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Vanadium-titanium sea sand ore contains carbon pellets and preparation method thereof

A technology of sea sand ore and carbon pellets, which is applied in the field of metallurgy, can solve the problems of no effective recovery means for titanium, high cost, and low sea sand dosage, so as to improve the utilization rate of sea sand, improve the compressive strength, and prepare The effect of simple process

Active Publication Date: 2019-08-16
NORTHEASTERN UNIV
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  • Description
  • Claims
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Problems solved by technology

The blast furnace method is to add vanadium-titanium sea sand ore to ordinary iron ore for sintering and then enter the blast furnace for smelting. During the smelting process, most of the vanadium is selectively reduced into molten iron, while titanium enters the slag; the disadvantage of the blast furnace method is that sea sand is mixed into Low amount and high blast furnace temperature cause TiO 2 Reduction increases the difficulty of smelting, and there is no effective recovery method for titanium in slag, etc.
The non-blast furnace method is a smelting method in which vanadium-titanium sea sand ore is pelletized and roasted, then pre-reduced, and then smelted in an electric furnace to generate vanadium-containing molten iron and slag. The disadvantages include low titanium recovery rate, complicated smelting process and high cost.

Method used

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  • Vanadium-titanium sea sand ore contains carbon pellets and preparation method thereof

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preparation example Construction

[0033] The present invention also provides a method for preparing vanadium-titanium sea sand ore carbon-containing pellets, which specifically includes the following steps:

[0034] Step S1, drying vanadium-titanium sea placer and ordinary vanadium-titanium ore at 110-130°C for 2-4 hours, drying bituminous coal and lean coal at 85-95°C for 2-4 hours, and then drying the vanadium-titanium sea placer Grinding treatment with common vanadium-titanium ore; then, uniformly mixing vanadium-titanium sea-sand ore, common vanadium-titanium ore, bituminous coal and lean coal according to the component distribution ratio of the above-mentioned vanadium-titanium sea-sand ore carbon-containing pellets to obtain a mixed material.

[0035] Step S2, heating the mixed material to 250-350° C., and then pressing to obtain a hot compact. When the hot-pressing temperature is 250-350°C, the compressive strength of hot-pressed carbon-containing pellets of vanadium-titanium sea sand ore can reach more...

Embodiment 1

[0044] Step S1, drying the vanadium-titanium sea placer and ordinary vanadium-titanium ore at 120°C for 2 hours, drying the bituminous coal and lean coal at 90°C for 2 hours, and then grinding the vanadium-titanium sea placer and ordinary vanadium-titanium ore treatment, so that the particle size of vanadium-titanium sea placer is less than 200 mesh, and the particle size of ordinary vanadium-titanium ore is less than 150 mesh; after that, uniformly mix 10% vanadium-titanium sea-sand ore, 60% ordinary vanadium-titanium ore, 25% bituminous coal and 5% lean coal to obtain mixed materials.

[0045] Step S2, heating the mixed material to 300° C., and then pressing to obtain a hot briquette.

[0046] Step S3, heat-treating the hot-pressed block, the heat-treatment temperature is 500°C, and the heat-treatment time is 4 hours, to obtain hot-pressed carbon-containing pellets of vanadium-titanium sea sand ore. According to GB / T 14201-93, the compressive strength of the vanadium-titani...

Embodiment 2

[0048] Step S1, drying the vanadium-titanium sea placer and ordinary vanadium-titanium ore at 120°C for 2 hours, drying the bituminous coal and lean coal at 90°C for 2 hours, and then grinding the vanadium-titanium sea placer and ordinary vanadium-titanium ore treatment, so that the particle size of vanadium-titanium sea placer is less than 200 mesh, and the particle size of ordinary vanadium-titanium ore is less than 150 mesh; after that, uniformly mix 10% vanadium-titanium sea-sand ore, 60% ordinary vanadium-titanium ore, 25% bituminous coal and 5% lean coal to obtain mixed materials.

[0049] Step S2, heating the mixed material to 250° C., and then pressing to obtain a hot compact.

[0050] Step S3, heat-treating the hot-pressed block, the heat-treatment temperature is 500°C, and the heat-treatment time is 4 hours, to obtain hot-pressed carbon-containing pellets of vanadium-titanium sea sand ore. According to GB / T 14201-93, the compressive strength of the vanadium-titanium...

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Abstract

The invention discloses a vanadium-titanium sea sand ore containing carbon pellet. The vanadium-titanium sea sand ore containing carbon pellet comprises the following components in percentage, by weight, 22% -28% of bituminous coal, 4% -7% of lean coal, 0% -62.5% of common vanadium-titanium ore and 10%-67.5% of vanadium-titanium sea sand ore, the vanadium-titanium sea sand ore containing the carbon pellets is hot-pressed carbon-containing pellets, the compressive strength is more than 3000N or higher, the high-proportioning amount of the sea sand ores is realized, and the utilization rate of the sea sand ores is remarkably improved. The vanadium-titanium sea sand ore containing carbon pellet also provides a preparation method of the vanadium-titanium sea sand ore, the preparation method comprises the following steps of S1, mixing the vanadium-titanium sea sand ore and ordinary vanadium-titanium ore, carrying out drying and sample grinding treatment on the bituminous coal and the lean coal in sequence, and uniformly mixing the vanadium-titanium sea sand ore according to the group distribution ratio of the carbon pellets of the vanadium-titanium sea sand ore, normal vanadium-titaniumore, bituminous coal and lean coal to obtain a mixed material; S2, heating the mixed material to a hot-pressing temperature, and then pressing to obtain the hot-pressing block; and S3, carrying out heat treatment on the hot-pressing block, so as to obtain the vanadium-titanium sea sand ore hot-pressed carbon-containing pellet. The method is simple in process and low in cost.

Description

technical field [0001] The invention belongs to the technical field of metallurgy, and in particular relates to a vanadium-titanium sea placer carbon-containing pellet and a preparation method thereof. Background technique [0002] Vanadium-titanium sea placer is a kind of secondary enriched iron placer ore formed by the action of rivers, waves, tides and ocean currents in the coastal area. Its main useful mineral components are vanadium, titanium, iron, etc. After beneficiation, it can be Iron concentrate containing vanadium and titanium is obtained. Vanadium-titanium sea placer is currently recognized as a difficult-to-select and difficult-to-smelt iron ore resource in the world. Vanadium-titanium sea placer has regular particle shape, smooth and dense surface, coarser particle size, higher hardness and melting point, and poorer ball milling performance and pelletizing performance than other iron ores. The vanadium-titanium sea placer contains a small amount of ilmenite ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C22B1/245C22B1/16
CPCC22B1/16C22B1/2406C22B1/2413C22B1/245
Inventor 储满生赵伟张泽栋柳政根王宏涛鲍继伟唐珏韩冬
Owner NORTHEASTERN UNIV