Efficient flame-retardant polyurethane rigid foam with reaction and synergistic effect and preparing method
A synergistic, rigid foam technology, applied in the field of fire-fighting materials, can solve problems such as flammability, easy dripping, and large smoke, and achieve good flame-retardant effect, enhanced flame-retardant performance, and obvious inhibitory effect
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Embodiment 1
[0019] Embodiment 1 is not the content of the present invention. It is a preparation method without adding a flame retardant in the prior art. prepared from 2 parts and 2 parts of modified polymeric silicon surfactant. Its preparation method is: first add 1 part of dimethylaminoethoxyethanol and 2 parts of modified polymeric silicon surfactant to 20 parts of polyether polyol and mix; then add 20 parts of polymethylene polyphenylisocyanate Mix, put it into a box of 15cm×15cm×5cm at room temperature (20-25°C) and normal pressure, stir and foam quickly with an electric stirrer, and bake at 80°C after the foaming is stable Dry it in a dry box for 30 minutes, and let it stand at room temperature for 24 hours to obtain the finished polyurethane rigid foam raw material.
Embodiment 2
[0021] A high-efficiency flame-retardant polyurethane rigid foam with reaction and synergy is composed of 20 parts of polyether polyol, 20 parts of polymethylene polyphenylisocyanate, 5 parts of aluminum diethylphosphinate, and 7.5 parts of sodium alginate 1 part, 1 part of dimethylaminoethoxyethanol, and 2 parts of modified polymeric silicon surfactant.
[0022] The preparation method is as follows: first add 5 parts of aluminum diethylphosphinate, 7.5 parts of sodium alginate, 1 part of dimethylaminoethoxyethanol, and 2 parts of modified polymeric silicon surfactant to 20 parts of polyether polyol. Mix in one part; then add 20 parts of polymethylene polyphenyl isocyanate and mix, at room temperature (20-25°C) and under normal pressure, put it into a box of 15cm×15cm×5cm, use an electric stirrer Quickly stir and foam. After the foaming is stable, put it in an 80°C drying oven for 30 minutes, and let it stand at room temperature for 24 hours to obtain the finished polyurethane...
Embodiment 3
[0024] A high-efficiency flame-retardant polyurethane rigid foam with reaction and synergy is composed of 20 parts of polyether polyol, 20 parts of polymethylene polyphenylisocyanate, 5 parts of aluminum diethylphosphinate, and 7.5 parts of sodium alginate 2.5 parts of expandable graphite, 1 part of dimethylaminoethoxyethanol, and 2 parts of modified polymeric silicon surfactant.
[0025] The preparation method is as follows: first add 5 parts of aluminum diethylphosphinate, 7.5 parts of sodium alginate, 1 part of dimethylaminoethoxyethanol, and 2 parts of modified polymeric silicon surfactant to 20 parts of polyether polyol. part; add 2.5 parts of expandable graphite to 20 parts of polymethylene polyphenyl isocyanate, then mix the above raw materials thoroughly, and put 15cm×15cm× In a 5cm box, use an electric stirrer to stir and foam quickly. After the foam is stable, place it in an 80°C drying oven for 30 minutes, and leave it at room temperature for 24 hours to obtain the ...
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