Mesoporous molecular sieve compound laser direct structuring material and application thereof

A technology of laser direct structuring and mesoporous molecular sieve is applied in the preparation of laser direct structuring materials and the compound modification of laser direct structuring additives. Achieve the effect of improving bonding strength, shortening plating time, and improving carbon-forming ability

Active Publication Date: 2019-09-27
无锡赢同新材料科技有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

If the laser direct structuring additive is not properly selected, it may cause defects such as silver wires and pitting on the surface after injection molding, resulting in slow or even unplating of electroless plating in the later stage, and the failure of the 100-grid test; or the decline in mechanical properties after electroless plating Obviously, it cannot meet the requirements of material performance
[0005] At present, when traditional laser direct structuring additives are used for the production of LDS engineering plastic parts, there is such a contradiction: the increase in the amount of laser direct structuring additives often leads to a decrease in the physical properties of the substrate
However, when the amount of laser direct structuring additives is low, the electroless plating performance is often unsatisfactory, and the bonding strength between the coating and the substrate is also poor, which cannot meet the needs of various occasions

Method used

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  • Mesoporous molecular sieve compound laser direct structuring material and application thereof
  • Mesoporous molecular sieve compound laser direct structuring material and application thereof
  • Mesoporous molecular sieve compound laser direct structuring material and application thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1-4

[0051] Firstly, the mesoporous molecular sieve MCM-41 (average pore size: 3.4nm; particle size: 200~1000nm) is placed at 200℃, pressure Drying for 2 hours under vacuum conditions of <0.1MPa, meanwhile preheating bisphenol A bis(diphenyl phosphate) at 100°C. Under pressure Under the vacuum condition of <0.1MPa, 100 parts (parts by weight) of mesoporous molecular sieve and 15 parts (parts by weight) of bisphenol-A-diphenyl phosphate were mixed and heated to 120°C for 2h with stirring to obtain the phosphate / medium The porous molecular sieve hybrid material is reserved.

Embodiment 1

[0052] In Example 1, the total amount of raw materials is 6kg. In terms of weight percentage, the components are as follows:

[0053] Component Weight percentage Polycarbonate90% Laser Direct Forming Additive A1% Phosphate / Mesoporous Molecular Sieve Hybrid Material 3% Toughener5% Other additives1%

Embodiment 2

[0054] In Example 2, the total amount of raw materials is 5.5 kg, in terms of weight percentage, the components are as follows:

[0055] Component Weight percentage Polycarbonate88% Laser Direct Forming Additive A3% Phosphate / Mesoporous Molecular Sieve Hybrid Material 3% Toughener5% Other additives1%

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Abstract

The invention discloses a mesoporous molecular sieve compound laser direct structuring material. The mesoporous molecular sieve compound laser direct structuring material is prepared from, by weight, 70-95% of polycarbonate, 1-10% of a laser direct structuring additive, 1-5% of a phosphate ester / mesoporous molecular sieve hybrid material, 1-15% of a flexibilizer and 0.5-5% of other additives. The phosphate ester / mesoporous molecular sieve hybrid material is prepared from phosphate ester and a mesoporous molecular sieve. The invention further discloses the phosphate ester / mesoporous molecular sieve hybrid material and a preparation method thereof. The mesoporous molecular sieve compound laser direct structuring material, the phosphate ester / mesoporous molecular sieve hybrid material and the preparation method thereof have the advantages that the phosphate ester / mesoporous molecular sieve hybrid material can promote the carbon formation action during laser activation, and is conductive to shortening the plating time; the special structure of the mesoporous molecular sieve is conductive to the adhesion of metal to the surface of a base material, and can significantly improve the bonding strength between a cladding layer and the base material.

Description

Technical field [0001] The invention relates to the technical field of polymer materials, in particular to the compound modification of additives for laser direct structuring and the preparation and application of corresponding laser direct structuring materials. Background technique [0002] LDS, or laser direct molding, is a 3D-MID production technology of professional laser processing, injection and electroplating processes. Its principle is to give ordinary plastic components / circuit boards the electrical interconnection function, the support component function and the plastic shell The functions of support, protection, etc., as well as the shielding, antenna and other functions produced by the combination of mechanical entities and conductive patterns are combined in one, suitable for local thin circuit production. [0003] LDS can largely avoid the environmental pollution and water consumption of traditional plastic electroplating process, simplify the production process, and...

Claims

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Application Information

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IPC IPC(8): C08L69/00C08L51/04C08K13/04C08K3/22C08K3/24C08K7/24C08K5/523
CPCC08L69/00C08L51/04C08K13/04C08K3/22C08K3/24C08K7/24C08K5/523
Inventor 吴彤李莹
Owner 无锡赢同新材料科技有限公司
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