Cathode slurry composition, secondary battery cathode comprising same, and lithium secondary battery
A lithium secondary battery and positive electrode slurry technology, which is applied in secondary batteries, secondary battery manufacturing, secondary battery repair/maintenance, etc., can solve problems such as thermal, mechanical shock and electrical shock instability, explosion, etc., to achieve Effect of Suppressing Interface Resistance
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Embodiment 1
[0199] (cathode preparation)
[0200] 1.2 g of polyvinylidene fluoride (PVDF) as a fluoropolymer was added to 30 g of N-methyl-2-pyrrolidone (NMP) to prepare a fluoropolymer solution.
[0201] Subsequently, 0.5 g of an oligomer (weight average molecular weight: 230,000, m1:n1=5:2) containing a unit represented by Formula 1a was added to the fluoropolymer solution to prepare a mixed solution.
[0202] 97.3g positive electrode active material (LiCoO 2 ) and 1.0 g of carbon black as a conductive agent were added to the mixed solution to prepare a positive electrode slurry composition (solid content of 65% by weight).
[0203] Subsequently, a positive electrode current collector (Al foil, Al foil) with a thickness of 10 μm was coated with the positive electrode active slurry composition, dried and rolled to prepare a positive electrode.
[0204] (Negative Electrode Preparation)
[0205] Artificial graphite as negative electrode active material, carbon black (carbon black) as co...
Embodiment 2
[0213] A positive electrode and a lithium secondary battery comprising the positive electrode were prepared in the same manner as in Example 1, except that 0.3 g of an oligomer (weight-average molecular weight: 230,000, m1:n1= 5:2), and 97.5g of positive electrode active material was added.
Embodiment 3
[0215] A positive electrode and a lithium secondary battery comprising the positive electrode were prepared in the same manner as in Example 1, except that an oligomer containing a unit represented by formula 1b (weight average molecular weight: 260,000, m2:n2=5: 2) Instead of oligomers containing units represented by formula 1a.
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