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Purpose of gamma-Al2O3 nano particles in preparation of modified high-silicon aluminum alloy

A high-silicon aluminum alloy and nanoparticle technology, applied in the field of high-silicon aluminum alloy metamorphism, can solve the problems of excessive metamorphism and weaken the metamorphic effect of high-silicon aluminum alloy, so as to improve wettability, strength and toughness, and avoid agglomeration. Effect

Inactive Publication Date: 2019-09-20
SHANGHAI JIAO TONG UNIV +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

However, there are many defects in chemical modification. First, the interaction between modified elements will weaken the modification effect of high-silicon aluminum alloys. For example, Sr and P generate Sr at high temperature. 3 P 2 , secondly, as the addition of P-containing master alloy increases, the refinement effect of the primary silicon phase will tend to be saturated, and even over-modification will occur. The essence of high-silicon aluminum alloy modification is to control the nucleation of silicon crystals. and growth process to tune the size and morphology of silicon crystals

Method used

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  • Purpose of gamma-Al2O3 nano particles in preparation of modified high-silicon aluminum alloy
  • Purpose of gamma-Al2O3 nano particles in preparation of modified high-silicon aluminum alloy
  • Purpose of gamma-Al2O3 nano particles in preparation of modified high-silicon aluminum alloy

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Embodiment 1~3

[0027] γ-Al 2 o 3 The method for modifying high-silicon aluminum alloys with nanoparticles is as follows: Weigh 20% of industrial pure silicon and 80% of commercial pure aluminum by weight percentage to form Al-20Si base alloy, and weigh 0.5% to 2% of the base alloy’s γ- Al 2 o 3 Nanoparticles, and wrapped with aluminum foil, the base alloy is added to the induction furnace for heating, and heated to 750 ° C, after the base alloy is completely melted, keep it warm for 10 minutes, remove the slag on the surface and stir to make the melt mix evenly, and then Set the induction furnace to 650°C to make it naturally cool in a semi-solid state. When the temperature of the alloy liquid reaches 650°C, remove the slag on the surface and add γ-Al wrapped in aluminum foil 2 o 3 Nanoparticles against encapsulated γ-Al with an ultrasound probe 2 o 3 Nano particles make it completely below the alloy liquid level, the immersion depth of the probe is 15mm, start the ultrasonic generator...

Embodiment 1

[0029] Example 1: γ-Al for modification 2 o 3 Nanoparticles as 0.5% of the mass of the base alloy,

Embodiment 2

[0030] Example 2: γ-Al for modification 2 o 3 Nanoparticles as 1% of the mass of the base alloy,

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Abstract

The invention belongs to the technical field of high-silicon aluminum alloys and particularly relates to a purpose of gamma-Al2O3 nano particles in preparation of a modified high-silicon aluminum alloy. The gamma-Al2O3 nano particles serve as a modificator, the usage amount of the modificator is 0.1 at. %-5.0 at. %, and the particle diameter is 20-50 nm; and the high-silicon aluminum alloy is composed of silicon and aluminum, the content of the silicon is 20 at. %-50 at. %, and the balance is aluminum. The gamma-Al2O3 nano particles are vibrated by means of ultrasound, the size of primary silicon becomes smaller, the morphology of the primary silicon is also converted from irregular, long-strip and five-disc star shapes into block shapes, eutectic silicon is also obviously refined, the shape of the eutectic silicon is converted into a short bar shape and a granulate shape from a long needle shape, both the primary silicon and the eutectic silicon achieve a modification effect, the strength and tenacity of the high-silicon aluminum alloy are improved greatly, and the high-silicon aluminum alloy is applicable to large-scale industrial production.

Description

technical field [0001] The invention belongs to the technical field of modification of high-silicon aluminum alloys, in particular to γ-Al 2 o 3 The use of nano particles in the preparation of modified high-silicon aluminum alloys. Background technique [0002] As an important lightweight metal structure material, high-silicon aluminum alloy has a series of excellent properties such as small specific gravity, high specific strength, low thermal expansion coefficient, good dimensional stability, wear resistance, and corrosion resistance. The improvement of the density of the alloy, the reduction of the thermal expansion coefficient, and the improvement of processing and casting properties, so high-silicon aluminum alloys are especially suitable for the manufacture of lightweight, wear-resistant structural parts, in aviation, aerospace, automotive industry, shipbuilding and electronic packaging and other fields have broad application prospects. [0003] At present, the rese...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C22C21/04C22C1/02C22C1/06
CPCC22C1/026C22C1/06C22C21/04
Inventor 王奎吕勋蒋海燕余水金余智成
Owner SHANGHAI JIAO TONG UNIV