xylene diisocyanate, 16g of melamine, 2g of silicone oil, 0.4 of composite catalyst, 6g of rubber and 3g of water and add them into the foaming mold; the composite catalyst is an amine catalyst Compounding with tin catalysts, and the mass ratio of amine catalysts to tin catalysts is 2:1; the amine catalysts are 33% triethylenediamine solution; the tin catalysts are stannous octoate.
[0051] b) Add 0.6g of a mixture of sodium bicarbonate and azodicarbonamide to the foaming mold, the mass ratio of sodium bicarbonate and azodicarbonamide is 1:2, heat up to 50°C, foam for 10 minutes, and cool naturally to room temperature, cooled and dried at -20°C to obtain an open-cell polyurethane sponge matrix;
[0052] S2, preparation of anti-mite flame-retardant layer:
[0053] 1) According to the formula, weigh 100g of water-based acrylic adhesive, 0.5-5g of water-based ...
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