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High-strength structural adhesive for bonding rubber and concrete, and preparation method thereof

A high-strength structural adhesive and rubber bonding technology, applied in the field of structural adhesives, can solve the problems of weak ultraviolet and aging resistance of structural adhesives.

Active Publication Date: 2019-07-19
陕西杨凌磐基新材料科技有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] At present, structural adhesives still have the problems of low temperature resistance, high temperature resistance, strong alkali resistance, hydrolysis resistance, and weak UV aging resistance.

Method used

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  • High-strength structural adhesive for bonding rubber and concrete, and preparation method thereof
  • High-strength structural adhesive for bonding rubber and concrete, and preparation method thereof

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preparation example Construction

[0048] In one embodiment, the preparation method of described modified nanometer calcium carbonate comprises the following steps:

[0049] Ultrasonic dispersion of nano-calcium carbonate, heating, then adding coupling agent A, stirring, cooling, filtering, washing with water, drying, and grinding.

[0050] Preferably, the ultrasonic dispersion time in the preparation of the modified nano-calcium carbonate is 30-45 minutes.

[0051] More preferably, the ultrasonic dispersion time in the preparation of the modified nano-calcium carbonate is 45min.

[0052] Preferably, during the preparation of the modified nano-calcium carbonate, heating is performed at 50-75°C.

[0053] More preferably, in the preparation of described modified nanometer calcium carbonate, be heated to 75 ℃

[0054] Preferably, the preparation of the modified nano-calcium carbonate is stirred for 1-2 hours.

[0055] More preferably, stirring for 2 hours in the preparation of the modified nano-calcium carbonat...

Embodiment 1

[0109] Embodiment 1 of the present invention provides a high-strength structural adhesive for bonding rubber and concrete. The high-strength structural adhesive includes component A, component B and a primer.

[0110] The preparation method of described high-strength structural adhesive comprises the following steps:

[0111] (1) Mix the components in Group A evenly for use;

[0112] (2) Mix the components in component B evenly and set aside;

[0113] (3) Mix the components in the primer evenly and set aside.

[0114] In parts by weight, the group A includes 35 parts of polyester polyol, 1 part of polyether polyol, 50 parts of nano calcium carbonate, 1 part of modified nano calcium carbonate, 0.3 part of small molecule polyol, 1 part of silane joint agent.

[0115] In parts by weight, the component B includes 90 parts of isocyanate and 0.01 part of organotin catalyst.

[0116] In parts by weight, the primer includes 2 parts of trichloroisocyanuric acid and 90 parts of smal...

Embodiment 2

[0134] Embodiment 2 of the present invention provides a high-strength structural adhesive for bonding rubber and concrete. The high-strength structural adhesive includes component A, component B and a primer.

[0135] In parts by weight, said group A includes 40 parts of polyester polyol, 5 parts of polyether polyol, 60 parts of nano calcium carbonate, 5 parts of modified nano calcium carbonate, 4 parts of small molecule polyol, 10 parts of fumed white Carbon black, 2 parts of silane coupling agent.

[0136] In parts by weight, the component B includes 99.99 parts of isocyanate and 1 part of organotin catalyst.

[0137] In parts by weight, the primer includes 5 parts of trichloroisocyanuric acid and 98 parts of small molecule organic solvents.

[0138] The polyester polyol is castor oil polyol, and the trade mark is Polycin GR-80.

[0139] The polyether polyol is polyoxypropylene triol, purchased from Shandong Binjiang Jinsheng New Material Technology Co., Ltd.

[0140] The...

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Abstract

The invention relates to the technical field of structural adhesives, in particular to a high-strength structural adhesive for bonding rubber and concrete, and a preparation method thereof. The invention provides a high-strength structural adhesive for bonding rubber and concrete on one hand; the structural adhesive at least comprises a component A, a component B and a primer, wherein the component A at least comprises polyester polyol, polyether polyol, small molecule polyol and a silane coupling agent, and the weight ratio of the polyester polyol to the polyether polyol is (38-40):(1-2); andthe component B at least comprises isocyanate.

Description

technical field [0001] The invention relates to the technical field of structural adhesives, more specifically, the invention relates to a high-strength structural adhesive for bonding rubber and concrete and a preparation method thereof. Background technique [0002] Ordinary glue cannot achieve firm bonding with rubber and concrete at the same time due to its low colloidal strength. Non-structural adhesives have low strength and poor durability, and can only be used for ordinary and temporary bonding, sealing, and fixing, and cannot be used for bonding structural parts. [0003] The structural adhesive has high strength, anti-stripping, impact resistance, and simple construction process. It is used for the bonding of metal, ceramics, plastic, rubber, wood and other materials of the same kind or between different kinds of materials, and can partially replace traditional connection forms such as welding, riveting and bolting. The stress distribution on the joint surface is...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C09J175/14C09J11/04C09J11/06C08G18/66C08G18/48C08G18/36C08G18/32
CPCC08G18/3206C08G18/36C08G18/4829C08G18/6696C08K2003/265C09J11/04C09J11/06C09J175/14C08K3/26C08K9/06C08K5/544
Inventor 张会仙
Owner 陕西杨凌磐基新材料科技有限公司
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