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High thermal conductivity thermal conduction silica gel gasket and preparation method thereof

A technology of thermally conductive silica gel and high thermal conductivity, which is applied in the field of thermal interface materials. It can solve the problems of limited dispersion and addition amount, low thermal conductivity of gaskets, and inability to form thermal conduction paths, etc., to achieve good operability, increase filling volume, The effect of reducing viscosity

Inactive Publication Date: 2019-08-16
INST OF ENGINEERING THERMOPHYSICS - CHINESE ACAD OF SCI
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, the thermal conductive powder treated by the existing wet or dry surface modification process has the problems of local agglomeration and uneven wrapping of the surface modifier, which limits its dispersibility and addition amount in methyl vinyl silicone oil. An effective heat conduction path cannot be formed, resulting in a low thermal conductivity of the gasket, which cannot well meet the needs of practical applications.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0036] The components used in the preparation process of the thermally conductive silicone gasket with high thermal conductivity are as follows: (A) 20 parts by weight of methyl vinyl silicone oil with a viscosity of 800mPa·s; (B) 2 parts by weight of hydrogen-containing silicone oil with a hydrogen content of 0.25% ; (C) 80 parts by weight of n-hexane; (D) 450 parts by weight of spherical heat-conducting alumina powder filler, the particle size of large particle size alumina is 130 μm, and the particle size of small particle size alumina is 4 μm, wherein the ratio of large and small particle sizes is 350 parts by weight : 100 parts by weight; 4 parts by weight of (E) KH-570 coupling agent; 2 parts by weight of (F) catalyst; 2 parts by weight of (G) inhibitor. Preparation process: (1) heat the (D) in vacuum to remove excess water; (2) stir the (A)-(D) at a low speed with a planetary mixer at a stirring speed of 800 rpm for 25 minutes. Preliminary mixture; (3) The ultrasonic ca...

Embodiment 2

[0038]The components used in the preparation process of the thermally conductive silicone gasket with high thermal conductivity are as follows: (A) 20 parts by weight of methyl vinyl silicone oil with a viscosity of 200mPa·s; (B) 5 parts by weight of hydrogen-containing silicone oil with a hydrogen content of 0.15% (C) 200 parts by weight of n-hexane; (D) 500 parts by weight of spherical heat-conducting alumina powder filler, the particle size of large-sized alumina is 140 μm, and the particle size of small-sized alumina is 2 μm, wherein the ratio of large and small particle sizes is 380 parts by weight : 120 parts by weight; 3 parts by weight of (E) KH-560 coupling agent; 2 parts by weight of (F) catalyst; 2 parts by weight of (G) inhibitor. Preparation process: (1) heat the (D) in vacuum to remove excess water; (2) stir the (A)-(D) at a low speed with a planetary mixer at a stirring speed of 600 rpm for 25 minutes Preliminary mixture; (3) The ultrasonic cavitation working fr...

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PUM

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Abstract

The invention discloses a high thermal conductivity thermal conduction silica gel gasket and a preparation method thereof. According to the present invention, a thermal conduction powder filler, methyl vinyl silicone oil, hydrogen-containing silicone oil, an organic volatile dilution solvent, a silane coupling agent, a catalyst, an inhibitor and other components are used during the preparation, wherein the thermal conduction powder filler is wet by using the organic volatile dilution solvent so as to substantially reduce the viscosity of the thermal conduction powder base material and improvethe processability, and is subjected to surface modification and dispersion stirring by using an ultrasonic cavitation and mechanical stirring synergistic method so as to greatly increase the fillingamount of the powder filler and easily construct a thermal conduction path, such that the thermal conductivity of the thermal conduction silica gel gasket can be greatly improved; and after heating, the dilution agent in the base material is completely volatilized so as not to affect other performances of the obtained high thermal conductivity thermal conduction gasket.

Description

technical field [0001] The invention belongs to the field of thermal interface materials, and relates to a heat-conducting silica gel gasket, in particular to a heat-conducting silica gel gasket with high thermal conductivity and a preparation method thereof. Background technique [0002] In the field of electronic products, a large amount of heat will be generated during the operation of electronic components. In order to ensure the normal and stable operation of the equipment, the waste heat generated by power dissipation must be removed in time, otherwise the temperature of the electronic equipment will be too high and the operation stability will be reduced. and service life, and even cause circuit damage and system crash. Studies have shown that the reliability of electronic components is very sensitive to temperature. At the level of 70-80 °C, the reliability of the device will drop by 5% for every 1 °C increase in device temperature, and the failure rate of integrate...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L83/07C08L83/05C08K7/18
CPCC08L83/04C08L2205/025C08K7/18
Inventor 刘斌淮秀兰周敬之李勋锋胡玄烨
Owner INST OF ENGINEERING THERMOPHYSICS - CHINESE ACAD OF SCI
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